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COOLING SYSTEMS
Cooling Towers
Corrosion leads to
• Leakage of Exchangers
• Unscheduled Shut Down
• Loss of Production
• High Equipment Replacement Cost.
Types of Corrosion
General Corrosion
• Less dangerous & uniform in nature .
Pitting Corrosion
• Most destructive
• Caused by Localized Deposition & Differential Oxygen cells.
• Tuberculation leads to pitting
Microbiological Induced Corrosion
• Leads to pitting
• Cause by mainly sulphate reducing bacteria
Types of Corrosion
Galvanized Corrosion
• It is caused due to the presence of dissimilar metals.
• When two dissimilar metals are in contact, more active metal
corrode first.
Stress Corrosion Cracking
• It occurs mostly in S.S. and some time in Copper Alloys and is
caused by high chloride, high temperature & pressure.
Erosion Corrosion
• High water velocity, High suspended solids, Turbulence
accelerates
Classification of Corrosion Inhibitors
Selection criteria
• Make up water parameter
• Cycle of concentration
• MOC of exchangers
• Water velocity in exchangers
• process parameters – Temperatures
• Environmental restrictions
Scaling
Anaerobic Bacteria
Takes place in absence of oxygen
Sulphate Reducing Bacteria
• Pitting type corrosion.
• Brown deposits on top. Under brown deposit black
deposit. Under black deposit, silvery shining surface.
SO4 H2S + Fe FeS
Different Types of Bacteria
Aerobic Bacteria
Takes place in presence of Oxygen
• Nitrifying Bacteria
Grows in presence of Ammonia / NO2 , leads to pH drop.
NH3 HNO3 , NO2 NO3
• Iron Bacteria
Oxidize ferrous to ferric iron which precipitate as brown slime.
• Slime Bacteria
Produces sticky gelatinous mass which traps the suspended
solids.
Microbiological Control
• Oxidizing biocide
Chlorine
Microbiological action of Chlorine :
Cl2 + H2O HOCl + HCl
HOCL is the active species and dissociates as pH increases
Bromine
Effective at high pH and in ammonia contaminated system
compare to chlorine.
HOCl + NaBr HOBr + NaCl
Microbiological Control
Ozone
• pH in sensitive
• Produced at site by electrolysis
Chlorine Dioxide
NaClO2 + 1/2 Cl2 ClO2 + NaCl