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Biosorption of Metals by Bioma Ss in Fixed-Bed Column
Biosorption of Metals by Bioma Ss in Fixed-Bed Column
ss in Fixed-Bed Column
2
Introduction(1/8)
★ That discharge industrial sewage
containing the excess heavy metals that
influences human function and health.
3
Introduction(2/8)
Table 1. Technologies for metals removal.
Technologies
Chemical precipitation and filtration
Chemical oxidation or reduction
Electrochemical treatment
Reverse osmosis
Ion Exchange
Evaporation
Biosorption 4
(Volesky, 2000 ;Chang et al ., 1997)
Introduction(3/8)
Biosorption
★Advantages:
- Have high density functional group
- Naturally can be acclimation
- Recycling
- Not to increase COD value in wastewater
★ Disadvantages:
- too slowly
5
Introduction(4/8)
★ Adsorption of heavy metals :
- Bounding to cell surface
- Algae gel adsorption
6
(Bohumil and Zdenek, 1995)
Introduction(5/8)
Biosorption treatment mechanism:
★ Extracellular accumulation
★ Intracellular accumulation
★ Bounding to the cells surface
8
( Jang, 1990 )
Introduction(7/8)
★Biofilter
In general, a reactor designs good or bad will
direct reflect on the removal rate. For giving th
e best removal ability of microorganism , a go
od reactor is the most important for biosorptio
n.
9
Introduction(8/8)
Bioreactor
★Mechanical dasher tank
★Fixed-bed
★fluidized-bed
10
Introduction(9/9)
Mechanical dasher tank Fixed-bed fluidized-bed
11
Objectives and scopes
★Find the parameter of the modelmass transfe
r and axial dispersion coeffcientswere adjust
ed from the experimental data.
★Proved the model adequate to decribe biosorpt
ion dynamics in fixed-bed column.
12
Materials and methods(1/9)
Piysics Definition
Desing experiment
13
Materials and methods(9/9)
150rpm at
About 16-
24 hour
aeration
Pump
Q=0.6
ml/min Discharge exit
C0
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Materials and methods(10/9)
C
u Z Uc z+△z
u CZ
b q
2
C
△Z
D Z 2 b t
ucz
17
Materials and methods(10/9)
★Mass balance
b q
u D
2
C C C
t Z Z 2 b t
Let
tu
L
Let C
t uL
Z C
Z
Z L
t L
u
18
Materials and methods(10/9)
C
t C
uL
u
L
C
b q
b t
u C
Z u C
L u
L
C
D 2C
Z 2 D 2C
L 2 D
L2
2C
2
b q
B t
b
b
q
ut
b
b
u
L
q
19
Materials and methods(10/9)
u
L
C
u
L
C
D
L2
2C
2
b
b
u
L
q
u
同除 L
C
C
D
Lu
2C
2
b
b
q
D
Lu 1
Pe Pe 為 peclet number
20
Materials and methods(10/9)
★Initial condition
C , 0 C0
★Boundary condition
C
0 Pe C 0, C F
C
1 0
21
Materials and methods(10/9)
★Boundary condition
C
0 Pe C 0, C F
1
CF
C 0, 0
0
22
CF
Materials and methods(10/9)
★Boundary condition
1
C
0
1
0
23
CF
Materials and methods(10/9)
★Initial condition
q , 0 q0
★Adsorption rate
q
Shm q qeq
★Coupling condition
q max bCeq
q eq 1 bCeq 24
Future work
★Use the numerical value analytical meth
od to proved the model adequate to decrib
e biosorption dynamics in fixed-bed colu
mn.
25
References (1/2)
• Leah C. Stanley, Kimberly L. Ogden. 2003. Biosorption of copper (II) fro
m chemical mechanical planarization wastewaters. Journal of Environment
al Management 69 : 289–297.
• Kimberly L. Ogden and Anthony J. Muscat, Leah C. Stanley. Investigating
the use of biosorption to treat copper CMP wastewater. Green and clean. Ju
ly/August 2001.
• Wang Jianlong. 2002. Biosorption of copper(II) by chemically modified b
iomass of Saccharomyces cereisiae. Process Biochemistry 37 : 847–850.
• Yesim Sag, Berya Tatar, Tulin Kutsal. 2003. Biosorption of Pb(II) and Cu
(II) by activated sludge in batch and continuous-flow stirred reactors. Biore
source Technology 87 : 27–33.
• Kuyucak, N., Volesky, B., 1988 , Biosorbent for recovery of metals from i
ndustrial solutions. Biotechnol. Lett. 10:137 142.
• Marshall S., 1976 ,Environmental Sources and Emissions Handbook, Noye
s Data Corporation, London.
26
References (2/2)
• N. Rangsayatorna, P. Pokethitiyooka, E.S. Upathamb, G.R. Lanza. 2004.
Cadmium biosorption by cells of Spirulina platensis TISTR 8217 immobili
zed in alginate and silica gel. Environment International 30 : 57– 63.
• Lyle Kirman. 1998. copper removal from cmp wasetewater. Prepared for
SEMATECH MEETING, SAN JOSE, CA.
• B. Volesk and Z. R. Holan. 1995. Biosorption of heavy metals. Biotechn
ol. Prog. 11:235-250.
• Kaewsarn P., 2002 , Biosorption of copper(II) from aqueous solutions by p
re-treated biomass of marine algae Padina sp, Chemosphere 47 : 1081 108
5.
• Ogden, K.L., Muscat, A., Stanley, L.C., 2001,Investigating the use of bios
orption to treat copper CMP wastewater. Micro 19 (7): 81 96.
• Sag Y., T. Kutsal, 1995 ,Biosorption of heavy metals by ZoogZea ramigera
: use of adsorption isotherms and a comparison of biosorption characteristi
cs , The Chemical Engineering Journal 60:181-188
27
Thanks for your attention
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