Professional Documents
Culture Documents
By
Insp/Exe P.Jagadish Chandra
Case Study : Bhopal Gas Tragedy
Structure of the Presentation
Structure of the Presentation
Industrial scenario in developing countries and double
standards of transnational companies
Bhopal Gas Tragedy
Union Carbide Corporation
Equipment and Safety Regulations/Norms
UCC Approach – Key Problems
Safety Measures in UCC plants - the USA and India
Legal Action Against Union Carbide
Conclusion
Lessons Learnt
Double Standards of Transnational Companies
Initially in quiet
suburb
The cases are still pending in the district court of United States, and also
in the District Court of Bhopal, India, on the employees, including
Warren Anderson who was CEO of UCC at the time of the disaster.
Seven ex-employees, including the former UCIL chairman, were
convicted in Bhopal of causing death by negligence and sentenced to
two years imprisonment and a fine of about $2,000 each, the
maximum punishment allowed by law in June 2010.
One former employee who was also convicted died before judgment was
passed.
UCC Approach – Key Problems
The various problems in the plant that were ignored:
The alarms of MIC tank had not worked since past four years
Only single manual back-up system as compared to USA where four-
stage system was used
The flare tower and the vent gas scrubber had been out of service for
five months before the disaster due to which flare tower could only hold
a quarter of the gas that leaked during the incidence
The refrigeration system was idle and the MIC was kept at 20 degrees
Celsius, not the 4.5 degrees as suggested by the manual
Due to absence of Slip-bound plates, the water leaked into the MIC
tanks from pipes being cleaned
Faulty valves were not installed by the operators
the MIC tank pressure gauge was not functioning properly for roughly a
week before the accident.
On the night shift, no maintenance supervisor was in place to record
instrument readings.
Legal Action Against Union Carbide
Dec 1984
Thank You
The Sevin Process
Chlorine (Cl2)
Alpha-Napthol (AN) }
made on site
Process route
CO + Cl2 COCl2 (Phosgene)
COCl2 + MMA MMC + MIC
MIC stored in three 15,000 gal tanks
MIC + AN SEVIN
Process
Plant used to produce a pesticide ‘SEVIN’.
This plant was to cater the demand of not only
India but also of East Asia.
The principal ingredients required for the
Production are alpha-napthol and methyl
isocyanate (MIC)
Company was manufacturing MIC at site
while alpha napthol was being imported.
THE WEATHER EGGED ON THE
PROCESS…
• The high moisture content (aerosol) in the discharge when
evaporating, gave rise to a heavy gas which rapidly sank
to the ground.
• A weak wind which frequently changed direction, which
in turn helped the gas to cover more area in a shorter
period of time (about one hour).
• The weak wind and the weak vertical turbulence caused a
slow dilution of gas and thus allowed the poisonous gas to
spread over considerable distances.
THE POSSIBLE REASONS…
• One of the main reasons for the tragedy was found
to be a result of a combination of human factors
and an incorrectly designed safety system.
• Conclusive reports indicated that 2000 lbs of water entered the tank and for this
water to build up and have an instantaneous exothermic reaction would not be
possible
THE DIRECT-ENTRY THEORY
• During the shift change -- that a disgruntled operator entered the storage
area and hooked up one of the readily available rubber water hoses to
Tank with the intention of contaminating and spoiling the tank's contents.
• The water and MIC reaction initiated the formation of carbon dioxide
which, together with MIC vapours, was carried through the header system
and out of the stack of the vent gas scrubber by about 11:30 to 11:45 p.m
Equipment and safety regulations
Unlike Union Carbide plants in the USA, its Indian subsidiary plants were
not prepared for problems.
No action plans had been established to cope with incidents of this
magnitude. This included not informing local authorities of the quantities or
dangers of chemicals used and manufactured at Bhopal.
The MIC tank alarms had not worked for 4 years.
The flare tower itself was improperly designed and could only hold one-
quarter of the volume of gas that was leaked in 1984.
To reduce energy costs, the refrigeration system, designed to inhibit the
volatilization of MIC, had been left idle—the MIC was kept at 20 degrees
Celsius , not the 4.5 degrees advised by the manual, and some of the coolant
was being used elsewhere.
The steam boiler, intended to clean the pipes, was out of action for
unknown reasons.
Slip-blind plates that would have prevented water from pipes being
cleaned from leaking into the MIC tanks through faulty valves were
not installed. Their installation had been omitted from the cleaning
checklist.
The MIC tank had been malfunctioning for roughly a week.
Carbon steel valves were used at the factory, even though they
corrode when exposed to acid.
On the night of the disaster, a leaking carbon steel valve was found,
allowing water to enter the MIC tanks. The pipe was not repaired
because it was believed it would take too much time and be too
expensive.
In November 1984, most of the safety systems were not
functioning. Many valves and lines were in poor condition. Tank
610 contained 42 tonnes MIC, much more than safety rules
allowed.
During the nights of 2–3 December, a large amount of water
entered tank 610.
A runaway reaction started, which was accelerated by
contaminants, high temperatures and other factors.
The reaction generated a major increase in the temperature
inside the tank to over 200°C .
This forced the emergency venting of pressure from the MIC
holding tank, releasing a large volume of toxic gases. The
reaction was sped up by the presence of iron from corroding
non-stainless steel pipelines.
It is known that workers cleaned pipelines with water. They
were not told by the supervisor to add a slip-blind water isolation
plate. Because of this, and of the bad maintenance, the workers
consider it possible for water to have accidentally entered the
MIC tank.
UCC maintains that a "disgruntled worker" deliberately
connected a hose to a pressure gauge.
UCC's investigation team found no evidence of the suggested
connection.[
VIEW OF TOP OF MIC STORAGE TANKS
MIC Storage Tank
STORAGE FACILITY
The tank farm at the Bhopal site had facilities for storage
of the following hazardous & toxic substances.
- Carbon monoxide CO
- Methyl iso-cyante MIC
- Chlorine Cl2
- Phosgene COCl2
amine (CH NH ) to form MIC.2 Finally, MIC is mixed with
3 2
to produce carbaryl.
naphthol
MIC is moderately solu-ble in water, and hydrolyzes to form
carbon dioxide and methylamine.
When MIC is pyrolyzed between 427 ° C and 548 °C, it
3
decomposes to hydrogen cyanide and carbon dioxide.
MIC irritates the skin, eyes, and respi-ratory mucus membranes.
It reacts with water to pene-trate tissues, including skin4; interacts
with protein; and
Introduction of water into a methyl isocyanate (MIC [CH –
3
N=C=O]) storage tank re-sulted in an uncontrollable reaction, with
liberation of heat and MIC gas.
Safety systems—such as a flare tower (for the burning of excess
gas), a caustic soda scrubber (for neutralization), and a refrigeration
1
unit—did not contain the reaction.
MIC is an intermediate product in the manufacture of carbaryl
(Sevin ), a carbamate pes-ticide.
As is shown in Table 1, a mixture of carbon monoxide (CO) and
chlorine (Cl2) forms phosgene (COCl2). Phosgene is then combined
with monomethyl-
cluded several toxic decomposition byproducts such as hydrogen
cyanide, nitrogen oxides, and carbon monox-ide. Contaminants such
as phosgene and monomethyl-amine, which were used in the
manufacture of MIC, might also have been present in the cloud.
Air monitor-ing was not possible at the time of the incident, nor was
it attempted subsequently.
The estimated mean MIC concentration in the cloud was 27 ppm—
1,400 times the U.S. Occupational Safety and Health Administra-
tion’s (OSHA) workplace standard (Table 3).
Properties of MIC
High production of MIC matched with high processing capacity. MIC not High production capacity of MIC but low processing capacity. MIC stored
stored for long periods of time. in large quantities for long periods of time.
MIC storage tank equipped with emergency scrubbers (to neutralize any No emergency caustic scrubber to neutralize any MIC leak.
escaping MIC) designed to operate under emergency conditions.
Computerized monitoring of instruments (gauges, alarms, etc) and No computerized monitoring of instruments and processes. Relied solely
processes to support visual observation. on manual observation.
MIC field storage tanks used a cooling system based on chloroform MIC tanks used a cooling system based on brine (highly reactive with
(inert and nonreactive with MIC). MIC).
Refrigeration unit to control temperature in the tanks was never turned Refrigeration unit had been turned off since June 1984.
off.
MIC was always maintained under nitrogen pressure. MIC tanks had not been under nitrogen pressure since October 1984.
Safety Measures in UCC plants - the USA and India
Institute, West Virginia, USA Bhopal, Madhya Pradesh, India
Emergency plan An elaborate four-stage emergency plan to deal with toxic No system to inform public authorities or the people living
releases, fires, etc, including a general public alert linked to adjacent to the plant. No emergency plan shared with
community police, river and rail traffic and local radio communities living adjacent to the plant; no system to
stations. Various emergency broadcast systems in place to disseminate information regarding emergency to the public
alert and disseminate appropriate information to the public. with the exception of a loud siren.
Maintenance programme A maintenance programme to determine and evaluate No evidence of an effective instrument maintenance
replacement frequency for valves and instrumentation and programme. Safety valve testing programme largely
alarm systems. Weekly review of safety valves and reviews ineffective and no proper records maintained of reviews of
and maintenance recorded extensively. instruments, valves and alarm systems, etc.
Lab analysis A lab analysis of MIC was conducted to test quality and check No lab analysis of quality was undertaken. MIC stored for
for contamination prior to storage, processing or distribution. long periods without testing for contamination.
Training Extensive employee training programme to ensure high level Operators put in charge without sufficient training.
of training and information among all employees of normal
and emergency procedures.
Protective equipment Extensive provision of appropriate personal protective Personal protective gear and breathing air equipment not
equipment to employees including protective clothing, air easily accessible, inadequate and of poor quality.
respirators, etc.
Lessons Learnt
• National governments and international agencies should focus on
widely applicable techniques for corporate responsibility and accident
prevention as much in the developing world context as in advanced
industrial nations .
• Local governments clearly cannot allow industrial facilities to be
situated within urban areas, regardless of the evolution of land use
over time.
• Industry and government need to bring proper financial support to
local communities so they can provide medical and other necessary
services to reduce morbidity, mortality and material loss in the case of
industrial accidents.
• Existing public health infrastructure needs to be taken into account
when hazardous industries choose sites for manufacturing plants.
Lessons Learnt
• Legislation and regulation needs to evolve in active
consultation with all stakeholders laying emphasis on
emerging requirements, and increasing standards with
appropriate emphasis on actual functioning of safety
mechanisms and inculcation of an active safety culture.
THANK YOU