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Lecture Presentation

Chapter 1

Chemistry in
Our Lives

Karen C. Timberlake
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Chapter 1 Chemistry in our Lives

Forensic scientists work in


crime laboratories where
they analyze bodily fluids
and tissue samples
collected by the crime
scene investigators.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
1.1 Chemistry and Chemicals

Chemists working in
laboratories test new
products and develop
new pharmaceuticals.

Learning Goal Define the term chemistry and identify substances as


chemicals.
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
What is Chemistry?

Chemistry
• is the study of composition,
structure, properties, and
reactions of matter.
• happens all around you
every day.

Antacid tablets undergo a


chemical reaction when dropped
in water.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Chemistry and Matter

Matter is another word for all substances that make up


our world.
• Antacid tablets are matter.
• Water is matter.
• Glass is matter.
• Air is matter.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Chemicals in the Kitchen

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Study Check

Which of the following contains chemicals?


A. Sunlight
B. Fruit
C. Milk
D. Breakfast cereal

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Solution

Which of the following contains chemicals?


A. Sunlight is energy; it does not contain chemicals.
B. Fruit is a type of matter; it contains chemicals.
C. Milk is a type of matter; it contains chemicals.
D. Breakfast cereal is a type of matter; it contains
chemicals.
Only B. fruit, C. milk, and D. breakfast cereal
contain chemicals.
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
1.2 Scientific Method

Thinking Like a
Scientist
Linus Pauling won
the Nobel Prize in
chemistry in 1954.

Learning Goal Describe the activities that are part of the


scientific method.
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
The Scientific Method

The scientific method is a set of general principles that


helps to describe how a scientist thinks.
1. Make observations about nature and ask questions
about what you observe.
2. Propose a hypothesis, which states a possible
explanation of the observations.
3. Several experiments may be done to test the
hypothesis.
4. When results of the experiments are analyzed, a
conclusion is made as to whether the hypothesis may
be true or false.
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Using the Scientific Method

Suppose you visit a friend in her home and soon after


you arrive, you begin to sneeze.
• You observe that your friend has a new cat.
• You ask yourself why you are sneezing and form a
hypothesis that you are allergic to cats.
• You perform experiments to test your hypothesis by
visiting other friends with cats.
• If you sneeze after leaving the other homes with
cats, you come to the conclusion that your
hypothesis is correct.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Using the Scientific Method

Through your observations, you may determine that you


are allergic to cat hair and dander.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Using the Scientific Method

The hypothesis is
modified if the results
of the experiments do
not support it.

The scientific method


develops conclusions
using observations,
hypotheses, and
experiments.
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Study Check

Identify each of the following as an observation (O), a


hypothesis (H), an experiment (E), or a conclusion (C):
A. During your visit to the gym, your trainer records that you
ran for 25 minutes on the treadmill.
B. Scientific studies show that exercising lowers blood
pressure.
C. Your doctor thinks that your weight loss is due to
increased exercise.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Solution

Identify each of the following as an observation (O), a


hypothesis (H), an experiment (E), or a conclusion (C):
A. During your visit to the gym, your trainer records that you ran
for 25 minutes on the treadmill. Observation (O)
B. Scientific studies show that exercising lowers blood
pressure. Conclusion (C)
C. Your doctor thinks that your weight loss is due to
increased exercise. Hypothesis (H)

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
B. Using Positive and Negative Numbers in Calculations

A positive number is any number that is greater than


zero and has a positive sign (+). Often the positive sign
is understood and not written in front of the number.

A negative number is any number that is less than zero


and is written with a negative sign (−).

Key Math Skill Using Positive and Negative Numbers in


Calculations

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Multiplication and Division: Positive and Negative Numbers

1. When two positive numbers or two negative numbers


are multiplied or divided, the answer is positive (+).

2. When a positive number and a negative number are multiplied or divided,


the answer is negative (−).

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Addition: Positive and Negative Numbers

1. When two positive numbers are added, the answer is


positive.
2. When two negative numbers are added, the answer is
negative.

3. When a positive number and a negative number are


added, the smaller number is subtracted from the larger
number and the result has the same sign as the larger
number.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Subtraction: Positive and Negative Numbers

When two numbers are subtracted, change the sign of the


number to be subtracted and then follow the rules for addition.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Study Check

Solve the following equation for P1.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Solution

Solve the following equation for P1.

To solve for P1, divide both sides by V1.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Scientific Notation

Numbers written in scientific notation have two parts:


Coefficient Power of 10
To write 2400 in the correct scientific notation,
• the coefficient is 2.4.
• the power of 10 is 3.
• write the product of the coefficient multiplied by a
power of 10.
2.4 × 103

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Scientific Notation

2 400 = 2.4 × 1 000 = 2.4 ×


103
 3 places Coefficient × Power
of 10

0.00086 = = 8.6 × 10−4

4 places  Coefficient × Power


of 10

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Some Positive Powers of 10

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Some Negative Powers of 10

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Measurements in Scientific Notation

Diameter of chickenpox virus = 0.000


000 3 m
= 3 × 10−7 m
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Some Measurements Written in Scientific Notation

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Scientific Notation and Calculators

Numbers in scientific notation can be entered into


a calculator using the EXP or EE key.

The calculator display shows a number between 1


and 10 followed by a space and the power of 10.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Study Check

Write each of the following in correct


scientific notation:
A. 64 000
B. 0.021

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Solution

Write each of the following in correct scientific


notation:
A. 64 000
STEP 1 Move the decimal point to
obtain a coefficient that is at least 1 but
less than 10.
6.4
STEP 2 Express the number of places
moved as a
power of 10.
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
4
Solution

Write each of the following in correct scientific


notation:
B. 0.021
STEP 1 Move the decimal point to
obtain a coefficient that is at least 1 but
less than 10.
2.1
STEP 2 Express the number of places
moved as a power of 10.
10−2
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Measurement of Matter

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Measurement of Matter

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Measurement of Matter
• Mass: The SI base unit of mass is the kilogram
(kg).

• Length: The SI base unit of length is the meter


(m).

• Volume: The SI base unit of volume is the cubic


meter (m3).

• Time: The SI base unit of time is the second (s).


General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Density

Density is defined as the


amount of matter in a given
amount of space.

d = m/V

The density of copper is


8.94 g/cm3.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Density: Practice Problem

Calculate the density of a metal sample with a


mass of 18.96 g and a volume of 4.31 cm3.

d = m/V

= 18.96 g/4.31cm3

= 4.40 g/cm3

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Density Calculations

Example 6. A certain mineral has a mass of


17.8 g and a volume of 2.35 cm3. What is the
density of this mineral?

mass
Density =
volume

17.8 g
Density =
2.35 cm3

3
Density = 7.57 g/cm
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Accuracy versus Precision

Accuracy refers to the proximity of a measurement to


the true value of a quantity.
Precision refers to the proximity of several
measurements to each other.

Neither accurate nor Precise but not Accurate and


precise
General, Organic, and Biological Chemistry: Structures of Life, 5/e
accurate © 2016 Pearson Education, Inc.
Karen C. Timberlake precise !!!!!
Significant Figures

• The term significant figures refers to


digits that were measured.
• When rounding calculated numbers, we
pay attention to significant figures so we
do not overstate the accuracy of our
answers.

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Counting Significant Figures
1. Nonzero integers ALWAYS count as significant figures.
3456 has 4 sig figs

2. There are 3 classes of zeroes:


Leading zeroes - Zeroes at the beginning of a number are never
significant
0.048 has 2 sig figs.
00481 has 3 sig figs
Captive zeroes - Zeroes between two significant figures are
themselves significant.
16.07 has 4 sig figs.
106 has 3 sig figs
Trailing zeroes - Zeroes at the end of a number are significant if a
decimal point is written in the number
9.300 has 4 sig figs.
150 has 2 sig fig.
1.50 has 3 sig fig
© 2012 Pearson Education, Inc.
General, Organic, and Biological Chemistry: Structures of Life, 5/e
Karen C. Timberlake
© 2016 Pearson Education, Inc.
Practice

a) 17 g contains ? significant figures


b) 17.0 g contains ? significant figures
c) 10.3 g contains ? significant figures
d) 4.307 g contains ? significant figures
e) 400g contains ? significant figures
a) 2 b) 3 c) 3 d) 4 e) 1

Try to determine the number of significant


figures:
a)245000 L b)0.00043 m
c)0.0500 in d)30501 mL
a) 3
General, Organic, and Biological Chemistry: Structures of Life, 5/e b) 2 c) 3 d) 5 © 2016 Pearson Education, Inc.
Karen C. Timberlake
a) 0.000122300 has ___ significant
figures
b) 0.00052
c) 12.2300
d) 1.2459
e) 1.2X104
f)
12X10-3

a) 6 b) 2 c) 6 d) 5 e) 2 f) 2
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Rounding The Numbers
When Calculator answer contains too many digits, it is
necessary to delete (drop) the nonsignificant figures. This
process is called Rounding off

(1) If the digit to be dropped is five or greater than 5, the


last retained digit is increased by one. For example,

13.6 is rounded to 14.

(2) If the digit to be dropped is less than 5, the last


remaining digit is left as it is. For example,

13.4 is rounded to 13.

© 2012 Pearson Education, Inc.


General, Organic, and Biological Chemistry: Structures of Life, 5/e
Karen C. Timberlake
© 2016 Pearson Education, Inc.
Round off the following numbers to two
significant figures ?

A) 25.7 26
B) 0.4327 0.43
C)432,117 430000
D)13500 14000

General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake

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