Professional Documents
Culture Documents
ELECTRO-CHLORINATION SYSTEM
Classroom Training in Tiejun Site
Contents
1
Safety Precautions
2 System Description
5 Main Equipment
6 Operation procedures
Corrosive
Irritant
High Pressure
Fire Hazard
Respiratory Mask
Goggles
As a protection against hazardous substances and strong
effects of light.
Prevention of eye injuries and blinding.
SAFETY PRECUATION
Safety Boots
As a protection against falling-down parts, sharp objects
and hazardous substances.
Prevention of foot injuries.
Wear it unconditionally!
Face Protection
As a protection against hazardous substances and strong
effects of light.
Prevention of eye and face injuries and blinding.
Wear it unconditionally!
SAFETY PRECUATION
Listed below are the specific system precautions that shall be ensure that
personnel do not suffer any physical injury during operation
System Description
Desalination membranes are very sensitive, and pre-treatment filters out most of the
suspended matter and colloids occurring naturally in seawater, such as silt, algae,
bacteria, and plankton. Water quality is crucial for ensuring steady operation, long
membrane life and reduced cleaning requirements. An elaborate pre-treatment system
functions to remove the colloidal, particulate content in the feed sea water to ensure
feed is suitable for continuous reverse osmosis operation. However, the biological
content, that grows exponentially, and could potentially lead to blockages in the intake
pipeline and subsequent plant disruption, is treated with sporadic bursts of sodium
hypochlorite (shock dosing).
Company Logo
SYSTEM DESCRIPTION
System Description
Sea Water Booster Pumps
The sea water booster pumps 31QCJ10AP001/ 31QCJ20AP001 (one working and
one standby) ensures the desired seawater flow rate to the electro-chlorination
system.
System Description
Company Logo
SYSTEM DESCRIPTION
System Description
The seawater with generated Sodium hypochlorite, coming from the Bipolar
electrolyser flows to the Gas separator (31QCO75BB001) which allows
disengagement of hydrogen gas from the liquid phase at the upper part of the
separator. After separation, the liquid flows to the storage tank. The gas
separator is flushed by a continuous stream of air with the help of air blower
(31QFD61AN001, 31QFD62AN001) in order to keep the hydrogen content
inside the header, separator, and vent pipes at about 1% by volume.
Company Logo
SYSTEM DESCRIPTION
System Description
Electrical conversion Units
The Electrolyser system will have a Transformer Rectifier (T-R) Unit. The T-R
provides direct current to electrolyser, which helps to generate sodium
hypochlorite solution. Two independent Transformer Rectifiers are provided
one for each Sodium hypochlorite generator comprising of one bipolar
electrolyser. Each Transformer Rectifier is designed to relevant Sodium
Hypochlorite generator with DC current which can be continuously and
automatically controlled.
Company Logo
SYSTEM DESCRIPTION
System Description
The products generated by the side reaction during the electrolysis process get
accumulated on the electrodes. The fouling takes place due to the presence of
Calcium and Magnesium salts in seawater. The precipitation is periodically
removed by dissolving it in a solution of diluted hydrochloric acid. The cleaning
does not require any dismantling and done by circulating dilute Hydrochloric acid
through the Electrolyser. The acid cleaning system consists of an acid preparation
tank (31QCS55BB001) and acid circulation pump (31QCS50AP001,
31QCS60AP001).
Company Logo
PROCESS FLOW
CHEMICAL REACTION
Main Equipment's
Main equipment
SYSTEM START-UP
Electro chlorination is a fully automated process, which is initiated from the HMI. The
master routine handles the production request from the operator, checks the available
equipment and reports the feasible production target back to the operator. The operator
interacts with the master routine using the plant recipe, where the operator enters the
request, receives the plant feedback, and executes the basic commands.
According to the start-up, normal or shutdown procedure, the master gives the command for
the operation of the electro-chlorination system. The slave, electro-chlorination system,
reports back which units are in operation and the actual flow output.
OPERATION PROCEDURE
SYSTEM START-UP
To start the Hypochlorite dosing system, 2 minutes after the start of the SBS dosing
system. If the signal is 0 then the hypochlorite system will stop and after a delay
the SBS dosing will stop.
During the shock treatment, required MG/L of hypochlorite & dosing timer.
Company Logo
OPERATION PROCEDURE
Starting the electro-chlorination system is manual from the HMI, however, the
operator can change the process set values on the screens by dictating
parameters (such as the time between shock dosing, timers and set values of the
acid wash program). The normal operating mode of the electro chlorination is auto
mode.
The following sequences are involved in operation of the electro-chlorination
system:
1. On-off valve 31QCJ01AA121 opening – manual from the HMI by operator or
automatic by clock counter set point.
2. Start-up of sea water booster pump: 31QCJ10AP001 or 31QCJ20AP001.
3. Start-up of filters 31QCJ40AT001 or 31QCJ50AT001.
4. Start-up of hydrogen dilution blower 31QFD61AN001 or 31QFD21AN001.
5. Start-up of the working electrolyser: 31QCJ46BB001 or 31QCJ47BB001.
6. Start-up of hypochlorite dosing pumps: 31QCO25AP001 or 31QCO26AP001 or
31QCO27AP001.
OPERATION PROCEDURE
Permissive Startup
Permissive Startup
Sea water Booster Pumps
Once the operator starts the electro-chlorination system manual from HMI, they
shall also select the route and the equipment involved in the process.
The sea water booster pumps 31QCJ10AP001/ 31QCJ20AP001 starts
automatically once the following preconditions are met: 1.
1. The flow transmitter FIT-31GAF40CF001 is indicating the desired flow.
Permissive Startup
Electrolysers
After the first sequence when operator has chosen the involved equipment's, in
this case the working electrolyser: 31QCJ46BB001 or 31QCJ47BB001, the unit
starts automatically once the following preconditions are met:
1. Sea water booster pump is available & ready for operation.
2. Self-Cleaning filter is available & ready for operation.
3. Flow indicator and control (31QCJ45CF001)indicate the set value.
4. One of the hydrogen dilution blowers 31QFD61AN001 or 31QFD21AN001 is
available and ready for operation
5. The on-off valves (31QCJ46AA101 and 31QCJ46AA102) for the electrolyser
31QCJ46BB001 are opened:
6. The acid cleaning solution inlet valve 31QCS15AA102, outlet valve
31QCS57AA102 and the on off valve 31QCS56AA102 are closed position
when the electrolyser 31QCJ47BB001 is online. Similarly, the acid cleaning
solution inlet valve 31QCS15AA101, outlet valve 31QCS57AA101 and on-off
valve 31QCS56AA101 are closed position when the electrolyser
31QCJ46BB001 is used.
OPERATION PROCEDURE
Permissive Startup
7. On-off valve 31QCO15AA001 on the header from the separator
31QCO75BB001 and the sodium hypochlorite storage tank 31QCO15BB001 shall
be opened.
8. Level indicator LIT-31QCO15CL002/31QCO16CL002 from the sodium
hypochlorite storage tank is not indicating High (H or HH) levels in the tank.
Permissive Startup
Acid cleaning system
The acid cleaning starts automatically once the following preconditions are met:
1. Level Indicator (31QCS55CL001) from the Acid Tank (31QCS55BB001) indicate
the set value for normal operation. 2.
2. One of the acid recirculation pumps 31QCS50AP001 or 31QCS60AP001 is
available and ready for operation. 3.
3. The acid cleaning solution inlet valve 31QCS15AA102 and outlet valve
31QCS57AA102 are in open position and the on-off valve 31QCS56AA102 is in
closed position when the electrolyser 31QCJ47BB001 is in the washing
sequence. The on-off valves 31QCJ47AA101 and 31QCJ47AA102 shall be in
closed position. Similarly, the acid cleaning solution inlet valve 31QCS15AA101
and outlet valve 31QCS57AA101 are in open position and the on-off
valve31QCS56AA101 when the electrolyser 31QCJ46BB001 is in the washing
sequence and the on off valves 31QCJ46AA101 and 31QCJ46AA102 shall be
in closed position. When the washing sequence of the electrolyser is over the
on-off valves 31QCS56AA101 or 31QCS56AA102 will be opened in order to
direct the acid from the system to the neutralization pit.
OPERATION PROCEDURE
NORMAL OPERATION
Prior to the electro-chlorination system operation, the operator shall select the
route, to set the valves in the plant and to set the route in the HMI. Only after
meeting the required permissive, the seawater booster pump will start, and the
production of sodium hypochlorite will occur. The electro-chlorination system is
fully automated. The normal operating mode is auto mode.
The flow indicator and control (FIT-31QCJ45CF001) installed on the discharge line
of the sea water booster pump, keeps constant flowrate to the electrolyser
31QCJ46BB001 / 31QCJ47BB001 by adjusting the sea water booster pump
speed. The operating electrolyser is also chosen previously by the operator from
the HMI.
OPERATION PROCEDURE
NORMAL OPERATION
• The temperature in the electrolyser is kept under control with the aid of
temperature indication and control TT-31QCJ46CT001 respectively TT-
31QCJ47CT001 in order to limit the formation of the bromine and bromate salts.
• The sodium hypochlorite solution output from the electrolyser is fed into the
hydrogen de-gassing tank 31QCO75BB001 where the product is held for sufficient
time to allow the hydrogen to disperse from the hypochlorite.
Set Points
Set Points The hypo dosing skid will use mg/l to calculate the desired
dosing rate based on the strength of the solution & intake flow. Operator will
have option to set and adjust mg/l in the HMI. Tabulated below, are the
initial set points for the hypochlorite dosing skid. These values are
adjustable on HMI screen and can be changed by the operator as per the
requirement of the plant.
Company Logo
SHUTDOWN PROCEDURE
System Shutdown
Shock Chlorination is a timer based operation and shall be done once or twice a day
for 30 mints. Shut down can be executed automatic through interlock:
1. Booster Pump VFD & Flow transmitter (FIC-31QCJ45CF001) provided at the
inlet of the Electrolyzes unit will control the seawater flow rate. In case of low
flow, it will generate an alarm and stop the running electrolyzes
(31QCJ46BB001 / 31QCJ47BB001)
2. Electrolyzes (31QCJ46BB001 /31QCJ47BB001) outlet temperature High
Alarm (TT- 31QCJ46CT001 / TT-31QCJ47CT001 ) and Trip - and stop the
running electrolyzes.
3. Transformer rectifier Voltage and Current Alarms / Trip - stop the running
electrolyzes.
4. The storage tank 31QCO15BB001 is equipped with a level indicator
transmitter (LIT 31QCO15CL002/31QCO16CL002) that stops the dosing
pumps (31QCO25AP001 / 31QCO27AP001 / 31QCO25AP001) when the tank
level drops to the minimum level set point.
SHUTDOWN PROCEDURE
System Shutdown
7. A Low-Low level alarm at acid tank will automatically trip the running acid
circulation pump.
SHUTDOWN PROCEDURE
Auto-System Shutdown
The following trip conditions are incorporated towards automatic
shutdown of the system.
Filtered Seawater flow (31QCJ45CF001) insufficient.
High solution temperature (31QCJ46CT001, 31QCJ47CT001) at the outlet of
respective electrolyzes.
High voltage/ current in Transformer - Rectifier.
Loss of power, Transformer trip, Rectifier Failure
Hydrogen Dilution Blowers stop/fault.
Emergency Shutdown
Events that may lead to an unplanned total plant shutdown:
Total electrical power failure.
Emergency situation such as fire, flow, personnel safety, in which the E-stop
(emergency stop) button for total intake or total plant is pressed.
Critical process interlock occurs.
In a shutdown caused by power failure the following activities
take place:
The use of chlorination is contingent upon sea conditions and is at the plant
manager and operator’s discretion. Free chlorine can cause irreversible damage
to the RO membranes. It is imperative to ensure that the SBS dosing system is
ready for operation before performing theLogo
Company shock treatment procedure.
MAINTENANCE & PRECUATION
As the hydrogen will be generated in the electrolysis, the good ventilation in the
chlorination generation room should be kept in the operation of the generator, and
do not conduct fire working in the workshop.
Even strength should be used on valves opening and closing, especially for UPVC
plastic valve
The corresponding valves on the pipeline should be opened before starting the
pump to make sure the pipeline unblocked, and do not conduct anhydrous
operation. 。
If any vibration or abnormal noise happens in the process of pump operation, stop
the pump immediately for inspection, and work after fault removal
MAINTENANCE & PRECUATION
Sludge pumps at the bottom of tanks need to be opened regularly (at least
once a week) for sediment discharge, in case the sediments block the
pipeline and affect the normal working of the auto control instrument.
When an alarm signal appears during the operation of the device, the cause
shall be found out and the fault shall be cleared out.
When the chlorination generation devices are in seasonal outage, the liquid
within the exhaust equipment and pipeline should be drained
MAINTENANCE & PRECUATION
During the operation of the device, if the wiring terminals of the generator and the
joints of rectifier power electric elements suffer an over-high temperature rise
(above 60°C), the device should be stopped to check whether the terminal stud is
fastened or the contact surface is smooth;
If any leakage happens in the operation, the accurate leakage location should be
checked out. The leakage in the joint of flange can be solved through adjusting or
replacing the sheet gasket and screwing down the bolt with spanner; the leakage in
the union joint of UPVC can be stopped through adjusting or replacing the O-rings
on the sealing surface and screwing down the union joint; leakage in the bonding
joint of UPVC pipe fitting can be welded by PVC welding rod;
TROUBLE SHOOTIING
10 Low concentration in sodium Improper sampling time Take samples after the equipment stays
hypochlorite in stable operation for 20 minutes.
Low chloride concentration in sea
water
Check if the sea water pipeline is
The electrolytic bath is not filled with unblocked or the sea water flow rate is
sea water.
After the rectifier cabinet is normal.
11 closed, there is only voltage
and the current is zero. Turn the “OUTPUT ADJUSTMENT”
The “OUTPUT ADJUSTMENT” knob on
the rectifier cabinet is at zero. potentiometer knob on the rectifier
cabinet.