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ENGINEERING
Atomic Structures and Interatomic Bonding
Engr. Joseph Benedict N. Prim
Atomic
Structures
and
Interatomic
Bonding
Objectives
• To be able to name two atomic models cited, and note the differences
between them.
• To describe the important quantum-mechanical principle that relates
to electron energies.
• Briefly describe ionic, covalent, metallic, hydrogen and van der Waals
bonds.
• Note which material exhibit each of these bonding types
Outline
• Fundamental Concepts
• Atomic Models
• Quantum Numbers
• Electron Configurations
• Periodic Table
• Atomic Bonding in Solids
• Bonding forces and Energies
• Primary interatomic bonds (ionic, covalent & metallic)
• Secondary bonding
Fundamental
Concepts
• Basic Idea:
Properties of materials are a
consequence of
• Identity of the atoms
• Spatial arrangement of the
atoms
• Interaction between the atoms
• Thus, the need to study atomic
structure/bonding.
Atom
Example
• Uranium (Z = 92) - The highest of the
naturally occurring elements
Atomic Mass
(A)
Sum of the masses of protons
and neutrons; atomic mass
unit = amu = 1/12 mass of 12C
Isotopes
• Atoms that have two or more different atomic masses due to variable
number of neutrons (N)
• A≈Z+N
Atomic Weight
• Weighted average of the atomic masses of the atom’s naturally
occurring isotopes.
• It may be expresses in terms of atomic mass units or an atomic basis,
or the mass per mole of atoms.
• Atomic wt = wt of 6.022 x 1023 molecules or atoms
(Unit for atomic weight /mass)
• 1 amu/atom = 1g/mol
• C 12.011
• H 1.008
Atom VS Molecules
Atom Molecule
• An atom is smallest particle in an • Molecules are formed by the
element that has the properties combination of two or more atoms.
of the element. • Unlike atoms, A molecules can be
• It is not possible to breakdown subdivided to individual atoms.
the atom further retaining the • Molecules also are not visible to
properties of the element. the naked eye, while can be seen
• Atoms are not visible to the through highly magnifying
naked eye and are the basic microscopes and other scientific
building blocks. devices.
Water is comprised of numerous water molecules. Each water molecule is made up of one oxygen atom and
two hydrogen atoms.
Electrons in Atoms
Example
• Figure 2.5 Schematic representation of
the filled and lowest unfilled energy
states for a sodium atom.
Electron Configuration
(structure of an atom)
• For an atom, it is the manner in which possible
electron state are filled with electrons.
• The number of electrons in each subshell is
indicated by a superscript after the shell-subshell
designation.
• Table 2.2 Listing of the expected electron
configuration for some of the common elements.
Callister
Valence electrons
• The electrons in the
outermost occupied
electron shell, which
participates in
interatomic bonding.
Stable Electron
Configurations
• The states within the outermost or valence electrons
shell are completely filled.
Example.
Neon (Ne), Argon (Ar), Krypton (Kr), Helium (He) – these
elements are inert, or noble gases, which are virtually
chemically unreactive.
Electro-negative
• They readily accept electrons to become negatively charged ions, or
sometimes share electrons with other forms.
Figure 2.7 the electronegativity values for the elements. (The nature of the Chemical Bond, 3rd ed. Linus Pauling)
Electro-negative
Elements
Xa, Xb - electronegativity
- from Pauling’s table of electronegativities
% Ionic Character
• Example
Given: XCl = 3.0, XH = 2.1, XNa = 0.9
Find:
(1) Determine the % ionic character of HCL, NaCl and Cl2;
(2) rank the bonds in HCL, NaCl and Cl2 from most covalent to most ionic
Ans.
(1)Cl2 – 0 difference
HCL = {1 –exp[-0.25 (2.1 – 3.0)2]} x 100%
= 18% ionic
NaCl = {1 –exp[-0.25 (0.9 – 3.0)2]} x 100%
= 67% ionic
(2) Cl2 > HCl > NaCl - differences in electronegativities
Metallic bonding
• Valence e- drifting through the entire metal to form a sea (cloud) of
electrons
• Sharing of electrons
• Comparable electronegativity
• Non-directional type
Metallic bonding
• Due to the presence of the delocalized or free-electrons of the valence
electrons, Paul Drude came up with the name “sea of electrons” in
1900. The various characteristics properties of the metals are; they
have high melting and boiling points, they are malleable and ductile,
good conductors of the electricity, strong metallic bonds, and low
volatility.
• In this type, the valence electrons continuously move from one atom to
other as the outermost shell of electrons of each metal atoms overlaps
the neighboring atoms. So we can say that the in metal the valence
electrons continuously moves independently from one place to another
throughout the entire space.
Metallic bonding
Metallic bonding
Examples.
• Elemental diatomic molecules (F2, O2, H2 etc)
• Compounds (H2O, CO2, HNO3, C6H6, CH4 etc)
• https://depositphotos.com/64489357/stock-illustration-black-and-white-gecko-lizard.html
• https://study.com/academy/lesson/what-is-a-wave-mechanical-model.html
• https://surfguppy.com/ionic-and-covalent-bonding/electronegativity-bond-scale/
• https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Supplemental
_Modules_(Physical_and_Theoretical_Chemistry)/Physical_Properties_of_Matter/Atomic_and_Molecular_Pro
perties/Intermolecular_Forces/Specific_Interactions/Lennard-Jones_Potential
• https://biodifferences.com/difference-between-covalent-metallic-and-ionic-bonds.html