Professional Documents
Culture Documents
CONTENTS
• Introduction
• Structure of NiTi
• Properties of nickel titanium alloy
• Shape memory
• Superelasticity
• Phase transformation
• Hysteresis
• Temperature transition range
• Properties of NiTiNOL
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CONTENTS
• Effect of additions and impurities
• Biocompatibility of NiTi alloys
• Nickel hypersensitivity
• Intraoral aging
• Corrosion susceptibility
• Recycling & Sterilization of Nickel Titanium
• Classification of NiTi compounds
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INTRODUCTION
• NiTi is a metal alloy containing roughly equal atomic
percentages of nickel and titanium. It was discovered in
early 1960s by William Buehler, a research metallurgist
at the US Naval Ordinance Laboratory in Silver
Springs, Maryland.
INTRODUCTION
• The Unitek Corporation licensed the patent [1974] and
offered a stabilized martensitic alloy under the name,
NiTiNOL, which is a stabilized form of the alloy in
which work hardening has abolished the phase
transformation
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STRUCTURE OF NITI
• Austenite phase/parent phase: Interpenetrating simple
cubic structure of the alloy at high temperature.
Stronger phase.
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STRUCTURE OF NITI
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STRUCTURE OF NITI
• Two crucial aspect of this phase transformation are
that the transformation is reversible, meaning that
heating above the transformation temperature will
revert the crystal structure to the simpler austenite
phase. The second key point is that the transformation
in both directions is instantaneous.
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• Super elasticity
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PHASE TRANSFORMATION
TERMINOLOGIES
• Phase Transformation: The change from one alloy phase to another
with a change in temperature, pressure, stress, chemistry, and/or
time. It is governed primarily by the free-energy difference between the
parent phase and potential new phases.
PHASE TRANSFORMATION
TERMINOLOGIES
• Austenitic finish (Af) Temperature: The temperature at which a shape
memory alloy finishes transforming to austenite upon heating. Most
important marker.
PHASE TRANSFORMATION
Reversible and instantaneous transformation as a function of temperature
heating
cooling
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PHASE TRANSFORMATION
TERMINOLOGIES
• Md: Upper limit of austenite finish temperature at which it is still possible to
stress-induce the formation of martensite.
Below Md, martensite formation under load allows superelasticity due to twinning.
Above Md, since martensite is no longer formed, the only response to stress is slip
of the austenitic microstructure, and thus permanent deformation.
• It does not offer the large memory effects of the martensite phase.
Superelasticity is exhibited within a very narrow temperature range.
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HYSTERESIS
• There is a difference in the transformation temperatures resulting in
a delay or lag in the transformation which is known as the
transformation temperature hysteresis.
HYSTERESIS
cooling
AP
MP
Heating
HYSTERESIS
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TEMPERATURE TRANSITION
RANGE
• Martensitic transformations do not occur at a precise temperature but
rather within a range known as temperature transition range(TTR).
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TEMPERATURE TRANSITION
RANGE
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SHAPE MEMORY
• Cooling austenite to form martensite, deforming the martensite,
heating to revert to austenite, thus returning the original, undeformed
shape is known as the thermal shape memory effect.
• To fix the original parent shape, the alloy must be held in position and
heated to about 500 °C (932 °F). This process is usually called shape
setting.
SUPERELASTICITY
• Stress induced martensitic transformation. Superelasticity occurs at a
narrow temperature range just above its transformation temperature.
• The springy, “rubber like” behaviour present in NiTi shape memory alloys at
temperatures above the Austenite finish temperature. The superelasticity
arises from the formation and reversal of stress induced martensite.
• In later 1980s, NiTi wires with an active austenitic grain structures (A NiTi)
appeared- with property of superelasticity.
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SUPERELASTICITY
• Typical Loading And Unloading Behavior Of Superelastic NiTi: Part of the
unusual nature of a superelastic material is that its unloading curve differs
from its loading curve (the reversibility has an energy loss associated with it).
Martensite
Austenite
• The force that the alloy delivers is not the same as the force applied to activate
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SUPERELASTICITY
• The different loading and unloading curves produce a more remarkable
effect that the force delivered by an A-NITI wire can be changed during
clinical use, merely by releasing and retying it to induce stress in wire.
• The initial activation force required for austenitic NiTi can be 3 times
greater than the force required to deflect a classic work hardened
martensitic wire (nitinol).
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MECHANISM OF
SUPERELASTICITY
• Unique force deflection curve for A-NiTi occurs because of phase transition
in grain structure from Austenite to Martensite, in response not to
temperature change but applied force.
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MECHANISM OF
SUPERELASTICITY
• Md of A-NiTi group is above mouth temperature allowing formation of stress
induced martensite at oral temperature.
• These alloys cannot be easily cooled down below their Ms (martensitic start)
temperature and do not display clinically useful shape memory.
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AF TEMPERATURE AND
SUPERELASTICITY
• To exploit superelasticity to its fullest potential, the working temperature of
orthodontic appliances should be greater than the Af temperature.
PROPERTIES OF NITINOL
• Spring back and Flexibility
Difference between maximum deflection and final deflection after loading.
Most advantageous property. Low force per unit of deactivation – stiffness.
NiTinol wires have greater spring back and larger recoverable energy than
Stainless Steel or β-Titanium when activated to same extent. High spring
back is useful in circumstances that require large deflections but low forces.
Delivers 1/5th – 1/6th force per unit of deactivation.
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PROPERTIES OF NITINOL
• Formability
Nitinol has poor formability. Bending adversely effects springback property of
this wire and so bending of loops and stops is not recommended.
Any 1st, 2nd and 3rd order bends have to be over prescribed to obtain
desired permanent bend.
Cinch backs distal to molar tubes can be obtained by flame annealing the
end of wire. This makes the wire dead soft and it can be bent into the
preferred configuration. A dark blue color indicates the desired annealing
temperature. Care should be taken not to overheat the wire because this
makes it brittle.
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PROPERTIES OF NITINOL
• Shape Memory
Andreasen and Morrow described the “shape memory” phenomenon as capability of
wire to return to a previously manufactured shape when it is heated through
Temperature Transition Range.
Shape memory effect had been suppressed by cold working the wire, during drawing
to more than 8 – 10%.
• Joinability: Not joinable. Crimpable hooks and stops are recommended for use.
• Friction: Bracket wire frictional forces with nitinol wires are higher than those with
SS wires and lower than those with β-Ti, in 0.018 inch slot.
In 0.022 inch slot – NiTi and β-Ti wires demonstrated similar levels of friction.
Although NiTi has greater surface roughness Beta –Ti has greater frictional resistance.
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ADVANTAGES AND
DISADVANTAGES
• Fewer arch wire changes. • Poor formability
• Poor joinability
• Less chair side time. • Low Stiffness and can be easily
deflected.
• Less patient discomfort. • Inadequate stability at
completion of treatment. Such
stability is often best maintained
• Reduction in time to accomplish by using stiffer Stainless Steel
rotations wires.
• Tendency for dentoalveolar
expansion.
• Expensive.
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• For thermally activated purposes most common third metals are Cu and Co
because thy reduce the hysteresis and bring TTR close to body temperature.
• Nickel-titanium alloys may have nickel content in excess of 50 per cent and can
thus potentially release enough nickel in the oral environment to elicit
manifestations of an allergic reaction.
• Manufacturers claim that these altered nickel titanium archwires exhibit less
corrosion than stainless steel or non-coated nickel-titanium wires, which results
in a reduction of the release of nickel and decrease the risk of an allergic
response.
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NICKEL HYPERSENSITIVITY
• Nickel is a strong immunologic sensitizer and may result in contact
hypersensitivity due to a direct relationship with the presence of this
metal in the environment and may be caused by ingestion or direct
contact with the skin and/or mucosa.
• The absorbed nickel binds to certain proteins and forms antigens that,
in turn, when in contact with the T lymphocytes of the regional lymph
nodes, result in the formation of activated specialized T-cells. These T-
cells are capable of causing tissue damage once brought into the blood
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NICKEL HYPERSENSITIVITY
• Tissue reactions may consist of intraoral diffuse red zones, blisters and
ulcerations extending to the perioral area, and eczematic and urticarial
reactions of the face or more distant skin areas.
NICKEL HYPERSENSITIVITY
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INTRAORAL AGING
• Intra oral exposure of NiTi wires alter the topography & structure of the
alloy surface through surface attack in form of pitting, crevice corrosion, or
formation of integuments.
• Variations in intra oral temprature might affect their properties & fracture
resistance.
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CORROSION SUSCEPTIBILITY
• Corrosion in alloys becomes a factor in the quality of the wire performance
in Orthodontics.
• Intra oral exposure of NiTi wires alter the topography & structure of the
alloy surface through surface attack in form of pitting, crevice corrosion, or
formation of integuments.
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CORROSION SUSCEPTIBILITY
• SEM photographs revealed that some nickel titanium and stainless steel
wires were susceptible to pitting and localized corrosion. The nitrides
coating did not affect the corrosion of the alloy, but epoxy coating decreased
corrosion.
• Titanium wires and epoxy-coated nickel titanium wires exhibited the least
corrosive potential.
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• The ability to recycle these archwire relies on effective sterilization of the wire
prior to re-use without resulting in deterioration of clinical properties.
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NITINOL
Presented by: Dr. H M Manisha
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Post Graduate Student I Year
Orthodontics and Dentofacial Orthopedics
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CONTENTS
• Classification of Orthodontic archwires
• Classification of NiTi Compounds
• Conventional NiTiNOL
• Pseudoelastic NiTiNOL
• Chinese NiTi
• Japanese NiTi
• Copper NiTi and its types
• Active Martensitic Thermodynamic NiTi
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CONTENTS
• Thermoelastic NiTi
• Graded Thermodynamic NiTi
• NiTiNOL Total Contro
• Supercable
• Esthetic NiTiNOL Archwires
• Clinical Applications
• References
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CLASSIFICATION OF ORTHODONTIC
ARCHWIRES
• Given by Evans and Durning, based on chronology.
Phase III- Superelastic active austenitic alloy (Chinese and Japanese alloy): 1980s
Phase IV- Thermodynamic active martensitic alloy (CuNiTi 40ºC): Early 1990s
CLASSIFICATION OF NITI
COMPOUNDS
• Kusy, 1991
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CONVENTIONAL NITINOL
Stabilized Martensitic form. Original alloy - 55% Nickel, 45% Titanium ratio of
elements
• Available as
PSEUDOELASTIC NITINOL
• Introduced in late 1980s.
• Exhibited Superelasticity.
• Referred to as A-NiTi
• Includes :
Chinese NiTi
Japanese NiTi (Sentinol)
27°C superelastic CuNiTi.
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CHINESE NITI
• Developed by Dr. Tien Hua Cheng in 1978 and was reported by
Burstone in 1985.
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CHINESE NITI
• High range of action of spring back is applicable when large deflections for
uprighting, labial and lingual movements are needed.
• Stiffness of Chinese NiTi is 36% that of Nitinol wire and 73% of stainless
stell wire. (Low)
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JAPANESE NITI
• Developed in 1978 by Furukawa Electric Co. Ltd. of Japan.
• Marketed as Sentalloy
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JAPANESE NITI
• Possible to modify the amount of orthodontic force in an individualized segment of archwire
by application of controlled heat with adequate temperature and time.
• Relationship between the temperature and time of heat treatment optimizes the superelastic
properties of the alloy.
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COPPER NITI
• Invented by Dr. Rohit Sachdeva & Suchio Miyazaki.
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COPPER NITI
• Martensitic phase at room temperature, it is possible to introduce relatively sharp bend on the
wire. The original arch form will be regained simply by heating the wire.
• Force extended on the dentoalveolar structure are remarkably low and thus, is recommended
for patients with periodontal problems.
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TYPES OF CU-NITI
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TYPES OF CU-NITI
3. Type III - Af temperature 35°C
Mid range of forces
Used in patients with low to normal pain threshold.
Can be used in periodontally compromised patients.
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ACTIVE MARTENSITE
THERMODYNAMIC WIRE
• CuNiTi Type II, III and VII. Also, Sentalloya and NeoSentalloy.
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ACTIVE MARTENSITE
THERMODYNAMIC WIRE
• Combines greater heat sensitivity, high shape memory, and extremely low
constant forces.
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ACTIVE MARTENSITE
THERMODYNAMIC WIRE
DISADVANTAGES
- Expensive
- Mouth breathers have a lower intraoral temperature and may not benefit from these.
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THERMOELASTIC NITINOL
• CHARACTERISTICS OF AN IDEAL THERMOELASTICIC NITINOL
WIRE:
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• Claims to deliver progressively heavier forces from anterior to posterior sections of the arch
wire of uniform dimension.
• Same arch wire has different TTR and different levels of forces are applied.
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• Marketed as BioForce (GAC), Titanol Triple Force (Forestadent), Tri-Force Thermal (ortho
Organizers) and Titanium Memory wire (AO).
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• BioForce arch wires with IonGuard finish: Developed by Ionization implant process. Have
less friction than non coated wires with no effects on its superelastic properties.
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• Accepts specific 1st-, 2nd-, and 3rd-order bends while maintaining its
desirable superelastic properties.
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SUPERCABLE
• Developed by Hanson. Combined the mechanical advantage of multistranded cables with
mechanical advantage of superelastic wires to create a super elastic NiTi coaxial wire.
• 7 individual strand woven together to maximize flexibility and minimize force delivery.
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SUPERCABLE
• Elimination of archwire bending.
• More efficient and effective control of rotations, tipping and leveling mechanics with 0.018”
archwire at the beginning of treatment.
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• Low friction between Teflon coating and the brackets, which enhances sliding mechanics.
• The size of the parent wire for a given slot size is made less to accommodate for the
thickness of the coating.
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• Turbo wire is a nine stranded rectangular braided NiTi, with low stiffness
and great flexibility. Turbo wire is recommended as an intial wire to unravel
and level while controlling torque and engaging brackets fully.
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• NiTi wires facilitate and simplify Beggs, because unravelling and leveling to attain good
tooth alignment occurs faster than with SS looped archwires and treatment time is
diminished.
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REFERENCES
• Orthodontic Materials – William. A . Brantley
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