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Properties of Transition

Metals
Transition
Metals
incompletely filled d subshells

ions

-distinctive coloring
Zn, Cd, Hg
-paramagnetic compounds
-catalytic activity
-complex ions
and so we will focus on ….
- have a close-packed structure (CN=12)
- have relatively small atomic radii
General Physical - have strong metallic bonds
Properties - have higher densities, higher melting points &
boiling points, and higher heats of fusion &
vaporization
- electronegativity increases from left to right
Periodic - Ionization energy increases from left to right
Trends - atomic radius decreases from left to right
- electrons are added to the 3d orbitals
Electron - exceptions: Cr and Cu
Configurations - electrons are removed first from the 4s orbitals
and then from the 3d orbitals
Oxidation
States

- electronegativity increases from left


to right
- Ionization energy increases from left
to right
- atomic radius decreases from left to
right
Chemistry of Iron and
Copper
Iron
Copper (Cu)
(Fe)
6.2 % by mass ABUNDANCE 0.0068 % by mass
hematite (Fe2O3) SOURCE
FeO (black), chalcopyrite (CuFeS2)
siderite (FeCO3) &
FeSO 4.7H
magnetite O (green),
gray 3O4)
2 (Fe COLOR reddish-brown
FeCl2 (yellow), and
HCl,
FeS conc. Fe
(black), H22SO
O34, REACTIONS hot conc. H2SO4 &
conc. HNO3
(reddish-brown), conc.
Cu HNO3 CuO
2O (black),
FeCl3 (brownish COMPOUNDS (black), CuSO4 5H2O
black) (blue), & CuS (black)

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