PH 2/2

Perhitungan PH pada asam/basa Lemah

Efek ion senama
buffer
Sebelum memulai pastikan anda memahami terlebih dahulu
mengenai :
1. Apa itu Asam Kuat dan Asam Lemah
2. Bagaimana membedakan asam kuat dengan asam Lemah
3. Apa itu Asam dan basa konjungasi; serta basa dengan Asam
konjungasi.
4. Apa itu senyawa Amfoter
PERHITUNGAN PH PADA
ASAM LEMAH/BASA LEMAH
Dapat menghitung PH dengan metode berdasarkan asumsi x=0 bila ka<<1
Dapat menghitung PH TANPA metode berdasarkan asumsi x=0 bila ka<<1
Weak Acids (HA) and Acid Ionization Constants

HA (aq) + H2O (l) H3O+ (aq) + A- (aq)

HA (aq) H+ (aq) + A- (aq)

[H+][A-]
Ka =
[HA]

Ka is the acid ionization constant

weak acid
Ka
strength

15.5
15.5
 What is the pH of a 0.5 M HF solution (at 250C)?
[H+][F-]
HF (aq) H+ (aq) + F- (aq) Ka = = 7.1 x 10-4
[HF]
HF (aq) H+ (aq) + F- (aq)
Initial (M) 0.50 0.00 0.00
Change (M) -x +x +x
Equilibrium (M) 0.50 - x x x
x2
Ka = = 7.1 x 10-4 Ka << 1 0.50 – x  0.50
0.50 - x
x2
Ka  = 7.1 x 10-4 x2 = 3.55 x 10-4 x = 0.019 M
0.50
[H+] = [F-] = 0.019 M pH = -log [H+] = 1.72
[HF] = 0.50 – x = 0.48 M
15.5
 When can I use the approximation?
Ka << 1 0.50 – x  0.50

When x is less than 5% of the value from which it is subtracted.

0.019 M Less than 5%
x = 0.019 x 100% = 3.8%
0.50 M Approximation ok.

What is the pH of a 0.05 M HF solution (at 250C)?

x2
Ka  = 7.1 x 10-4 x = 0.006 M
0.05
0.006 M More than 5%
x 100% = 12%
0.05 M Approximation not ok.

Must solve for x exactly using quadratic equation or method of

successive approximation. 15.5
Solving weak acid ionization problems:
1. Identify the major species that can affect the pH.
• In most cases, you can ignore the autoionization of
water.
• Ignore [OH-] because it is determined by [H+].
2. Use ICE to express the equilibrium concentrations in terms
of single unknown x.
3. Write Ka in terms of equilibrium concentrations. Solve for x
by the approximation method. If approximation is not valid,
solve for x exactly.
4. Calculate concentrations of all species and/or pH of the
solution.

15.5
 What is the pH of a 0.122 M monoprotic acid whose
Ka is 5.7 x 10-4?
HA (aq) H+ (aq) + A- (aq)
Initial (M) 0.122 0.00 0.00
Change (M) -x +x +x
Equilibrium (M) 0.122 - x x x
x2
Ka = = 5.7 x 10-4 Ka << 1 0.122 – x  0.122
0.122 - x
x2
Ka  = 5.7 x 10-4 x2 = 6.95 x 10-5 x = 0.0083 M
0.122

0.0083 M More than 5%

x 100% = 6.8%
0.122 M Approximation not ok.

15.5
 x2
Ka = = 5.7 x 10-4 x2 + 0.00057x – 6.95 x 10-5 = 0
0.122 - x
-b ±  b2 – 4ac
ax2 + bx + c =0 x=
2a
x = 0.0081 x = - 0.0081

HA (aq) H+ (aq) + A- (aq)

Initial (M) 0.122 0.00 0.00
Change (M) -x +x +x
Equilibrium (M) 0.122 - x x x

[H+] = x = 0.0081 M pH = -log[H+] = 2.09

15.5
 Ionized acid concentration at equilibrium
percent ionization = x 100%
Initial concentration of acid

For a monoprotic acid HA

[H+]
Percent ionization = x 100% [HA]0 = initial concentration
[HA]0

15.5
Weak Bases and Base Ionization Constants

NH3 (aq) + H2O (l) NH4+ (aq) + OH- (aq)

[NH4+][OH-]
Kb =
[NH3]

Kb is the base ionization constant

weak base
Kb
strength

Solve weak base problems like weak acids

except solve for [OH-] instead of [H+].

15.6
Monoprotic acids
HCl H+ + Cl- Strong electrolyte, strong acid
HNO3 H+ + NO3- Strong electrolyte, strong acid
CH3COOH H+ + CH3COO- Weak electrolyte, weak acid

Diprotic acids
H2SO4 H+ + HSO4- Strong electrolyte, strong acid
HSO4- H+ + SO42- Weak electrolyte, weak acid

Triprotic acids
H3PO4 H+ + H2PO4- Weak electrolyte, weak acid
H2PO4- H+ + HPO42- Weak electrolyte, weak acid
HPO42- H+ + PO43- Weak electrolyte, weak acid

4.3
ION SENAMA
Dapat menjelaskan maksud dan efek dari ion senama terhadap rx kimia
Dapat membuat rumus Henderson-Hasselbalch pada asam-basa konjungasi
Dapat menghitung efek Ion senama terhadap nilai PH
The common ion effect is the shift in equilibrium caused by the
addition of a compound having an ion in common with the
dissolved substance.

The presence of a common ion suppresses

the ionization of a weak acid or a weak base.

Consider mixture of CH3COONa (strong electrolyte) and

CH3COOH (weak acid).
CH3COONa (s) Na+ (aq) + CH3COO- (aq)
common
ion
CH3COOH (aq) H+ (aq) + CH3COO- (aq)
16.2
 Rumus PH pada Asam Lemah& Ion senama
Consider mixture of salt NaA and weak acid HA.

NaA (s) Na+ (aq) + A- (aq)

[H+][A-]
Ka =
HA (aq) H+ (aq) + A- (aq) [HA]

Ka [HA]
[H ] =
+
[A-] Henderson-Hasselbalch
equation
[HA]
-log [H+] = -log Ka - log
[A-] [conjugate base]
- pH = pKa + log
-log [H ] = -log Ka + log
+ [A ] [acid]
[HA]
-
pH = pKa + log [A ] pKa = -log Ka
[HA]
Contoh soal 16.1
Raymon Chang bab 16
Larutan Buffer
Dapat menjelaskan komposisi dan fungsi larutan buffer
Dapat menjelaskan mekanisme penstabilan PH pada larutan buffer
Dapat menghitung PH pada larutan Buffer
A buffer solution is a solution of:
1. A weak acid or a weak base and
2. The salt of the weak acid or weak base
Both must be present!

A buffer solution has the ability to resist changes in pH upon

the addition of small amounts of either acid or base.

Consider an equal molar mixture of CH3COOH and CH3COONa

Add strong acid
H+ (aq) + CH3COO- (aq) CH3COOH (aq)
Add strong base
OH- (aq) + CH3COOH (aq) CH3COO- (aq) + H2O (l)

16.3
 HCl H+ + Cl-
HCl + CH3COO- CH3COOH + Cl-

16.3
 Which of the following are buffer systems? (a)
KH2PO4/H3PO4
(b) NaClO4/HClO4, (c) C5H5N/ C5H5NHCl)

(a) H3PO4 is a weak acid its conjugate base and H2PO4- is a

weak base buffer solution
(b) HClO4 is a strong acid
not a buffer solution
(c) C5H5N is a weak base and its conjugate acid, C5H5NH
(the cation of the salt C5H5NHCl), is a weak acid.
Therefore, this is a buffer system.

16.3
Contoh soal 16.3