ADIB ADNAN I M E C H E A F F I L I AT E M E M B E R 80315369 The Modern Climate Crisis • The world is in the midst of perhaps the greatest environmental crisis of all time; global warming •Rapid industrialization, coupled with a reliance on fossil fuels, has led to a large amount of and greenhouse gas emissions •This has led to the current state, where the global concentration of in the atmosphere has reached levels not seen since the Pliocene era The Modern Climate Crisis The Modern Climate Crisis As shown in this chart by the US Environmental Protection Agency, the leading contributors to global greenhouse gas emissions are the transportation, power and industrial sectors. The transportation sector is the largest contributor at 29% The Transportation Sector •This graph shows the increase in greenhouse gas emissions since 2017 • Emissions reached a peak around 2006, with emissions slowly decreasing since then •This may be due to greater industry awareness regarding the effects of greenhouse gases, and the subsequent trends towards cleaner energy How to decrease emissions? Reducing emissions With the harmful effects of increasing atmospheric levels becoming more and more apparent, it becomes imperative to find methods to reduce greenhouse emissions. Some methods for achieving this are listed below; •Increasing energy efficiency •Fuel switching •Recycling •Increasing awareness •Reducing demand The Hydrogen Solution What is Hydrogen? •The first element in the periodic table •The most commonly available element in the universe •Solar fuel, used in nuclear fusion processes in the Sun •The possible solution to the global transportation sectors greenhouse emission crisis Why Hydrogen? •Widely available, and can be easily synthesized from water, hydrocarbons, and can even be produced through biological processes by bacteria and algae •Has very high energy density, meaning lower volumes can be used to produce large amount of energy •Has very clean emissions, the majority being pure water •Has already seen use in the space exploration industry, as well as in commuter transportation Hydrogen production most common method of producing hydrogen is by The electrolysis. A DC electrical power source is connected to two electrodes, or two plates (typically made from some inert metal such as platinum, stainless steel or iridium) which are placed in the water. Hydrogen will appear at the anode (where electrons enter the water), and oxygen will appear at the cathode The efficiency of electrolysis is increased through the addition of an electrolyte (such as a salt, an acid or a base) and the use of electrocatalysts. The overall chemical reaction thus becomes; Hydrogen as fuel There are two primary methods of harnessing power from hydrogen 1. Hydrogen Combustion 2. Hydrogen Fuel Cells
Let us first discuss hydrogen fuel combustion
Hydrogen Combustion •Since the success of Project Suntan in the 1960s, liquid hydrogen has become the fuel of choice in the space exploration sector • It’s low molecular weight and high intensity(5,500°F) means that when used in combination with an oxidizer such as liquid oxygen, liquid hydrogen yields the highest specific impulse, or efficiency in relation to the amount of propellant consumed, of any known rocket propellant Hydrogen Combustion •Hydrogen has also been used in automotive internal combustion engines, with companies such as BMW, Mazda and Aston Martin having also developed custom designs using hydrogen internal combustion engines. •Gasoline engines can also be retrofitted to operate on hydrogen, a process that is able to increase energy output by 15%. However, the modifications often amount to 1.5 times the initial cost of the engine, and as such is not always viable. Hydrogen Fuel Cells •The more commonly used form of hydrogen energy is the hydrogen fuel cell •This process takes advantage of the electrochemical reactions that occur during the oxidation of hydrogen to form water, in order to produce energy •There are many different types of fuel cells, such as PAFC, SAFC, etc. However, we will only be discussed the most commonly used type, PEMFCs. How do they work? How do they work?
There are thus two main reactions occurring throughout the process •At the anode;
•At the cathode;
•Overall;
By controlling the flow of the electrons, we are
able to power different electrical loads PEMFC performance •Multiple fuel cells are connected in parallel to create a stack, in order to produce the required amount of energy •Factors affecting fuel cell performance include; • Flow channel geometry • Type of electrolyte used • Operating temperatures • Type of catalyst used Hydrogen Fuel Cells in use •PEMFCs thus basically use the process used for electrolytic production of hydrogen in reverse to produce electrical energy. •This energy can then be used to power loads, such as electric motors •Vehicles thus using hydrogen fuel cells can be classified as electric vehicles •Due to the lack of fossil fuel combustion, the amount of greenhouse gases is greatly reduced compared to traditional automotive vehicles Hydrogen v Lithium The question thus arises, why use hydrogen instead of lithium ion battery technology? Some points to be noted; • Lithium has a much lower energy density compared to hydrogen • The lead time for production of lithium ion batteries is longer than that for hydrogen • Widespread use in applications ranging from commercial electronics, drones, and the automotive industry means that supply is lagging behind demand Hydrogen v Lithium Conversely, it should also be noted that; ◦ Lithium battery technology has more substantial existing infrastructure ◦ Batteries can be easily charged by the National Grid ◦ Lithium ion has lower cost to mileage ratio compared to hydrogen ◦ Storage and transportation of hydrogen poses a great problem, as high pressure vessels are required, and these may be costly ◦ While fuel cells themselves may not have any carbon emissions, the processes used to produce hydrogen may Addressing the issues •The lack of supply for the huge demand of lithium battery technology means that an alternative is required, regardless of advantages and disadvantages •Hydrogen, being already widely available in water, is able to meet such high demand •Carbon emissions can be kept low from the initial supply simply by using renewable energy sources, such as solar and wind, for initial hydrogen production •Storage and transportation pose the greatest problem. This can be combatted by installing small hydrogen production plants at each refueling center, an idea that has already been put into use by Shell and Toyota Conclusion With the rapid depletion of global fossil fuel reserves and the worsening effects of global warming and climate change, the world is on the cusp of an energy crisis. While numerous alternatives have been proposed, no concrete solution has been found to address this issue. Hydrogen poses a unique option, as a widely available fuel alternative that is not dependent upon fossil fuel use. It provides the most pragmatic path towards the automotive industry’s abolition of fossil fuels, and if the problems regarding it’s commercialization can be solved, it will possibly solve our global energy crisis. References 1. https://www.epa.gov/ghgemissions/sources-greenhouse-gas-emissions#industry 2. https://climate.nasa.gov/climate_resources/24/graphic-the-relentless-rise-of-carbon-dioxide/ 3. https://www.youtube.com/watch?v=f7MzFfuNOtY&t=807s 4. https://www.youtube.com/watch?v=iPheEg-K2qc&t=480s 5. https://www.latimes.com/business/autos/la-fi-hy-tesla-musk-model3-delivery-dates-20190302 -story.html 6. http://www.fuelcelltoday.com/technologies/pemfc 7. Aiyejina, Ararimeh & Sastry, M. (2012). PEMFC flow channel geometry optimization: A review. Journal of Fuel Cell Science and Technology. 9. 011011. 10.1115/1.4005393.