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Part 1: Structure and Properties of Carboxylic Acid Derivatives
Part 1: Structure and Properties of Carboxylic Acid Derivatives
L. G. Wade, Jr.
Chapter 21
Part 1: Structure and Properties of
Carboxylic Acid Derivatives
Chapter 21 5
Amide Structure
Chapter 21 7
Classes of Amides
Chapter 21 11
Structures of Acetonitrile and
Propyne
Chapter 21 16
Anhydride Nomenclature
Chapter 21 17
Multifunctional Compounds
The functional group with the highest priority
determines the parent name.
acid > ester > amide > nitrile > aldehyde > ketone >
alcohol > amine > alkene > alkyne
Chapter 21 18
Name the following compounds:
Chapter 21 19
Chapter 21 20
Chapter 21 23
Boiling Points of Carboxylic Acid Derivatives
Chapter 21 24
Intermolecular Forces of Amides
Chapter 21 25
Melting Points
Chapter 21 28
• Esters, tertiary amides, and nitriles provide a polar reaction
medium without or groups that can donate protons or act as
nucleophiles.
Chapter 21 29
IR Spectroscopy
Chapter 21 30
IR Spectrum of Ethyl Octanoate
Chapter 21 31
IR Frequencies of Lactones and
Lactams
Chapter 21 33
1
Typical H–NMR Absorptions
Chapter 21 34
NMR Spectra of DMF
Chapter 21 35
13C–NMR Spectroscopy