Roll No. : 18123123-012 Fischer-Tropsch Synthesis • Fischer-Tropsch synthesis is a set of chemical reaction that can be used to produce fuels and chemicals from synthesis gas. • Synthesis gas is a mixture of CO and H2,which can be derived from natural gas, coal, or biomass. • CH4 + H2O → 3H2 + CO • C + H2O → H2 + CO Invention • The process was invented by German inventors Franz Fischer and Hans Tropsch in the 1920s. Reaction of the Process • In the process, carbon monoxide (CO) and hydrogen (H2) in the syngas are converted into hydrocarbons of various molecular weights according to the following reaction. • (2n+1) H2 + n CO → Cn H(2n+2) + n H2O • There are other side reactions taking place in the process, among which the water-gas-shift reaction is important. Catalyst • Fe • Ni • Co • From bottom to top it becomes cheaper, iron is very cheap among all above. • Most commly used catalyst is Fe (iron). Types of Reactor • Fluidized bed reactor • Fixed bed reactor • Slurry bed reactor
From up to down activity decreases upon space time yield.
Fischer-Tropsch Process Use of the Liquid fuel (hydrocarbon) Thank You