Total RR Solution Program Training

Training on
Total RR Solution Program

Oh-Taek Son,
Application Engineer APAC, CIH
18 Mar 2018
© 3M 2018. 3M Confidential. #3MScienceofSafety | 1

Total RR Solution
RR Product Cleaning and

Risk Service Life Training and
Selection: FF Storage: Maintenance:
Assessment: Estimation: Fit Testing:
or HF with disinfection product
detection or software based QLFT or
filter or guideline and consumables
monitors or ESLI QNFT
cartridges shelf life

Badge Monitor
3M Organic Vapor Monitors (3500, 3510, 3520, 3530) may be used to sample many organic
(solvent) vapors such as benzene, toluene, xylene, etc. Also available are 3M Formaldehyde
Monitors (3720, 3721) and 3M Ethylene Oxide Monitors (3550, 3551). 3M monitors are small,
lightweight and easy to use (no pump to charge or calibrate). They are accurate to with +/-25% for
many contaminants, exposure levels and sampling times. However, they are not for sampling
particles or certain gases or vapors.
Reference: 3M TDB 245

Badge Monitor
Reference: 3M TDB OV monitors

Prepaid analysis can choose 3 chemicals listed whereas 3rd party has no limit.

Oil 95% 99% 99.97%
Particulate Filters N N95 N99 N100
R R95 R99 R100
P P95 P99 P100
N-Series: These filters are restricted to use in those atmospheres free of oil aerosols.
N95 Particulate Filter- At least 95% filter efficient when tested with ~0.3 μm NaCl aerosol.
N100 Particulate Filter- At least 99.97% filter efficient when tested with ~0.3 μm NaCl aerosol.
R-Series: If the atmosphere contains oil, the R-series filter should be used only for a single shift (or for 8 hours of continuous or intermittent use).
R95 Particulate Filter- At least 95% filter efficient when tested with ~0.3 μm DOP (Dioctyl Phthalate) aerosol.
P-Series: 3M recommends that in atmospheres containing oil aerosols, P-series filters should be used and reused for no more than 40 hours of use or 30 days,
whichever occurs first.
P95 Particulate Filter- At least 95% filter efficient when tested with ~0.3 μm DOP (Dioctyl Phthalate) aerosol.
P100 Particulate Filter- At least 99.97% filter efficient when tested with ~0.3 μm DOP (Dioctyl Phthalate) aerosol.
Where oil is suspected, but air samples have not been taken to determine its presence, an R- or P- series filter should be selected.
Only if a P-series filter is used in an environment that contains only oil aerosols does the full time use limitation apply.
Reference: 3M Respirator Selection Guide, TDB 137 Understanding P-Series Particulate Filters, TDB 129 Selection Guide for 42 CFR 84 Filters

Particulate Filters for Special Cases
Filter Type Contaminant Comment
Coal tar pitch volatiles (as Benzene solubles) 65996-93-2 Respirators with nuisance level organic vapor or acid gas relief, F
Coke oven emissions 65996-93-2 Respirators with nuisance level organic vapor or acid gas relief, F
Glycerin mist 56-81-5 N/A
R95, P95
Mineral oil (pure, highly and severely refined), excluding metal
Due to uncertainty about additives and contaminants1
working fluids 8012-95-1
Vegetable oil N/A
Arsenic, elemental 7440-38-2 N/A
Asbestos 1332-21-4 Dual cartridge as per 29 CFR 1910.1001, 1915.1001 and 1926.1101
N100
Cadmium and compounds (as Cd) 7440-43-9 N/A
Lead, elemental and inorganic compounds (as Pb) 7439-92-1 N/A
5X PEL maximum for disposables, per OSHA cotton dust standard. If oil aerosol
Cotton dust, raw
present, use R or P95.
N95
This category includes many materials. For oils, an R or P95 filter/respirator is
Particulates Not Otherwise Regulated
recommended.
This information is not an exhaust listing of contaminants that specific filter grade is designated.
There is no guideline on the P100 use
Cr VI, Mn, and Si crystalline – N95
Reference: 3M Respirator Selection Guide, 1 3M Matalworking slide deck by Joe Hockett

Chemical Cartridges
Selection Guide Brochure Technical Document
AG: Acid Gas

AM: Ammonia/ Methylamine
FORM: Formaldehyde
HF: Hydrogen Fluoride
Hg: Mercury Vapor or Chlorine Gas
MG: Multi Gas and Vapor
** Reminder: These cartridges are approved for respiratory protection from
OV: Organic Vapor hydrogen sulfide gas up to 10 times the permissible exposure limit (PEL) with
half facepiece respirators and full facepiece respirators when qualitatively fit
tested, or up to less than 300 parts per million (ppm) with full facepiece
OZ: Ozone – 3M 2078, 2097, 2297 respirators when quantitatively fit tested or according to specific OSHA
standards or applicable government regulations, whichever is lower. 300 ppm is
the concentration considered Immediately Dangerous to Life or Health (IDLH)
for hydrogen sulfide.
Reference: 3M Respirator Selection Guide, 3M RR Brochure, FF-400 TDS

Chemical Cartridges
Pre-conditioning
3 as received
2 equilibrated at 25%, 25 lpm, 6 hrs
2 equilibrated at 85%, 25 lpm, 6 hrs
Test condition: 50%, 25⁰C
Special gases: ClO2, H2S, HF, HCHO, Hg,

CO, CN (Chloroacetophenone), EO, HCN,
Phosphine, NO2, CS (Chlorobenzylidene
Malononitrile)
Test protocols are prepared by NIOSH.
Reference: 42 CFR 84, NIOSH website https://www.cdc.gov/niosh/npptl/stps/apresp.html

Respirator Selection Guide
Reference: 3M Respirator Selection Guide

Respiratory Protection Program by 29 CFR 1910.134
1910.134(c)(1)(i) Procedures for selecting respirators for use in the workplace;

1910.134(c)(1)(ii) Medical evaluations of employees required to use respirators;
1910.134(c)(1)(iii) Fit testing procedures for tight-fitting respirators;
1910.134(c)(1)(iv) Procedures for proper use of respirators in routine and reasonably foreseeable emergency situations;
1910.134(c)(1)(v) Procedures and schedules for cleaning, disinfecting, storing, inspecting, repairing, discarding, and otherwise maintaining respirators;
1910.134(c)(1)(vi) Procedures to ensure adequate air quality, quantity, and flow of breathing air for atmosphere-supplying respirators;
1910.134(c)(1)(vii) Training of employees in the respiratory hazards to which they are potentially exposed during routine and emergency situations;
1910.134(c)(1)(viii) Training of employees in the proper use of respirators, including putting on and removing them, any limitations on their use, and their maintenance;
1910.134(c)(1)(ix) Procedures for regularly evaluating the effectiveness of the program.
Reference: 29 CFR 1910.134

IDLH Levels
• This is the concentration considered Immediately Dangerous to Life or Health (IDLH), as published by the National Institute for Occupational Safety and
Health (NIOSH) (DHHS [NIOSH] Publication No. 90-117).
• The lower explosive level (LEL) has been listed when an IDLH value was not located.
• The concentration that would result in an oxygen deficient atmosphere should also be considered to be IDLH.

OEL
• The occupational exposure limits listed are 2015 ACGIH Threshold Limit Values (TLVs), unless otherwise stated.
• The concentrations are expressed in ppm — parts per million (parts of contaminant per million parts of air) — unless specifically stated as mg/m3
(milligrams of contaminant per cubic meter of air) or some other unit.
• The OSHA Permissible Exposure Limit (PEL) is listed when it is more stringent than the current TLV.
• The 2010 Workplace Environmental Exposure Levels (WEEL) from the American Industrial Hygiene Association is listed when it is the most stringent
value or there is no TLV or PEL
• Time Weighted Average (TWA) exposure limits are for a normal eight (8) hour workday and a forty (40) hour work-week.
• Short-Term Exposure Limit (STEL) is a 15-minute time weighted average exposure which should not be exceeded at any time during a workday. Exposure
above TWA and up to the STEL should be less than 15 min, no more than 4 times a day, and at least 60 min interval.
• Ceiling (C) exposure limits refer to concentrations that should not be exceeded during any part of the working exposure.
• Exposure limits for particulates are as total dust unless otherwise noted (e.g., inhalable fraction, respirable fraction, respirable fibers, etc.)
• Skin notations indicate the substance can be absorbed through the skin. In these cases, appropriate measures must be taken to prevent skin and eye contact
to avoid invalidating the OEL.
Reference: 3M Respirator Selection Guide, 2016 TLVs and BEIs by ACGIH

Respirator Recommendations
• In some cases, the respirator is preceded by an “(F)” designation. This means full facepiece respirators. For concentrations not exceeding ten times (10X)
the OEL, half facepiece respirators (maintenance-free or reusable) with equivalent filters or cartridges may be suitable if appropriate eye protection is
provided.
Reference: 3M Respirator Selection Guide, TDB 175 Assigned Protection Factors (APF) for 3M™ Hoods and Helmets

Comments
• A: Short service life means predicted cartridge life of less than 30 minutes at concentrations of ten times (10X) the OEL, or the contaminant’s boiling point
is less than 65C.
• Sometimes, a supplied air respirator is recommended because the service life may be so short that the frequency required for changing the cartridges may
not be practical.
• References to Ineffective sorbents or Unknown sorbent effectiveness indicate 3M does not make chemical cartridge respirators appropriate for these
substances at this time or it is not known how effective the sorbents would be for these materials.
• D: These compounds have been identified as possibly existing in both particulate and vapor phase in the workplace. For these compounds, 3M
recommends that a gas/vapor cartridge be used in addition to the traditionally accepted particulate filter.
• E: These compounds have been identified as possibly existing in both vapor and particulate phase in the workplace. Even though these chemicals would be
expected to be in the vapor phase, when other aerosols are present or there is high humidity, it is possible that the vapor may be adsorbed onto these
coexisting particles or dissolved in available water droplets; therefore, 3M recommends a filter for the particulate phase be used in addition to the
traditionally accepted chemical cartridge.
• F: It is believed that an N-series filter is sufficient since these materials will not coat the filter fibers, but since this material may contain oil aerosols, an R-
or P-series filter is recommended until further research or a regulatory agency takes a specific position.
• H: Listing of 3M 3510, 3530, 3550, or 3720 refers to a 3M™ Personal Air Monitor which may be used to measure the amount of contaminant in the air.



Respirator Selection Guide - Exceptions
• TDB 146: 60928 for Radioiodine, Methyl Iodide (74-88-4, CH3131I) with TWA 2ppm, up to 5 ppm for 8 hours, or (F)SA
• TDB 146: 60928 for Methyl Bromide (74-83-9, CH3Br) with TWA 1ppm, up to 5 ppm for 8 hours, or (F)SA
• TDB 185: 6002/3/6 for Peracetic Acid (79-21-0) and Acetic Acid (64-19-7), or (F)OV/AG; Peracetic at least 8hrs and Acetic SLS available.
• TDB 185: 6001/3/5/6 for Hydrogen Peroxide, (7722-84-1, H2O2) with TWA 1 ppm, up to 10 or 50 ppm for 8 hours , or (F)OV
• TDB 186: 6001/3/6 for Isoflurane and Sevoflurane - anesthetic gases
• TDB 203: 6006 for Cyanogen (460-19-5) with TWA 10 ppm, or MG with SLS available
• TDB 212: 6009S for Phosphine (7803-51-2) with TWA 0.3 ppm, or SA
• TDB 220: 60921 for Isocyanates, MDI (101-68-8), TDI (91-08-7, 584-84-9), and HDI (822-06-0) with TWA 0.005 ppm, or OV/N95 with SLS available –
very long SLS
Reference: 3M Respirator Selection Guide, TDB 146, TDB 185, TDB 186, TDB 203, TDB 212, TDB 220

Service Life http://extra8.3m.com/SLSWeb/home.html?region=AMERICA&reglId=20&langCode=EN&countryName=United%20States
• TDB 118: Selection of 42 CFR 84 approved particulate filters - NIOSH user’s guide
• N-Series: In dirty workplaces (high aerosol concentrations), NIOSH recommends service time should only be extended beyond 8 hours of either
continuous or intermittent use by performing a workplace evaluation - that the total mass loading of the filter(s) is less than 200 mg. For a dual filter
respirator this is 100 mg/filter. To make these estimates the level of contaminant needs to be known along with an estimate of the workers breathing rates.
For example, a moderate breathing rate has been considered to be 10 m3 in an 8 hour day. At a level of 0.5 mg/m3 and a 10 m3/8 hr day breathing rate, a
respirator would load with approximately 5 mg/day.
• R-Series: NIOSH states the R-series filter has no specific service time when oil aerosols are not present and should be used only for a single shift (8 hours
of continuous or intermittent use) when oil is present.
• P-Series: Use and reuse of P-series filters is subject only to considerations for hygiene, damage, and breathing resistance.
Reference: TDB 118, Service Life Software Help

• TDB 142: Reuse of Organic vapor chemical cartridges – OV cartridge running clock method
• Migration is mainly a concern for organic vapors, and less so for acid gases, ammonia, methylamine and formaldehyde. Organic vapors can migrate
through an organic vapor cartridge during periods of non-use.
• For organic vapors with a boiling point less than 65°C, OSHA states that organic vapor cartridges must be changed at least every work shift unless the
employer has data regarding contaminant migration – Benzene.
• In general, activated carbon in organic vapor cartridges adsorbs organic vapors with; Molecular weight > 50, Vapor pressure < 10 mm Hg at 25°C, and Not
for chemicals with vapor pressure > 100 mm Hg at 25°C
• An easier solution may be a “running clock”. In other words, the estimated service life starts when the cartridge is first used and continues whether the
cartridge is being used or stored. For example, if the estimated service life is 40 hours, then the organic vapor cartridge may be used for 8 hours, stored 16
hours and used for 8 hours (total time 30 hours) before being discarded.
Reference: TDB 142, Service Life Software Help

CAS Number is the best way of searching.

Exposure should be less than APF multiplied by OEL.
Multiple chemicals could be added up together.
Reference: Service Life Software Help

Select a cartridge and put conditions.

The uncertainty in the service life estimate made by this software
may be as much as ± 50%. Accurate input data from the user is
essential. Appropriate safety factors should be used to account for
any sources of uncertainty.
Humidity and Temperature sensitive SL for OV.
Specific regulation around Benzene is mentioned.

SA is recommended by short service life restriction.

Warning on the more then 8 hours SL.

Migration needs to be considered.
5168 hours by 6006 MG

Sulfur dioxide can be used as a surrogate to provide a

conservative service life estimate for hydrogen chloride,
hydrogen fluoride, hydrogen sulfide, chlorine or chlorine
dioxide.
No effect by temperature and humidity to SL

Chemical adsorption is not affected by the humidity and

temperature.
Select the most appropriate work rate for your work
environment from those listed. Light, medium and heavy
are defined as 20, 40 or 60 liters per minute, respectively.


temperature.
89 min by 6006 MG cartridge


temperature.
477 hours by 6002 AG cartridge

Service Life - Mixtures
• Short Service Life for Low Exposure Levels: Volatile organic vapors (eg. acetone, isopropanol) will move through the cartridge quickly, regardless
of exposure concentration. If exposure << OEL, may wish to remove them from service life calculation as they will give very short service life
estimate
• Example: 2 ppm acetone vs. OEL of 250 ppm, 2 ppm acetone may come through cartridge before other organic vapors, but is not hazardous
amount, so remove it from service life calculation
• Cartridge change schedule if my exposures are all less than the occupational exposure limits (OELs)?
• Calculate hazard ratio for each contaminant –Exposure level / OEL Toluene: 5 ppm / 20 ppm = 0.25 –For mixtures, sum the hazard ratios 0.25 +
0.1 +… –If hazard ratio < 1 then may not need a respirator or cartridge change schedule… –If hazard ratio > 1 then must determine cartridge
change schedule
• Gas/vapor exposures not hazardous (hazard ratio < 1)
• US OSHA: voluntary use of respirators –change schedules Not required per 29 CFR 1910.134(c)(2
Reference: Service Life Software Help, Developing Respirator Cartridge Change Schedules AIHA Webinar - March 10, 2015 by Erik Johnson

Assigned Protection Factor
Half Facepiece Respirators = 10 APF
Full Facepiece Respirators = 50 APF, if QNFT passed
APF 10 = 10X reduction inside respirator

Outside Inside
Respirator Respirator
Concentration Concentration
Reference: TDB 175

Assigned Protection Factor
• Workplace Protection Factor (WPF): Real measurement of protection factors during work shift in the actual workplace
• Nominal Protection Factor (NPF): NPFs are calculated from the maximum permitted total inward leakage (TIL) values specified in the appropriate CEN
standards. Example: EN149 FF P3 max TIL = 2%, NPF = 50
• Simulated Workplace Protection Factor (SWPF): Sampling is performed while the user performs a series of set exercises representative of the workplace –
required for APF 1000 of loose fitting headtops.
• Effective Protection Factor (EPF): EPF* is calculated using leak rate, wear time, and non-wear time. A higher EPF means the worker is better protected.
Reference: TDB 175

Fit Test
PortaCount Qualitative PortaCount

Filtering Facepiece Yes1 Yes Filtering Facepiece 100 (25*)
Half Mask Yes Yes Half Mask 100
Full Face Mask Yes OSHA: Yes, HSE: No Full Face Mask OSHA: 500, HSE: 2000
1
N95 companion may be required * HSE: If used without a N95 companion
Reference: TDB 165, TDB 228, TDB 241

Respiratory Protection Program
• Written worksite-specific procedures for:
• Respirator selection – Selection guide
• Medical evaluations - Doctors
• Use of respirators – User instruction, TDS, or Youtube
• Maintenance and care – User instruction, TDS, or Youtube
• Assuring adequate air quality – SAR only
• Training and fit testing – UI and Fit test kits Q: Who can conduct medical evaluations related to fit testing? The evaluation must be
performed by a physician or other licensed health care professional (PLHCP), per OSHA
• Program evaluations – Employer 29 CFR 1910.134. This may include a variety of health care professionals, depending on
the scope of practice permitted by each state’s licensure.
• Requires a program administrator
Reference: TDB 228, 3M administrative respiratory protection program

Inspection
FF-400 6500
Reference: User Instruction

Cleaning in Special Application

Seal Check FF-400
6500

Fit Testing

3M™ Ultimate FX Full Facepiece Reusable Respirator
Reference: 3M Official Website



Reference: YouTube

3M™ Full Facepiece Reusable Respirator 6800



Reference: YouTube

3M™ Half Facepiece Reusable Respirator 7502



Reference: YouTube

3M™ Rugged Comfort Quick Latch Half Facepiece
Reusable Respirator 6502QL


Reference: YouTube




Reference: YouTube

s
Questions

Question
BASF has a workplace where they handle MEK (ambient concentration of 300 ppm) and HCl (5 ppm) with 85% humidity and 40˚C temperature. Let’s assume
the worker is doing a hard job with 60 lpm air consumption. Select an economic solution to this key account with a proper cartridge change cycle. This job is
only for 30 min a day though.
• Face protection consideration (10 pt)

• Service life estimation with running clock (25 pt)
• O2 estimation of HCl (25 pt)
• APF consideration (20 pt)
• Right input of temp, hum, and breathing rate (20 pt)

Question
Grain storage area is planning fumigation and Aluminum Phosphide is the fumigant to be used. During the process, to ensure the fumigation is over and
phosphine is extinguished, some people need to enter the workplace and measure the concentration. The concentration expected is up to 50 ppm and the job is
less than 15 min. However the storage area is in total 4 sites and he need to do this job for 5 days. Select the most favorable solution if the employer has
concern on budget. Set up the service life.
• Particulte filter (10 pt)

• Right cartridge selection (10 pt)
• Full facepiece with APF and STEL approach (30 pt)
• 1 hour interval consideration with 4 times limit (10 pt)
• Service life setup with TDB data (40 pt) – 300 ppm approach 20 pt and intermittent approach 40 pt

Question
HF 5 ppm TWA was measured in Al smelting area. This area is very hot with 50˚C temperature and 90% humidity. This area also has some metal particles
flying around but the concentration is less than 10 times OEL. Suggest right solution for this customer with service life estimation. Consider about a price
competitive solution.
• Face protection consideration (10 pt)

• Half facepiece (10 pt)
• APF mentioning (10 pt)
• Particulate filter selection (10 pt)
• Service life estimation (60 pt)

Question
Lead acid battery manufacturer has a huge concern on the workers’ health as they need to measure blood concentration of Lead periodically. This time 3M
would like to approach with good RR solution at 0.2 mg/m3 concentration workshop. Select a good respirator for general workers. If customer ask a service life
of the filters then how can you answer?
• N100 selection (20 pt)

• Daily intake of lead calculation (20 pt)
• Filter loading estimation and loading limit 200 mg apply (50 pt)

Question
Formaldehyde handling worker needs a respirator and also fit test by his company policy. The HCHO concentration of his workshop is 3 ppm with 40˚C
temperature and 85% humidity. Suggest the most acceptable respiratory solution to cost sensitive customers. (Assume that the ceiling limit of HCHO is 3 ppm
even it is written as 0.3 ppm on the selection guide)
• Full pacepiece (10 pt)

• Understanding STEL and TWA concept (10 pt)
• Service life estimation (60 pt)

s
Thank you

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Training on

Total RR Solution Program

© 3M 2018. 3M Confidential. #3MScienceofSafety | 1

RR Product Cleaning and

© 3M 2018. 3M Confidential. #3MScienceofSafety | 2

Reference: 3M TDB 245

© 3M 2018. 3M Confidential. #3MScienceofSafety | 3

Reference: 3M TDB OV monitors

© 3M 2018. 3M Confidential. #3MScienceofSafety | 4

© 3M 2018. 3M Confidential. #3MScienceofSafety | 5

© 3M 2018. 3M Confidential. #3MScienceofSafety | 6

AG: Acid Gas

Reference: 3M Respirator Selection Guide, 3M RR Brochure, FF-400 TDS

© 3M 2018. 3M Confidential. #3MScienceofSafety | 7

Special gases: ClO2, H2S, HF, HCHO, Hg,

Reference: 42 CFR 84, NIOSH website https://www.cdc.gov/niosh/npptl/stps/apresp.html

© 3M 2018. 3M Confidential. #3MScienceofSafety | 8

Reference: 3M Respirator Selection Guide

© 3M 2018. 3M Confidential. #3MScienceofSafety | 9

1910.134(c)(1)(i) Procedures for selecting respirators for use in the workplace;

Reference: 29 CFR 1910.134

© 3M 2018. 3M Confidential. #3MScienceofSafety | 10

Reference: 3M Respirator Selection Guide

© 3M 2018. 3M Confidential. #3MScienceofSafety | 11

Reference: 3M Respirator Selection Guide, 2016 TLVs and BEIs by ACGIH

© 3M 2018. 3M Confidential. #3MScienceofSafety | 12

© 3M 2018. 3M Confidential. #3MScienceofSafety | 13

Reference: 3M Respirator Selection Guide

© 3M 2018. 3M Confidential. #3MScienceofSafety | 14

Reference: 3M Respirator Selection Guide

© 3M 2018. 3M Confidential. #3MScienceofSafety | 15

Reference: 3M Respirator Selection Guide

© 3M 2018. 3M Confidential. #3MScienceofSafety | 16

© 3M 2018. 3M Confidential. #3MScienceofSafety | 17

Reference: TDB 118, Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 18

Reference: TDB 142, Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 19

CAS Number is the best way of searching.

Reference: Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 20

Select a cartridge and put conditions.

Reference: Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 21

SA is recommended by short service life restriction.

Reference: Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 22

Warning on the more then 8 hours SL.

Reference: Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 23

Sulfur dioxide can be used as a surrogate to provide a

Reference: Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 24

Chemical adsorption is not affected by the humidity and

Reference: Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 25

Chemical adsorption is not affected by the humidity and

Reference: Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 26

Chemical adsorption is not affected by the humidity and

Reference: Service Life Software Help

© 3M 2018. 3M Confidential. #3MScienceofSafety | 27

© 3M 2018. 3M Confidential. #3MScienceofSafety | 28