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Acid-Base Equilibria
8–1
8–2
E.g. determine which acid is the strongest and which the weakest.
Acid Ka
HCN 4.9x1010
HCOOH 1.8x104
CH3COOH 1.8x105
8–3
HF 3.5x104
– Strategy
• Calculate the [H3O+] from pH; this is x in the table above.
• The rest of the quantities are obtained from the bottom row.
8–4
equilibrium calculation.
8–10
HCOOH
E.g. given the Ka’s of the following acid
1.8x104
list their conjugate bases in terms of
relative strength. HOCl 3.5x10 8
8–11
HCN 4.9x1010
8–15
• WB + SA
– SA produces H3O+ ions; use base as is.
– E.g. NH3 + HCl NH+ Cl or
4
NH3 + H2O NH4 + OH Ka = 1.8x105
H3O+ + OH 2H2O K w1= 1.00x10+14
NH3 + H3O+ NH4 + H2O K = Ka K w1= 1.8x109
• Conclusion: Quantitatively generate product (nearly).
• WA + WB: initially undissociated species dominates.
HOCl + H2O H3O+ + OCl Ka = 3.5x108
NH3 + H2O NH + OH Kb = 1.8x105
4
+
H3O + OH 2H2O K w1= 1.00x10+14
NH3 + HOCl NH4 + OCl K = KaKb K w1 = 63
• Conclusion: Reaction will sometimes, but not always, be quantitative.
E.g. determine the extent of reaction when di methyl amine (Kb =
5.4x104) reacts with either HF (Ka = 3.5x104) or HOCl (Ka = 3.5x108). 8–21
pH
• Sharp rise in curve is 6 WA
4
equivalence point. 2
SA