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  • Thermodynamic Mind Map

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    LEE LEE LAU
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    1) The first law of thermodynamics states that energy can neither be created nor destroyed, only transferred or changed in form. The change in internal energy of a system is equal to the heat transferred plus work done. 2) The second law of thermodynamics states that heat cannot spontaneously flow from a colder location to a hotter location without an external work being performed. In any cyclic process, the entropy of the universe increases or remains the same. 3) The third law of thermodynamics states that as the temperature of a system approaches absolute zero, the entropy of the system approaches a minimum finite value, usually zero.

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    1) The first law of thermodynamics states that energy can neither be created nor destroyed, only transferred or changed in form. The change in internal energy of a system is equal to the heat transferred plus work done. 2) The second law of thermodynamics states that heat cannot spontaneously flow from a colder location to a hotter location without an external work being performed. In any cyclic process, the entropy of the universe increases or remains the same. 3) The third law of thermodynamics states that as the temperature of a system approaches absolute zero, the entropy of the system approaches a minimum finite value, usually zero.

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    562 views1 page

    Thermodynamic Mind Map

    Uploaded by

    LEE LEE LAU
    1) The first law of thermodynamics states that energy can neither be created nor destroyed, only transferred or changed in form. The change in internal energy of a system is equal to the heat transferred plus work done. 2) The second law of thermodynamics states that heat cannot spontaneously flow from a colder location to a hotter location without an external work being performed. In any cyclic process, the entropy of the universe increases or remains the same. 3) The third law of thermodynamics states that as the temperature of a system approaches absolute zero, the entropy of the system approaches a minimum finite value, usually zero.

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    © All Rights Reserved
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    of 1

    1st Law 2nd Law

    • conservation of energy
    • thermal equilibrium
    • energy can be neither
    • process occurs sponteneous
    created nor destroyed
    • in any cyclic process the
    • ΔU=q+w
    entropy will either increase or
    • irreversible process: not in
    remain the same
    equilibrium changes
    (wirreversible=-ʃPext.dV) ΔQ
    • reversible process: Thermodynamic T1 heat transfer T2
    infinitesimal changes • energy transfer (work/heat) Hot Cold
    (w=-ʃPdV) • spontaneous direction of
    • constant P, isobaric chemical process
    (w=-PΔV) ΔS = Entropy = ΔQ/T
    • equilibrium states
    • constant V, isochoric (w=o) V1 Sf = Si (reversible)
    Pext
    • constant T, isothermal PS Sf > Si (irreversible)

    • two different T, T1 and T2 V2


    dw = F.dx
    (w=-nR(T2-T1)) Volume = Area (A) × Distance (dx)
    dV = A .dx
    3rd Law
    independent on the extensive properties
    mass of system system
    • open • a state of 0 entropy can only
    surroundings exist in a perfectly pure
    • closed
    dependent on the • isolated boundary crystalline solid at absolute 0
    intensive
    mass of system

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