L/O/G/O

Polypropylene Process
Technology
 Unipol -Dow

Gas phase Innovene- INEOS Technologies (BP)

reactor
Horizone- Japanese Polymer corp.

Novoven- Targor (Lumus ABB)

Spherizone - Basell

Borstar - Boreali

Bulk phase Click to add

Spheripol Title
- Basell
reactor Hypol II –Misui Chemical
Contents

1 UNIPOL™Polypropylene Technology

2 SPHERIPOL Polypropylene Technology

3 NOVOLEN Polypropylene Technology

UNIPOL™PolypropyleneTechnology
UNIPOL™PolypropyleneTechnology
POLYMERIZATION
UNIPOL™PolypropyleneTechnology
DEGASING AND RECOVERY
UNIPOL™PolypropyleneTechnology
REACTION CONDITION

• Pressure :  2,5 MPa.

• Temperature : 65-70 0C.
• Resident time :  1,25 hrs.
• Fluidized Bed Reactor
UNIPOL™PolypropyleneTechnology
BENEFITS PROCESS

• Enables a reduction in resin manufactur

ing costs through reduced peroxide usa
• Maintains the excellent operability you
have come to expect from Dow catalyst
and donor systems
• Compatible with the existing Dow fami
of SHAC Catalysts and Donor Systems
• Suitable for all other gas phase polypro
pylene technologies
SPHERIPOL Polypropylene Technology
SPHERIPOL Polypropylene Technology
SPHERIPOL Polypropylene Technology
SPHERIPOL Polypropylene Technology
 Grade Case Abbr. Grade Raw Material Property/Usage
Homo Polymer B HOMO F30G C3 Workability/Film,Tape,Extr. Molding
Random Co-Polymer C RACO EP 2Z 29G C3+3.5%C2 Transparency /Bear Box, Dashboard
Hetero Co-Polymer A HECO EPL31UA C3+12%C2 Impact/Car Bumper, Case
TERP
Ter-Polymer D O EP 3C 39F C3+C2+C4 Low Temp Seal/Food Wrap
81.4% CW 1 * C3: Propylene, C2: Ethylene, C4: Butene // H2 need to all grade as chain stopper
PL F302A/B C30 PL: Propylene Temp(^C)/Press(Barg)
Fresh C3 E304 To 5.9 81.4%
E-302 PL PP: PP Polymer Flow : Kg/Hr
Cat’ | 5.3 kg/h Cat:25% of C3
Bulk 12/18.3
TEAL | 10 Kg/h Grease/Oil Sol. Polymerization. V202 LS 11 V304 Material Consumption (Basis : A Grade HECO)
8.0 83/0.6 K301
Donor | 2.0 Kg/h 45/0.5 Flow
73/42 73/42 Service Name Abbr. Remark
WL 19.6 E203 CW Kg/H
Kg/h C302
JW F301 Propylene PRY 45,461 　
Oil JW
A dd
20/44 Ethylene ETY 5,330 Gas Phase Reactor(A only)
WL Liq kg/h LS Oil Off Gas Hydrogen H 14.1 0.54Kg/H Gas Phase Rx
WL R200 R201 55% PP R202 P304
V201 50 6. 7 44.6 Propylene P303 Liq. Add E504 WL Catalyst CAT 6.7 25% Cat of Grease/Oil Sol.
Rx Loop Pump 2.6 2.6 98%PP 2.7 Recycle. Tri-methyl Alum. TEAL 9.6 　
WL 33%PL 0.9 Donor DO 3.2
P200/201/202 F505 　

D ow n
80% PL

Blow
0.9 Off Gas
E201 46 0.8 29 CW 0.9 Liq. Add-tmer ALD 6.7 2nd Rx Feed (A Grade)
0.4 0.8 V504 Other Grade Specification
E501 45/0.1
7.4 0.6 105/0.6 Ethylene ETY - Rx; C:1.5T/H, D:0.8T/H
Polymer
79.5 LS
Neucl. V501 LS 0.8 Steaming
16 V507 Butene BTE - 1.7 T/H only D Grade

V508
H2 13.5Kg/h C2 1.6 T/h; C,D Grade K501
5.9 Agent 22 C501
WL/JW Pump| P203 P204 P205 P206 Utility Condition

V506
Propylene 44.7 16.5 LS CW Utility Abbr. Flow (Kg)
Flow M3/H | 2.2 45.0 1,400 1,400 V301 2%H2O 0.4 V505
Feed:80T/H 31.6 E303 Cooling Water (T/H) CWS 8,000
WL 90/18.5 81/0.1 2.2 E505 WO Instrument Air IA 920
Off Gas 8 CW
V502 70 PK501 V513
Plant Air PA 162
E310 CW Polymer C502 LP Steam (T/H) LS 13.5
79.5 CW 49.0
37.5 Degassing. N E502A/B P501A/B F502A/B Phase Separation 35Kg HP Steam HS 24
35.0 82%PL E301 82%PL Waste Water
Polymer Drying Inert Gas(Nitrogen) N 938
E305 P302A/B 15.5 90 Blow Down | V601 V602 V603 Flare Condition HP Purified N2 HN 100
22 48.0 43.8 BL502A/B Boiler Feed Water BFW 600
91.8%
PL V302 45/18 46/18
91%PP 0%H2O P502A/B Cap.Nm3/h | 365 186 8.4 140 T/H, 35/1.8
HP800 3.1 WW
E802
LS C301 CW 70
P301A/B Rx Top CW Powder BL853
E-405 0.0 E801 K800A/B PCS
44.5 E302 E303 SL303 90
60.3 304 SL903 SL904 HP34101/2/3
Propylene 99.6% PL 87%PP V855 A~E A~E Elutriator
2.5 HECO
LS N SL810 V811 PK811A/B SE853 BL34121/2/3
Purification Fresh Propylene F901/2/3
2.8 A/B Talc Solid
Powder PCS HP857
Butene-1 & Silo Sys. W Additive 45
D Grade
W
Extruder & PCW F34121
5kg/h WL 2.1T/H (JSW 30T/H x 2) MI34121/2/3/2/3
Off Gas 30/30 BL854A/B
48.1
E405 91%PP Melt/Liq
End of 20/20
K401 K801A/B/C/D SL34103 A~F
Additive V856 SL34104 A~F
TERPO Run CW HECO Peroxide DMW Blending PCS & Silo (700m3-22m; 5x2)
MX801A/B
R401
E403 6.9 CW CW PCS Comp| K800 K801 BL854 BL34121
WL

TERP 75/20
I-Powder Silos EX851/861 Cap.Nm3/h| 6450 13490 Product Silos
E401 (500m3-18m; 2) E853A/B (700m3-22m; 6x2)
LS O
52/21 P851A/B
2.1 HS/ N2/Hot Oil
4.9 WL E404 Column | C301 C302 C401 C501 C502 Pumps | P220 P201/2 P205/6 P301 P302 P601 P612 P613 P851 Bagging-25Kg
Feed
2.1 Cap’ M3 | 30 0 13.6 13.5 15.5 35.1 Cap.m3/h| 250 9000 1400 190 120 350 200 820 390
C3 2.8 / C2 5.3 / H2 0.54Kg / Liq Add 3.83Kg Big Bag-1Ton
56.2 Gas Phase Vessels | R201/2 R401 V302 V501 V502 Comp. | K301 K401 K501 BL502 K603 BL610 K704 K705 Bulk Loading
400 Section : HECO/TERPO Grade 93%PPReactor Sys Vol. M3 | 75 .0 138 140 42.0 23.7 Nm3/h | 4337 33000 952 12855 406 5000 1600 370
SPHERIPOL Polypropylene Technology
REACTION CONDITION

Prepolyreaction:
- Temperature : 20 °C
- Pressure : 34 –45 barg (same as in the 1st loop reactor)
Two Loop reactions and cooling system
(slurry reaction: 50 wt% slurry)
Loop reactor Operating condition:
- Temperature : 70 ~ 73 degC
- Pressure : 35 ~ 45 barg
- Production split : 65% in the first reactor, 35% in the second reactor
- Monomer (propylene, ethylene..)+hydrogen.
SPHERIPOL Polypropylene Technology
REACTION CONDITION

Sect.400 : Gas phase polymerization:

- Pressure : 14 bar g
- Temperature : 75-80 °C
Average bed density : 300-350 kg/m³
SPHERIPOL Polypropylene Technology
PICTURES

16
SPHERIPOL Polypropylene Technology
REACTION CONDITION

Sect.400 : Gas phase polymerization:

- Pressure : 14 bar g
- Temperature : 75-80 °C
Average bed density : 300-350 kg/m³
SPHERIPOL Polypropylene Technology
REACTION CONDITION

Sect.400 : Gas phase polymerization:

- Pressure : 14 bar g
- Temperature : 75-80 °C
Average bed density : 300-350 kg/m³

18
SPHERIPOL Polypropylene Technology
REACTION CONDITION

Sect.400 : Gas phase polymerization:

- Pressure : 14 bar g
- Temperature : 75-80 °C
Average bed density : 300-350 kg/m³

19
SPHERIPOL Polypropylene Technology
REACTION CONDITION

Sect.400 : Gas phase polymerization:

- Pressure : 14 bar g
- Temperature : 75-80 °C
Average bed density : 300-350 kg/m³

20
SPHERIPOL Polypropylene Technology
REACTION CONDITION

Sect.400 : Gas phase polymerization:

- Pressure : 14 bar g
- Temperature : 75-80 °C
Average bed density : 300-350 kg/m³

21
SPHERIPOL Polypropylene Technology
REACTION CONDITION

Sect.400 : Gas phase polymerization:

- Pressure : 14 bar g
- Temperature : 75-80 °C
Average bed density : 300-350 kg/m³

22
SPHERIPOL Polypropylene Technology
BENEFITS PROCESS

Product capability and versatility

- Wide range of homopolymers, random
copolymers and heterophasic impact and specialty
impact copolymers, as well as terpolymers for all
PP applications
- Unmatched product quality with minimum
property variation due to excellent process
- Stability and catalyst performance
SPHERIPOL Polypropylene Technology
BENEFITS PROCESS

Design flexibility
- Proven, single-line capacities, from 40 up to 550
kt/a are available for homopolymer, random
copolymer and heterophasic impact copolymer
production
SPHERIPOL Polypropylene Technology
BENEFITS PROCESS

Modular flexibility
- Expansion achievable through minor adjustments
- Extension of product range possible through
introduction of Metocene PP process as an add-on
technology
- Flexible modular design facilitates low investment
costs
NOVOLEN Polypropylene Technology
NOVOLEN Polypropylene Technology

Pressure: 2.2 - 3.0 Mpa;

Temperature: 65 - 90 0C
Resident time: 1.0 - 1.2 hrs.
Stire gas phase reactor
NOVOLEN Polypropylene Technology
BENEFITS PROCESS

- Produces a full range of homopolymers, random and impact

copolymers in only two identical reactors with Ziegler-Natta
and metallocene catalysts
- No dedicated reactor for impact copolymer production
- Small reactor volume = small gas inventory
- Rapid grade changes
NOVOLEN Polypropylene Technology

Parallel configuration  (homo, random)

NOVOLEN Polypropylene Technology

Cascade configuration 
NOVOLEN Polypropylene Technology
  UNIPOL SPHERIPOL NOVOLEN INNOVENE HYPOL-
  DOW / U. BASELL TARGOR BP AMOCO II
CARBIDE MITSUI

1. Năm hoàn thành phân

xưởng thương mại đầu
tiên 1968 1953 1967 1971 1968
2. Số phân xưởng sử
dụng license tính đến
2002 33 73 38 7 23
3. Tổng công suất các
phân xưởng sử dụng
license tính tới 2002
(tr.T/n) 5,0 13,8 4,3 2,1 2,1
4. Số lượng quốc gia có
phân xưởng theo license 17 32 17 5 8
pha khí
(phản ứng
5. Loại công nghệ tầng sôi) pha lỏng pha khí pha khí pha lỏng
  UNIPOL SPHERIPOL NOVOLEN INNOVENE HYPOL-
  DOW / U. BASELL TARGOR BP AMOCO II
CARBIDE MITSUI

2 lò
2 lò phản ph/ứng
6. Kiểu thiết bị phản ứng dọc, 2 lò ph/ứng 2 lò ph/ứng 2 lò ph/ứng dạng
ứng không khuấy dạng vòng khuấy dọc khuấy ngang vòng
bằng
bằng bơm tuần bơm tuần
7. Kiểu pha trộn khí hoàn cơ học cơ học hoàn
8. Công suất thiết kế
dây chuyền sản
xuất, nghìn tấn/năm 80 - 220 40 - 400 60 - 360 65 - 280 40 - 275
 L/O/G/O

Thank You!