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Carbon Compounds
Inorganic Organic
carbon compound carbon compound
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
Testosterone
Thujone
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
e.g.
Carbohydrates
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
e.g.
Carbohydrates
Proteins
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
e.g.
Carbohydrates Vitamins
Proteins
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
e.g. fuels
Petroleum Coal
Natural gas
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
e.g. fuels
Petroleum Coal
Natural gas
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
e.g. fuels
Petroleum Coal
Natural gas
Synthetic materials
Carbon Compounds
Inorganic Organic
carbon compound carbon compound
(from living things)
Synthetic plastic
e.g. fuels
make
Petroleum Coal
Natural gas
Synthetic rubber
Carbon Compounds as fuels
When carbon compounds are completely burnt,
the reaction needs O2
and produces CO2 and H2O
Carbon Compounds as fuels
When carbon compounds are completely burnt,
the reaction needs O2
and produces CO2 and H2O
For example,
For example,
1) C2H5COOH
2) C3H7OH
3) C12H12O11
Practice Questions
Write the chemical equations for the incomplete combustion (burning) of:
1) C2H5COOH
2) C3H7OH
3) C12H12O11
Carbon
compounds
Hydrogen Carbons
Hydrogen Carbons
Practice Questions
Identify if the following substances are hydrocarbons:
Practice Questions
Identify if the type of hydrocarbons
Hydrocarbons
Alkane Alkene
Hydrocarbons
Alkane Alkene
Hydrocarbons
Alkane Alkene
All C-C At least one C=C
Practice Questions
Identify if the type of hydrocarbons
Hydrocarbons
Alkane Alkene
All C-C At least one C=C
Practice Questions
Identify if the type of hydrocarbons
Alkane Alkene
Esters
s s
Alkanes
Alkanes
• Each C can have a maximum of 4 bonds
• Only has C-C or C-H bonds
Alkanes
• Each C can have a maximum of 4 bonds
• Only has C-C or C-H bonds
Alkanes
• Each C can have a maximum of 4 bonds
• Only has C-C or C-H bonds
When C = 1,
Molecular formula Structural formula
CH4
When C = 1,
Molecular formula Structural formula
CH4
When C = 2,
Molecular formula Structural formula
C2H6
When C = 2,
Molecular formula Structural formula
C2H6
When C = 2,
Molecular formula Structural formula
C3H8
When C = 2,
Molecular formula Structural formula
C3H8
1 2 3 4 5
Practice Questions
Name the alkanes below:
Physical properties of Alkanes
Physical properties of Alkanes
Alkanes
Chemical
Reactions
1) Methane
2) Propane
3) Octane
1) Methane
2) Propane
3) Octane
Alkanes
Chemical
Reactions
Alkanes
Chemical
Reactions
• Tri-substitution
Naming the products of Substitution Reaction
Mono-substitution
Methane Chloromethane
Ethane Chloroethane
Methane Bromomethane
Naming the products of Substitution Reaction
Multi-substitution
• Di-substitution
Methane Dichloromethane
Structral
formula
Molecular
formula
Word
Writing chemical equation of Substitution Reaction
Structral
formula + +
Molecular
formula
Word
Writing chemical equation of Substitution Reaction
Structral
formula + +
Molecular
CH4 + Cl2 CH3Cl + HCl
formula
Word
Writing chemical equation of Substitution Reaction
Structral
formula + +
Molecular
CH4 + Cl2 CH3Cl + HCl
formula
Word Hydrogen
Methane + Chlorine Chloromethane + chloride
Writing chemical equation of Substitution Reaction
uv
Structral
formula + +
Molecular uv
CH4 + Cl2 CH3Cl + HCl
formula
Word uv Hydrogen
Methane + Chlorine Chloromethane + chloride
Structral
formula +
Molecular
formula
Word
Writing chemical equation of Substitution Reaction
uv
Structral
formula + +
Molecular
formula
Word
Writing chemical equation of Substitution Reaction
uv
Structral
formula + +
Molecular
formula
Word
Note: For one H replaced, one Cl2 is needed and one HCl produced
Writing chemical equation of Substitution Reaction
uv
Structral
formula + +
Molecular uv
C2H6 + 2Cl2 C2H4Cl2 + 2HCl
formula
Word uv Hydrogen
Ethane + Chlorine Dichloroethane + chloride
Note: For one H replaced, one Cl2 is needed and one HCl produced
Do your practice sheet
Chemical properties of Alkanes
Unreactive because strong C-H and C-C bonds
Alkanes
Chemical
Reactions
Alkanes
Chemical
Reactions
Hot Al2O3
+
Hot SiO2
+
Hot SiO2
+
Alkanes
Chemical
Reactions
b) Substitution
- one H replaced by one Halogen atom
- requires ultraviolet light/sunlight
c) Cracking
- long chain hydrocarbon to short chain hydrocarbon
- requires hot alumina or silica as catalyst
Practice Questions
1. What is the general formula of alkanes?
2. Write the molecular formula for an alkane that has four carbon atoms
and name the alkane.
3. Explain why the melting point and boiling point of alkanes increases when
the number of carbons increases
Alkane Alkene
Esters
s s
Carbon
compounds
H H
C C
H H
Double bond
Alkenes
• Has at least one C=C (unsaturated)
Functional groups
- Atoms responsible for the for the chemical
properties
Alkenes
• Has at least one C=C (unsaturated)
Functional groups
- Atoms responsible for the for the chemical
properties
e.g.
Alkenes
The general formula of alkenes is CnH2n
Ethane
General formula = CnH2n+2
Alkenes
The general formula of alkenes is CnH2n
Ethane Ethene
General formula = CnH2n+2 General formula = CnH2n
Alkenes
The general formula of alkenes is CnH2n
Ethane Ethene
General formula = CnH2n+2 General formula = CnH2n
Alkenes
The general formula of alkenes is CnH2n
When C = 2,
Molecular formula Structural formula
C2H4
When C = 2,
Molecular formula Structural formula
C2H4
When C = 3,
Molecular formula Structural formula
C3H6
When C = 3,
Molecular formula Structural formula
C3H6
1 2 3 4 5 1 2 3 4 5 1 2 3 4 5
But-1-ene But-2-ene But-3-ene
(?)
One last thing about naming alkenes
You can number the carbons by:
1. Find the longest straight chain
2. Number the carbon in the longest chain, starting with the carbon atom that has
the double bond closest to the end of the chain
1 2 3 4 5 1 2 3 4 5 1 2 3 4 5
But-1-ene But-2-ene But-3-ene
(?)
One last thing about naming alkenes
You can number the carbons by:
1. Find the longest straight chain
2. Number the carbon in the longest chain, starting with the carbon atom that has
the double bond closest to the end of the chain
1 2 3 4 5 1 2 3 4 5 5 4 3 2 1
But-1-ene But-2-ene But-2-ene
Same molecule
Practice Questions
Write down ALL the different alkenes that you can form from:
1) Pentene
2) Heptene
3) Hexene
Physical properties of Alkenes
Physical properties of Alkenes
Alkenes
Chemical
Reactions
1) Ethene
2) Propene
3) Octene
1) Hexene
2) Nonene
3) Decene
Alkenes
Chemical
Reactions
Addition
ALKENES
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Substitution Addition
ALKANES ALKENES
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Hydrogenation Hydrohalogenation
Hydration
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Hydrogenation Hydrohalogenation
Hydration
Generation Reaction:
+ X-X
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Halogenation
+
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Halogenation
+
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Halogenation
1,2- dichloro
+
pentane
+ 2,3- dichloro
pentane
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Halogenation Chlorination
1,2- dichloro
+
pentane
+ 2,3- dichloro
pentane
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Halogenation
1,2- dibromobutane
+
+ 2,3- dibromobutane
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Halogenation Bromination
1,2- dibromobutane
+
+ 2,3- dibromobutane
Addition Reaction
Chlorination Bromination
Observation Observation
Pale yellow colour of chlorine water Brown/orange colour of brominewater
decolourized decolourized
Addition Reaction
Chlorination Bromination
Observation
Brown/orange colour of brominewater
decolourized
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Hydrogenation
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Hydrogenation
But-1-ene Butane
Alkene Alkane
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Hydrogenation
Ni
+
180
But-1-ene Butane
Alkene Alkane
Addition Reaction
- Atoms are ADDED to molecules
Hydration
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Hydration
Addition Reaction
- Atoms are ADDED to molecules
Hydration
Addition Reaction
- Atoms are ADDED to molecules
Hydration
H3PO4
+
60 atm, 300
Addition Reaction
- Atoms are ADDED to molecules
Hydrohalogenation
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Hydrohalogenation
But-1-ene 1-chlorobutane
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Oxidation
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Oxidation
+ +
But-1-ene Butan-1,2-diol
Addition Reaction
Addition Reaction
- Atoms are ADDED to molecules
Oxidation
+ +
But-1-ene Butan-1,2-diol
Oxidation
Alkenes
Chemical
Reactions
Monomer Polymer
Polymerization Reaction
Polymerization reaction
- Combining small molecule units (monomers) to form
one long chain molecule (polymer)
Monomer Polymer
Polymerization Reaction
Polymerization reaction
- Combining small molecule units (monomers) to form
one long chain molecule (polymer)
Monomer Polymer
Condition
1. High pressure
2. High Temperature
n n
Ethene Poly(ethene)
Chemical properties of Alkenes
Reactive because of C=C bonds
Alkenes
Chemical
Reactions
b) Addition
- H2C=CH2 + X-X C2H2X2
1. Halogenation 4. Hydration
2. Hydrogenation 5. Polymerization
3. Hydrohalogenation
c) Polymerization
- small molecules to long chain
Practice Questions
1. Write the chemical equation for the reaction between:
2. Describe two tests that can be carried out to differentiate alkenes from
alkanes
Similarities between alkanes and alkenes
Alkanes Alkenes
CnH2n+2 General formula CnH2n
Saturated Type of hydrocarbon Unsaturated
Only C-C or C-H Type of bond in At least one C=C
molecule
1. Substitution Type of chemical 1. Addition
2. Cracking reaction 2. Polymerization
No change Reaction with bromine Brown to colourless
water
No change Reaction with KMnO4 Purple to colourless
Less sootier Combustion Sootier
Carbon Alkane Alkene Homologous Series
number (Family)
1 Methane -
2 Ethane Ethene Properties of Homologous Series
3 Propane Propene 1. Same general formula
4 Butane Butene 2. Each member differs by –CH2
5 Pentane Pentene 3. Similar chemical properties
6 Hexane Hexene 4. Physical properties follow a trend
5. Can be prepared using same methods
7 Heptane Heptene
8 Octane Octene
9 Nonane Nonene
10 Decane Decene
Carbon
compounds
Isomerism
Naming more difficult molecules
Isomers
- Compounds of the same molecular formula but different structural formula
C4H10
Isomerism
Isomers
- Compounds of the same molecular formula but different structural formula
C4H8
Practice Questions
Pentane has three structural isomers. Draw and name all of them.
Practice Questions
Pentane has three structural isomers. Draw and name all of them.
Pentane
2,2-dimethylbutane
2-methylbutane
Practice Questions
Pentene has five structural isomers. Draw and name all of them.
Practice Questions
Pentene has three structural isomers. Draw and name all of them.
Pent-1-ene
3-methylbut-1-ene
Pent-2-ene
2-methylbut-1-ene
2-methylbut-2-ene
Do your practice sheet
Carbon
compounds
Isomerism
Carbon
compounds
Isomerism
Alcohol
Alcohol
• Has at least one O-H
Alcohol
• Has at least one O-H
Alcohol
• Has at least one O-H
Functional groups
- Atoms responsible for the for the chemical
properties
Hydroxyl group
Alcohol
The general formula of alcohol is CnH2n+1OH
Ethane
General formula = CnH2n+2
Alcohol
The general formula of alcohol is CnH2n+1OH
Ethane Ethanol
General formula = CnH2n+2 General formula = CnH2n+1OH
Alcohol
The general formula of alcohol is CnH2n+1OH
Ethane Ethanol
General formula = CnH2n+2 General formula = CnH2n+1OH
Alcohol
The general formula of alcohol is CnH2n+1OH
When C = 2,
Molecular formula Structural formula
C2H5OH
Alcohol
The general formula of alcohol is CnH2n+1OH
When C = 2,
Molecular formula Structural formula
C2H5OH
Alcohol
The general formula of alcohol is CnH2n+1OH
When C = 2,
Molecular formula Structural formula
C2H5OH
Carbon number Formula Name of compound
1
2
3
4
5
6
7
8
9
10
Do your practice sheet
Isomerism in Alcohol
Isomerism: Same molecular formula, different structural formula
When C = 3,
Molecular formula Structural formula
C3H7OH
Isomerism in Alcohol
Isomerism: Same molecular formula, different structural formula
When C = 3,
Molecular formula Structural formula
Propan-1-ol
C3H7OH
Isomerism in Alcohol
Isomerism: Same molecular formula, different structural formula
When C = 3,
Molecular formula Structural formula
Propan-1-ol
C3H7OH
Propan-2-ol
Practice Questions
Butanol has five isomers. Draw and name all of them.
Preparation of Alcohol
Preparation of Alcohol
Hydration of
ethene
Preparation of Alcohol
Hydration of
ethene
H3PO4
+
60 atm, 300
Hydration of Fermentation
ethene
Fermentation
- Breaking down carbohydrates into ethanol and carbon dioxide using yeast
Glucose
Ethanol vapour
condenses
Pure Ethanol
vapourized
Mixture of
yeast, ethanol
and water Ethanol collected
Physical properties of Alcohol
Physical properties of Alkenes
Alkyl chain
Insoluble in Hydroxyl
water Soluble in water
Alcohol
Chemical
Reactions
1) Methanol
2) Butanol
3) Pentanol
Chemical properties of Alcohol
Alcohol
Chemical
Reactions
+
Dehydration
Dehydration
- Removal of H2O from molecule
Porcelain
C2H5OH C2H4 + H2O
Dehydration
Dehydration
- Removal of H2O from molecule
Method 1 Method 2
a) Ethanol
b) Hexa-1-ol
c) Penta-1-ol
Chemical properties of Alcohol
Alcohol
Chemical
Reactions
+2 +
+2 +
+2 +
H+/KMnO4
C3H7OH + 2[O] C2H5COOH + H2O Heat
H+/KMnO4
C3H7OH + 2[O] C2H5COOH + H2O Heat
H+/K2Cr2O7
C3H7OH + 2[O] C2H5COOH + H2O
Observation: Observation:
KMnO4 turns from purple to colourless K2Cr2O7 turns from orange to green
Oxidation
Oxidation
- Molecule gains O
Oxidation
Oxidation
- Molecule gains O
Alcohol is volatile
(evaporates easily)
Oxidation
Oxidation Why do you need a
- Molecule gains O Liebig condenser?
Alcohol is volatile
(evaporates easily)
Oxidation
Oxidation
- Molecule gains O
Reflux
Oxidation
Oxidation
- Molecule gains O
Reflux
Distillation
Practice Questions
Write the chemical equation for the oxidation of:
a) Ethanol
b) Hexa-1-ol
c) Penta-1-ol
Chemical properties of Alcohol
Alcohol
Chemical
Reactions
b) Dehydration
- removing H2O
- using dehydrating agents such as porcelain or conc H2SO4
c) Oxidation
- adding O
- using H+/KMnO4 or H+/K2Cr2O7 and heat in reflux
Uses of Alcohol
Lord Nelson’s
body inside
Uses of Alcohol
Uses of Alcohol
1. Alcohol drinks
2. Medicine (e.g. antiseptic)
3. Cosmetics (solvent)
4. Fuel
Abuse of Alcohol
2. Draw all the structural formulae of an alcohol that has three carbon atoms
and name each of the isomers
Isomerism
Carbon
compounds
Isomerism
Carboxylic Acids
Carboxylic acid
• Has COOH
Functional groups
- Atoms responsible for the for the chemical
properties
Ethane
General formula = CnH2n+2
Carboxylic acid
The general formula of carboxylic acid is CnH2n+1COOH
Ethane Ethanol
General formula = CnH2n+2 General formula = CnH2n+1COOH
Carboxylic acid
The general formula of carboxylic acid is CnH2n+1COOH
When C = 1,
Molecular formula Structural formula
HCOOH
Carboxylic acid
The general formula of carboxylic acid is CnH2n+1COOH
When C = 1,
Molecular formula Structural formula
HCOOH
Carboxylic acid
The general formula of carboxylic acid is CnH2n+1COOH
When C = 1,
Molecular formula Structural formula
HCOOH
Methanoic acid
Carboxylic acid
The general formula of carboxylic acid is CnH2n+1COOH
When C = 2,
Molecular formula Structural formula
CH3COOH
Carboxylic acid
The general formula of carboxylic acid is CnH2n+1COOH
When C = 2,
Molecular formula Structural formula
CH3COOH
Carboxylic acid
The general formula of carboxylic acid is CnH2n+1COOH
When C = 2,
Molecular formula Structural formula
CH3COOH
Ethanoic acid
Carbon number Formula Name of compound
1
2
3
4
5
6
7
8
9
10
Do your practice sheet
Practice Questions
Draw the structures of:
a) Propanoic acid
b) Butanoic acid
c) Hexanoic acid
Preparation of Carboxylic acid
Preparation of Carboxylic acid
+2 +
+2 +
+2 +
Alkyl chain
Carboxyl
Insoluble in
Soluble in water
water
CH3COOH CH3COO- + H+
Chemical properties of Carboxylic acid
Carboxylic acid is a weak acid
So it has all properties of an acid
Note: Weak acid ionize partially in water to provide H+
CH3COOH CH3COO- + H+
Sign for
weak acid
Video
Chemical properties of Carboxylic acid
Carboxylic acid
Chemical
Reactions
Carboxylic acid
Chemical
Reactions
Carboxylic acid
Chemical
Reactions
Isomerism
Carbon
compounds
Isomerism
Esters
Ester
• Has COO
Ester
• Has COO
Functional groups
- Atoms responsible for the for the chemical
properties
Ester group
(Carboxylate group)
Preparation of Ester (Esterification)
Preparation of Ester
+ +
+ +
+ +
Practice problems
Determine the word equation for the following reactions:
1. Ethanol + Butanoic acid
2. Butanol + Ethanoic acid
3. Methanoic acid + Propanol
4. Pentanol + Ethanoic acid
5. Butanoic acid + Butanol
Preparation of Ester (Esterification)
Let’s look at how to draw ester
Ethylpropanoate
Propanoate Ethyl
Ethylpropanoate
Practice problems
Determine the word equation for the following reactions:
1. Ethanol + Butanoic acid Ethylbutanoate + water
2. Butanol + Ethanoic acid Butylethanoate + water
3. Methanoic acid + Propanol Propylmethanoate + water
4. Pentanol + Ethanoic acid Pentylethanoate + water
5. Butanoic acid + Butanol Butylbutanoate + water
Writing chemical equation of Esterification
World
equation
Structural
formula
Molecular
formula
Writing chemical equation of Esterification
H2SO4
World Ethanol + Butanoic acid Ethylbutanoate + water
equation
Structural
formula
Molecular
formula
Writing chemical equation of Esterification
H2SO4
World Ethanol + Butanoic acid Ethylbutanoate + water
equation
Structural H2SO4
+ +
formula
Molecular
formula
Writing chemical equation of Esterification
H2SO4
World Ethanol + Butanoic acid Ethylbutanoate + water
equation
Structural H2SO4
+ +
formula
H2SO4
Molecular
formula C2H5OH + C3H7COOH C3H7COOC2H5 + H2 O
H2SO4
Writing chemical equation of Esterification
H2SO4
World Ethanol + Butanoic acid Ethylbutanoate + water
equation
Structural H2SO4
+ +
formula
H2SO4
Molecular
formula C2H5OH + C3H7COOH C3H7COOC2H5 + H2 O
H2SO4
Esters are sweet smelling
Isomerism