HUT- P CM - Bruker D8 Advance - #200-1/3 - A

400

d=12,36848

300
Lin (Cps)

d=2,98330
d=3,28838
d=8,72589

d=3,70669
200

d=3,34636

d=2,62143
d=4,10142
d=7,11216

d=5,51222

d=3,40849

d=3,23385
100
d=4,24866

d=2,89959

d=2,04953
d=2,75304

d=2,50638

d=2,17298
d=2,27205
0

5 10 20 30 40

2-Theta - Scale
HUT- PCM - Bruker D8 Advance - #200-1/3 - A - File: 200-1.3 - A - Type: 2Th/Th locked - Start: 5.000 ° - End: 45.000 ° - Step: 0.050 ° - Step time: 0.3 s - Temp.: 25 °C (Room) - Time Started: 1098782976 s - 2-Theta: 5.000 ° - Theta: 2.500 ° - Chi: 0.00 ° - Phi: 0.0
39-0222 (C) - Sodium Aluminum Silicate Hydrate - Na96Al96Si96O384·216H2O - Y: 96.13 % - d x by: 1. - WL: 1.5406 - Cubic - a 24.61000 - b 24.61000 - c 24.61000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centred - Fm3c (226) - 14905.1 -
88-2487 (C) - Quartz low - SiO2 - Y: 44.57 % - d x by: 1. - WL: 1.5406 - Hexagonal - a 4.93000 - b 4.93000 - c 5.38500 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - 3 - 113.347 - I/Ic PDF 3. -
85-0460 (A) - Quartz low - alpha-SiO2 - Y: 10.48 % - d x by: 1. - WL: 1.5406 - Hexagonal - a 4.73100 - b 4.73100 - c 5.28000 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - 3 - 102.346 - I/Ic PDF 2.8 -
44-0052 (C) - Sodium Aluminum Silicate Hydrate - Na3.6Al3.6Si12.4O32·14H2O - Y: 5.25 % - d x by: 1. - WL: 1.5406 - Tetragonal - a 9.99890 - b 9.99890 - c 10.06970 - alpha 90.000 - beta 90.000 - gamma 90.000 - Body-centred - I41/amd (141) - 1 - 1006.75 - I/Ic

1
 Zeolit Y
Zeolite-X
1100

1000
d=14,64391

900

800

700
Lin (Cps)

600

500

400

d=3,82086

d=2,88755
d=3,34202
300
d=5,75300
d=8,90123

d=4,43300
d=7,57608

d=2,95048

d=2,79455

d=2,66869
200

d=2,40855
d=3,05308

d=2,62609
d=4,83045

d=2,74684
d=3,96348

d=3,25662

d=2,20974

d=2,11999
d=2,08350
100

5 10 20 30 40 50

2-Theta - Scale
Zeolite-X - File: Mau Hat dai YV-300703.raw - Type: 2Th/Th locked - Start: 2.000 ° - End: 50.000 ° - Step: 0.050 ° - Step time: 0.3 s - Temp.: 25 °C (Room) - Time Started: 1059537984 s - 2-Theta: 2.000 ° - Theta: 1.000 ° -
Operations: Smooth 0.150 | Import
38-0237 (*) - Sodium Aluminum Silicate Hydrate - Na2Al2Si2.5O9·6.2H2O/Na2O·Al2O3·2.5SiO2·6.2H2O - Y: 83.64 % - d x by: 1. - WL: 1.5406 - Cubic - a 24.99000 - b 24.99000 - c 24.99000 - alpha 90.000 - beta 90.000

2
 HUT - PCM - Bruker D8 Advance - 30-9-05 -ZSM5-2000

d=11,06609
400

300
d=9,92321
Lin (Cps)

200

d=3,83464
d=3,71828
d=5,96968

100
d=6,33088

d=5,53728

d=2,97886
d=3,34034
d=4,24852
d=6,68014

d=4,34246

d=2,00673
d=3,43281

d=3,03904
0

5 10 20 30 40 50

2-Theta - Scale
HUT - PCM - Bruker D8 Advance - 30-9-05 -ZSM5-2000 - File: ZSM5-2000.raw - Type: 2Th/Th locked - Start: 5.000 ° - End: 50.000 ° - Step: 0.050 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 1128396032 s - 2-Theta: 5.000 ° - Theta: 2.500 ° - Chi: 0.00 ° - Phi: 0.00 ° - X: 0.0 mm - Y: 0.0 mm - Z: 0.0 mm - Aux1: 0.0 - Aux2: 0.0 - Aux3: 0.0 - Display pl
44-0003 (*) - Aluminum Silicate - Al2O3·54SiO2 - Y: 56.25 % - d x by: 1. - WL: 1.5406 - Orthorhombic - a 20.10400 - b 19.89700 - c 13.39500 - alpha 90.000 - beta 90.000 - gamma 90.000 - Primitive - Pnma (62) - 5358.12 -

3
Quatz

4
Đẳng nhiệt hấp phụ (isotherm)
Giản đồ đẳng nhiệt hấp phụ

25

20
n ad (mmol/g) 1

15 Desorption

10

5
Adsorption
0
0 0.2 0.4 0.6 0.8 1
p/p 0
Vòng trễ trên đẳng nhiệt hấp phụ

HI H2 H3
nad

nad

nad
p/p0 p/p0 p/p0

Cho biết thông tin về hình dạng của mao quản

 Đẳng nhiệt hấp phụ N2 và phân bố kích thước mao quản
wide-pore silica -alumina
25 25

20 20

n ad (mmol/g)1
n ad (mmol/g) 1

15 15

10 10

5 5

0 0
0 0.2 0.4 0 0.6 0.8 1 0 0.2 0.4 0 0.6 0.8 1
p/p p/p
0.10 0.5

0.08 0.4
dV /dd (ml/g/nm)

dV /dd (ml/g/nm)
0.06 0.3

0.04 0.2

0.02 0.1

0.00 0.0
1 10 100 1000 1 10 100 1000
d pore (nm) d pore (nm)
 Đẳng nhiệt hấp phụ N2 và phân bố kích thước mao quản
-alumina activated carbon
25 25

20 20
n ad (mmol/g) 1

n ad (mmol/g)1
15 15

10 10

5 5

0 0
0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
0 0
p/p p/p
0.010 0.5

0.008 0.4

dV/dd (ml/g/nm)
dV /dd (ml/g/nm)

0.006 0.3
} Tensile strength effect
0.2
0.004

0.1
0.002

0.0
0.000 1 10 100 1000
d pore (nm)
1 10 100 1000
d pore (nm)
 Đẳng nhiệt hấp phụ N2 và phân bố kích thước mao quản
Raney Ni ZSM-5
25 25

20 20

n ad (mmol/g)1
n ad (mmol/g)1

15 15

10 10

5 5

0 0
0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1
0 0
p/p p/p

0.10 10

0.08 8

dV /dd (ml/g/nm)
dV /dd (ml/g/nm)

0.06 6

4
0.04

2
0.02
0
0.00 0.0 0.5 1.0 1.5 2.0
1 10 100 1000 d pore (nm)
d pore (nm)
 Đẳng nhiệt hấp phụ N2 và phân bố kích thước mao quản
wide-pore silica -alumina
1.2 1.2

1.0 1.0

0.8 0.8

V (ml/g)
V (ml/g)

0.6 0.6

0.4 0.4

0.2 0.2

0.0 0.0
0.1 1 10 100 1000 0.1 1 10 100 1000
p (MPa) p (MPa)
0.08 0.5

0.4
0.06
dV /dd (ml/g/nm)

dV /dd (ml/g/nm)
0.3
0.04
0.2

0.02
0.1

0 0.0
1 10 100 1000 10000 1 10 100 1000 10000
d pore (nm) d pore (nm)
Đường cong nén thủy ngân của -Alumina
1.2

1.0

0.8
V (ml/g)

0.6

0.4

0.2

0.0
0.1 1 10 100 1000
p (MPa)
 Diện tích bề mặt riêng - SHg and SBET
Adsorbent SHg SBET 
m2/g m2/g deg
Iron Oxide 14.3 13.3 130
Tungsten Oxide 0.11 0.10 130
Anatase 15.1 10.3 130
Hydroxy Apatite 55.2 55.0 130
Carbon Black (Spheron-6) 107.8 110.0 130
0.5 % Ru/-Al2O3 237.0 229.0 140
0.5 % Pd/-Al2O3 115.0 112.0 140
TiO2 Powder 31.0 25.0 140
Sintered Silica Pellets 20.5 5.0 140
Zeolite H-ZSM-5 39.0 375.0 140
Norit Active Carbon R1 Extra 112.0 915.0 140
TPD-NH3
TPD-NH3
Illite
Quartz, Illite and Kaolinite
Calcite
Calcite và Dolomite
 PCM - Bruker D8 Advance -MCM 41
d=33,51559
300

200
Lin (Cps)

d=3,95205
d=3,78641

d=3,34820
d=4,15784
100
d=6,79928

2 10 20 30 40 50 60

2-Theta - Scale
PCM - Bruker D8 Advance -MCM 41 - File: MCM 41.raw - Type: 2Th/Th locked - Start: 1.500 ° - End: 60.000 ° - Step: 0.050 ° - Step time: 0.3 s - Temp.: 25 °C (Room) - Time Started: 1082774016 s - 2-Theta: 1.500 ° - Theta: 0.750 ° - Chi: 0.00 ° - Phi: 0.00 ° - X: 0.0
49-1711 (Q) - Silicon Oxide - SiO2 - Y: 31.98 % - d x by: 1. - WL: 1.5406 -
50-0511 (*) - Silicon Oxide - SiO2 - Y: 74.63 % - d x by: 1. - WL: 1.5406 - Cubic - a 81.09000 - b 81.09000 - c 81.09000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Body-centred - Ia-3d (230) - 533214 -
71-0261 (C) - Tridymite - SiO2 - Y: 27.71 % - d x by: 1. - WL: 1.5406 - Triclinic - a 9.93200 - b 17.21600 - c 81.86400 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centred - F1 (0) - 64 - 13997.9 - I/Ic PDF 1.4 -
82-1573 (C) - Silicon Oxide - SiO2 - Y: 10.66 % - d x by: 1. - WL: 1.5406 - Triclinic - a 4.72090 - b 4.56220 - c 6.03940 - alpha 90.905 - beta 93.359 - gamma 105.959 - Primitive - P1 (1) - 4 - 124.778 - I/Ic PDF 0.5 -

22
 HUT - P CM - Bruke r D8 Adva nce - 29-9-05 - Be ntonit My

d=15,50532
140

130

120

110

100

90

80

70

d=4,04296
60

50

d=3,21752
d=4,47782

d=3,12755
40

d=2,52855
30

20

10

0
5 10 20 30 40 50

2-Theta - Scale
HUT - PCM - Bruker D8 Advance - 29-9-05 - Bentonit My - File: Bent My.raw - Type: 2Th/Th locked - Start: 5.000 ° - End: 50.000 ° - Step: 0.050 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 1127963392 s - 2-Theta: 5.000 ° - Theta: 2.500 ° - Chi: 0.00 ° - Phi: 0.00 ° - X: 0.0 mm - Y:
03-0015 (D) - Montmorillonite (bentonite) - (Na,Ca)0.3(Al,Mg)2Si4O10(OH)2·xH2O - Y: 60.42 % - d x by: 1. - WL: 1.5406 -
86-1565 (C) - Quartz low - SiO2 - Y: 22.92 % - d x by: 1. - WL: 1.5406 - Hexagonal - a 4.70220 - b 4.70220 - c 5.25610 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - 3 - 100.646 - I/Ic PDF 2.9 -
79-1915 (A) - Quartz - SiO2 - Y: 20.83 % - d x by: 1. - WL: 1.5406 - Hexagonal - a 4.53500 - b 4.53500 - c 5.17000 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3121 (152) - 3 - 92.0822 - I/Ic PDF 2.5 -

23
 Gibbsit
HUT - P CM - Bruke r D8 Adva nce - 12.4.06#a Don - Ma u 17/45 D

d=4,85758
400

300

200

d=4,37800

100

d=2,38605
d=3,31658

d=2,45789

d=2,05000
d=4,73501

d=3,18356

d=2,24712
d=2,42389

d=2,16534
0
5 10 20 30 40

2-Theta - Scale
HUT - PCM - Bruker D8 Advance - 12.4.06#a Don - Mau 17/45 D - File: Mau 17-45.raw - Type: 2Th/Th locked - Start: 5.000 ° - End: 45.000 ° - Step: 0.050 ° - Step time: 0.4 s - Temp.: 25 °C (Room) - Time Started: 1144827648 s - 2-Theta: 5.000 ° - Theta: 2.500 ° - Chi: 0.00 ° - Phi: 0.00 °
70-2038 (C) - Gibbsite - Al(OH)3 - Y: 26.66 % - d x by: 1. - WL: 1.5406 - Monoclinic - a 8.68400 - b 5.07800 - c 9.73600 - alpha 90.000 - beta 94.540 - gamma 90.000 - Primitive - P21/n (14) - 8 - 427.985 - I/Ic PDF 1.8 -

24
 HUT - PCM - Bruker D8 Advance - Boehmite

100

d=6.276
90

d=1.847
d=3.166
80

70

d=2.347
60
Lin (Cps)

50

d=1.442
40

30

20

10

10 20 30 40 50 60 70

2-Theta - Scale
PCM - Bruker D8 Advance -Al2O3 Mau KP[PH=9-10]-T230 - File: Mau KP[PH=9-10] - T230.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.050 ° - Step time: 0.3 s - Temp.: 25 °C (Room) - Time Starte
Operations: Smooth 0.986 | Smooth 0.564 | Smooth 0.150 | Import
05-0190 (D) - Boehmite - alpha-Al2(OOH)2 - Y: 91.67 % - d x by: 1. - WL: 1.5406 - Orthorhombic - a 2.86800 - b 12.22700 - c 3.70000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centred - Cmcm (63) - 129.748 -

25
 -Al2O3
PCM - Bruker D8 Dvance - Mau gama Al2O3 -H2 -A4-500C-8h
90

d=1.394
80

70

d=1.989
d=2.738

d=2.425
60

d=2.311
50

40

30

20

10

0
10 20 30 40 50 60 70

2-Theta - Scale
PCM - Bruker D8 Advance-NaA-240-24-4-100-450 - File: Hoang - Mau gam H2-A118-4ppm- 500-8h[2].raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.050 ° - Step time: 0.3 s - Temp.: 25 °C (Room) - Time Starte
01-1307 (D) - Aluminum Oxide - gamma-Al2O3 - Y: 83.33 % - d x by: 1. - WL: 1.5406 -
29-0063 (N) - Aluminum Oxide - gamma-Al2O3 - Y: 53.04 % - d x by: 1. - WL: 1.5406 - Cubic - a 7.92400 - b 7.92400 - c 7.92400 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centred - Fd3m (227) - 10 - 497.546 -

26