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Posgrado en Ciencias de la Energía

Universidad Autónoma de Querétaro Introduction


Ag
• Great electrical properties.
• Work function = 4.4 eV

MoO3 • Improves the stability of cells in air.


• Work function = 5.3 eV • Increases the life time.
• Band gap = 3.2 eV • Low surface roughness.

P3HT
Donor material • Relative stability and scalability.
• HOMO = 5.2 eV. PC61BM
• Absorption in the range between
• LUMO = 3.3 eV.
Acceptor material 300 and 650 nm.
• Band gap= 1.9 eV. • HOMO = 5.9 eV.
• Relative low cost
• LUMO = 3.9 eV.
• Band gap = 2 eV.

PFN
•Work function =4.2 eV
• High transmission over 300 nm.
TiO2 • Increase air stability.
• VB = 7.2 eV • Low surface roughness.
Fig. 1. Structure of an inverted organic cell and its • CB = 4.2 eV
energy levels’ diagram • Band gap = 3.2 eV

FTO • Thermal stability over 350 °C.


P3HT: Poly(3-hexylthiophene)
PC61BM: [6,6]-phenyl-C61-butyric acid methyl ester •Work function = 4.4 eV • Less expensive. 1
PFN: Poly [(9,9-bis(3'-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9–dioctylfluorene)]

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