SPEKTROSKOPI MASSA

Prof. Dr. Maulidiyah, M.Si.

CHEMISTRY DEPARTMENT
MATHEMATICS AND NATURAL SCIENCES FACULTY
HALU OLEO UNIVERSITY
KENDARI
2020
Spektrum massa diisopropil eter
Fragmentasi diisopropil eter

M+ = m/z = 102
m/e = 65
Penataan ulang McLafferty

Heterolitik :
+. +.

..
.. Penataan ulang
McLafferty

Homolitik : +.

+.
Spektrum massa 2-metil pentanal
 FragmentasiOMS 2-metil pentanal
   O
CH3CH2CH2CH C - e-
H3C H2C CH2 CH C
H
H
CH3
CH3
M+ , m/e = 100

H3C H H H
H O O
C O H3C C CH2 +
H C C
 H2 C C HC H
 HC H
CH
H
CH3 CH3
CH3 m/e = 58
O
O
CH2 CH C
H3C H 2C CH2 CH C H3C CH2
+ H
H
CH3
CH3
m/e = 71
O
H3C H2C CH2 CH C H3 C H2 C CH2 O
+
H CH C
CH3 m/e = 43 H
CH3
Spektrum massa 3-heptanon
Fragmentasi MS 3- heptanon

O O
-
-e
H3C CH2 C CH2 CH2 CH2 CH3 H3C CH2 C CH2 CH2 CH2 CH3
  
M+ , m/e = 114

H3C H
C O H H
H
H O O
H2C  C H3C C CH2 + C C
CH2 CH2 CH3
H2C CH2CH3 H2C CH2CH
3
m/e = 72
 O O
H3C CH2 C CH2 CH2 CH2 CH3 H3C CH2 + C CH2 CH2 CH2 CH3
m/e = 29
O
O
H3C CH2 + C CH2 CH2 CH2 CH3
H3C CH2 C CH2 CH2 CH2 CH3
m/e = 29

C CH2 CH2 CH2 CH3

m/e = 85
O
O
H3C CH2 C CH2 CH2 CH2 CH3 +
H3C CH2 C CH2 CH2 CH2 CH3

H3C CH2 C
m/e = 57
Spektrum massa metilbutirat
Spektrum massa metil benzoat
Fragmentasi metil benzoat

O
O
C CH3 O
O - e- C CH3
O
- O CH3 C

M+ , m/e = 136

C
- HC CH - C=O

m/e = 51
m/e = 77 m/e = 105
Spektrum massa O-nitrotoluena
THANK YOU