Professional Documents
Culture Documents
Learning Objectives
2
References
• Bourne, M.C. (2002). Food Texture and Viscosity: Concept and Measurement
(2nd ed.). San Diego: Academic Press.
• Rao, M. A. (2007). Rheology of Fluid and Semisolid Foods: Principles and
Applications (2nd ed.). New York: Springer.
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What is Rheology?
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Why is RHEOLOGY important in
food industry?
• Crucial when the processing steps involve flow of liquid (such as pumping
of milk), or mixing (such as mixing during cooking of sauces).
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Sensory qualities of food: 3 categories
- Jowitt, 1974
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Texture
• A group of physical properties that derive from the structure of the food, e.g.
hardness, smoothness, fluffiness.
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Why different foods have different
textural properties?
Protein,
Chemical Physical
Physical
fat,
Composition Structure
Air
sugar,
(chemical analysis) (Microscopy
(Microscopy
water X-ray diffraction)
X-ray diffraction)
Fat globule
Physical properties
(texture or viscosity)
Creaminess, sandiness,
Sensorymelting etc Hardness etc
Mechanical
analysis 9
tests
Texture
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Texture & Viscosity
• Texture:
usually refers to solid foods
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Texture & Viscosity
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Quiz: True or False
2. Food rheology mainly studies how foods deform or flow under force.
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Terms in Rheology
•• Stress
() = Force (N)/Area (m2)
: pronounced as “sigma”
Unit: N/m2 or Pascal (Pa)
• Strain = L/L = change in length/original length
No unit: it’s a ratio (e.g. 0.2) or a percentage (e.g. 40%)
• Shear rate = shear strain/time (s-1)
Unit: s-1 (pronounced per second or second reciprocal)
• Viscosity () =
h pronounced as “eta”
Unit: Pa.s, mPa.s s pronounced as “sigma”
g pronounced as “gamma”
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Stress: force per unit area
Given force = 100 N, area A = 1 m2, area B = 100 m2, which area, A or B, is
experiencing a higher stress?
100N 100N
Stress=100N/1m2 A B Stress=100N/100m2
= 100 Pa = 1 Pa
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Types of Stress
Force
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Types of Stress
Force
Compressive stress:
• Stress resulted from force vertically Area
Force
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Types of Stress
Shear stress: L
Force
• Stress resulted from force pushing the top Area
layer of the object in parallel to the bottom
plane L
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STRAIN: CHANGE IN
DISTANCE
Strain (symbol ε = epsilon)
• refers to change of size / original size of the object under stress
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STRAIN: CHANGE IN
DISTANCE
• Shear strain: deformation in a shearing action (e.g. mixing or pumping)
Change in length, F
Shear Strain =
Unit length, b
b
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SHEAR RATE: RATE OF
DEFORMATION
• Shear Rate ( γ )
• is the velocity gradient established in a fluid as a result of an applied shear
stress (in other words, it’s rate of deformation).
• If a shearing force F is applied over an area A of the surface of a fluid in contact
with a flat stationary plane, the upper layer of the fluid will move with a
velocity v, while the layer in contact with the plane will remain stationary.
dv
A V V dy
F
Y
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Y
SHEAR RATE
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VISCOSITY
•• Viscosity
can be considered as the internal friction of a fluid or its internal resistance
to flow
• It is resulted from the internal structure/ inter-molecular force of the liquid
• Liquid with strong internal structure or intermolecular force
e.g. tomato ketchup has higher viscosity than water
Viscosity () =
• SI unit = Pa.s or mPa.s [1000 mPa.s = 1 Pa.s]
• Other common unit: centi-poise (cP)
• 1 mPa.s = 1 cP 24
VISCOSITY
Substance Viscosity (cP or mPa.s)
Water (0oC) 1.000
Water (20oC) 0.2838
20% sucrose solution (20oC) 1.967
40% sucrose solution (20oC) 6.223
60% sucrose solution (20oC) 56.7
Honey (25oC) 10000
Tomato ketchup (20oC, 10 RPM) 16500
Tomato ketchup (20oC, 5 RPM) 27000 25
Quiz: Calculation
1. 200N is applied on a surface of 100cm2, calculate the stress (Pa). 200N 100cm2
3. A 200Pa of stress is applied to a liquid and results in 500s-1 of shear rate. Calculate
the viscosity of the liquid.
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Food Rheology Overview
Solid Elastic
Texture
Viscoelastic
Viscous
Viscosity
Liquid Newtonian
Non-Newtonian
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Food Rheology
Elastic food
• Ideal solids deform reversibly – energy required for deformation is fully
recovered when stress is removed.
• Few foods are perfectly elastic.
h F
Original Original
h shape h shape
Compressed
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Food Rheology
Elastic food
• When weight is placed on the food, there is an instantaneous elastic
deformation (immediate deformation)
• There is no further change in deformation with time.
• When the weight is removed, there is an instantaneous elastic recovery to its
original height (immediate recovery).
• Examples: gelatin dessert (e.g. gummy bear, jelly)
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Deformation-time relationship for an elastic food
under constant stress
Deformation = h Force
removed
Gelatin desserts
Deformation h
Instantaneous Instantaneous
Elastic Elastic
deformation recovery
Gummy bear
Time
Force
applied
Deformation = h = 0
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Food Rheology
Viscoelastic food
• When the weight is removed, there is an instantaneous partial elastic recovery.
• Followed by retarded recovery
• The food does not return to its original height.
• It is permanently and irreversibly compressed (permanent deformation).
• Example: bread, steamed bun (mantou), bao
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Deformation-time relationship for a
viscoelastic food under constant stress
Force
removed
Instantaneous
Elastic
Retarded recovery
deformation
Deformation h
Retarded
Instantaneous recovery
Elastic
deformation
Permanent deformation
Time
Force
applied
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Viscoelastic Food
Force
h=2.2cm
Force
h=1.9cm Steamed 2.8cm
Bun
Steamed
Bun 3.1cm Force
removed
Force Force
h=1.5cm h=1.4cm
Instantaneous
Steamed Elastic Steamed
3.5cm Retarded 3.6cm
Bun recovery Bun
deformation
Deformation h
Retarded Force
recovery h=0.2cm
Instantaneous
Steamed Elastic Steamed
5cm deformation 4.8cm
Bun Bun
Permanent deformation=0.2cm
Time
Force 33
applied
How much is the permanent deformation?
Quiz: True or False
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Types of Viscous Behaviour
Liquid
Newtonian Non-Newtonian
Viscous Viscous
One-point
Viscosity η
Shear stress
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Shear rate Shear rate
Newtonian Fluid
• Viscosity is independent of the shear rate within the laminar flow range.
• Laminar flow is a streamline flow in a fluid.
• Turbulent flow is a fluid flow in which the velocity varies erratically in
magnitude and direction.
nt
u le
nte
b
bul
Tur
Shear stress σ
Onset of
Tur
Viscosity η
turbulence Laminar
i nar Onset of
Lam turbulence
Laminar flow: slow and calm Turbulent flow: fast and erratic
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Newtonian Fluid
In Summary
• Shear rate is directly proportional to the shear stress
• Viscosity is independent of the shear rate within the laminar flow range or
viscosity is constant with changing shear rate or time
Viscous
Viscous
Shear stress σ
Viscosity η
Intermediate Intermediate
Mobile
Mobile
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Shear rate Shear rate
Quiz: True or False
1. Newtonian fluid has constant viscosity in both laminar and turbulent flow regions.
2. The solutes in Newtonian fluid behave in similar patterns under both under low
and high shear rate (within laminar flow region)
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Non-Newtonian Fluid
• Plastic or Bingham
• Pseudoplastic Shear rate dependent (viscosity changes with shear rate)
• Dilatant
• Thixotropic
Time dependent (viscosity changes with time)
• Rheopectic
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Plastic or Bingham Fluid
• Named after Bingham who discovered the important principle that no flow occurs
at low stress.
• Apparent viscosity decreases with increasing shear rate (shear thinning)
• The term ‘plastic’ refers to materials that exhibit the yield stress (NOT synthetic
plastic)
• Must exceed a minimum shear stress known as “Yield Stress” before the flow
begins Is this rheological
e.g. must squeeze ketchup bottle before it can flow behaviour desirable for
ketchup?
• Yield Stress results from internal structure of food that binds it together
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Plastic or Bingham Fluid
• Plot of shear stress vs. shear rate: straight line with an intercept on the y-
axis (yield stress = a, b, c).
• Plot of Apparent viscosity vs. shear rate: apparent viscosity decreases with
increasing shear rate-> Shear Thinning
A
Yield stress B
Shear stress σ
b C Viscosity ηa
c
A
B
a
C
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a Shear rate ( γ
) b Shear rate ( γ )
Pseudoplastic Fluid
Salad dressing is a
lot more watery
than ketchup and
hence does not
have a yield stress
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Pseudoplastic Fluid
a b
Viscosity ηa
At low shear
Shear stress σ
rate,
pseudoplastic
fluid behaves like
Newtonian Newtonian fluid.
regime
Shear rate ( γ ) Shear rate ( γ )
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Underlying reasons for shear-
thinning behaviour
• At low shear rate, macro-molecules entangle with each
other to form some structure that significantly increases
viscosity
• At high shear rate, macro-molecules extend and align
At low shear rate
themselves in the direction of the flow
Direction of shear
• This in turn reduces resistance to flow (i.e. viscosity) at
higher shear rate, hence resulting in shear-thinning
behaviour
Solutes are macro-
molecules At high shear rate
(e.g. starch, pectin,
carrageenan) 50
Dilatant Fluid
• This type of fluid is fairly rare in the food industry and extremely rare in finished
products.
e.g. starch suspension (note: it’s different from starch gel or solution, which are made from
gelatinized starch).
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Dilatant Fluid
Viscosity ηa
• Time independent: At a given shear rate, viscosity remains constant over time
• Time dependent: At a given shear rate, viscosity changes with time
Shear stress
Shear stress
Shear stress
Hint: draw two dots on the line and compare the angle of two red lines. If the angle 55
is getting larger, it is shear thickening
Factors Affecting Viscosity
• Temperature
• Concentration of solute
• Suspended matter
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Temperature
Viscosity (mPa.s)
faster
less resistance to flow 60% Sucrose
40% Sucrose
• As viscosity is very temperature dependent, important to 2
20% Sucrose
control the experimental temperature and state the Water
temperature when quoting viscosity data 0 Temperature (oC) 100
E.g. 150mPas at 25oC
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Concentration of Solute
Viscosity (mPa.s)
• As concentration of solute increases, viscosity increases
• Higher concentration of solute, higher resistance to 2
flow, as each solute molecule contributes some
resistance 0.5
0 20 40 60
Concentration (% w/w)
58
Molecular Weight of Solute
Viscosity (mP.s)
• Corn syrup / maltodextrin is made by hydrolyzing high MW starch
into shorter chain polysaccharide. 500
• D.E. = dextrose equivalent (measures how close the
20
maltodextrin’s composition is to dextrose (glucose)) 10
30 40 50
• Low D.E. long chain high molecular weight (similar to starch) Solids (%)
60
Suspended
matter is
undissolved
substance in a
liquid 60
Quiz
Identify the factors involved in the following scenarios that affect viscosity.
1. Honey stored in fridge is much harder to scoop out
than that is stored under room temperature.
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Instruments for Texture Measurements
Uses:
• For measuring firmness of fruits (ripeness) and some vegetables
e.g. Magness-Taylor
Magness-Taylor
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Bloom Gelometer
Puncture Test
“Yield point” (YP) occurs when the punch begins to penetrate into
the food, which is represented by the sudden change in slope.
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Force Measuring Instruments:
Compression Extrusion Test
• Back extrusion: apply force to food until it flows through an outlet.
• The maximum force needed to accomplish extrusion is measured and is Annulus
used as an index to texture quality
e.g. Pea Tenderometer
Uses:
Food
• Viscous liquid, gels, fats, fresh and processed vegetables and fruits
• For foods that flow fairly readily under an applied force
• Not suitable for foods that do not flow easily e.g. bread, cakes, cookies,
breakfast cereals and candy
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A typical extrusion test graph
Point C: gives the force necessary to begin the process of extrusion
and the plateau C-D shows the force needed to continue extrusion.
B-C: the pack is solid except for C
small amounts of entrapped air, D
and the force increases steeply
from B to C pressing out the
Forc
remaining juice in the process.
e
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Warner-Bratzler Shear
Force Measuring Instruments:
Compression Test
• The sample is compressed in one direction and is unrestrained in the other two
dimensions.
• It causes a change in shape.
• Typically the platen that compressed the food should be larger in diameter than
the food specimen for a true compression test. Otherwise, it becomes a puncture
test.
• For measuring the hardness/ firmness of solid foods
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Which one is a true compression test?
Distance Measuring Instruments:
Linear & Volume
Linear Principle:
• Fluid or semi-fluid food sample is allowed to flow for specific period of time
and the distance traveled was measured as an indication of the viscosity of
the product.
• e.g. Bostwick Consistometer (measures the consistency of a thick liquid in a
quick but crude manner; often used for quick QC or comparison purposes).
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Distance Measuring Instruments:
Linear & Volume
Volume Principle:
Seed replacement
• Traditional method: volume replacement using method
fine particle such as rapeseed or sago.
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Quiz
Identify the type of test performed by the following equipment.
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Multiple Measuring Instruments
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Stable Micro Systems Texture analyser Instron system
Texture profile analysis
Principle of TPA:
• The machine compresses a bite-size food sample twice to imitate the action of the
jaw, and extracts from the resulting force-time curve (TPA), a number of textural
parameters that correlate well with sensory evaluation of those parameters.
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Video: TPA on white bread
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Texture profile analysis
Fracturability
Cohesiveness
Force
Area 1
Springiness Area 2
0
Length 1 Area 3 Length 2
Time
Adhesiveness
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Texture profile analysis
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Texture profile analysis
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Quiz: interpreting a TPA graph
280 g
Hardness
190 g
Cohesiveness
Force,
Adhesiveness
Gumminess
g
350 g s
Sprininess
220 g
s
- 26 g
0 s
5.4 s 3.8 s
Time, s
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Congratulations! You’ve made it to the end.
END of Topic.
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