Professional Documents
Culture Documents
6: AIR
POLLUTIO
N
Here is where our presentation begins
Learning Objectives:
04 05 06
Indoor Air Pollution Effects of Air Acid Rain
Pollution on Human
Health
07
Air Pollution
Legislation
01
Composition &
Structure of the
Atmosphere
Composition & Structure of the Atmosphere
Atmosphere refers to the layer of gases that surrounds Earth and is held in place by Earth’s
gravitational attraction (gravity). The mix of gases in the atmosphere forms a complex
system organized into layers that together support life on Earth. Although there are numerous
gases, as shown in Table 6.1, the top four gases make up 99.998 % of the volume of
clean dry air (unpolluted air that does not contain water vapor). Of this dry composition of
the atmosphere nitrogen, by far, is the most common (78%).
Nitrogen is also needed and used by living things to make proteins, though as nitrogen gas,
N2, it is unavailable to most living things.
Oxygen is used by all living things to make molecules that are essential for life. It is also
essential for aerobic respiration as well as combustion or burning.
Argon is a non-reactive gas, and we use it in light bulbs, in double-pane windows, and to
preserve priceless documents such as the original Declaration of Independence and the
Constitution.
Carbon dioxide is an essential gas used by plants and other organisms to make sugar (food)
through photosynthesis. Carbon dioxide also acts as a blanket that prevents the escape of heat
into outer space.
Water vapor (water in a 'gas' state) is usually present up to about 4% of the total volume
depending on location. In the Earth's desert regions (30° N/S) when dry winds are blowing,
the water vapor contribution to the composition of the atmosphere will be near zero.
Earth’s atmosphere is divided into four distinct layers based on thermal
characteristics (temperature changes), chemical composition, movement, and
density (Figure 6.1).
Air pollution encompasses the release of substances into the atmosphere that
pose harmful effects on humans, other organisms, and the environment, manifesting as
solid particles, liquid droplets, or gases. It may arise from natural phenomena like dust
storms, forest fires, and volcanic eruptions, as well as human activities such as biomass
burning, vehicle emissions, mining, agriculture, and industrial processes. Enhanced
technology and governmental regulations have led to a reduction in various forms of
outdoor air pollution in many industrialized nations, including the United States, in
recent years. Nevertheless, outdoor air quality remains a significant concern in less
industrialized countries, particularly in rapidly industrializing megacities such as those
in China and India.
Outdoor pollutants originate from either stationary (point) sources or mobile
(nonpoint) sources (see Figure 6.7). Stationary sources are fixed in location, such as
power plant smokestacks, construction sites, farmlands, and surface mines. Conversely,
mobile sources emit pollutants while moving from one place to another. Examples of
mobile sources include vehicles, aircraft, ships, and trains.
Pollutants are typically classified into two main types based on their
origin: primary and secondary pollutants. Primary pollutants are directly
released into the air in harmful forms from their sources. The primary
pollutants that contribute to almost all air pollution issues include carbon
monoxide (58%), volatile organic compounds (VOCs, 11%), nitrogen oxides
(15%), sulfur dioxides (13%), and particulate matter (3%). Secondary
pollutants, on the other hand, are formed through chemical reactions between
primary pollutants and normal atmospheric compounds. For instance, ground-
level ozone develops over urban areas through reactions, facilitated by sunlight,
between primary pollutants like nitrogen oxides and other atmospheric gases
such as VOCs.
Criteria pollutants
Under the Clean Air Act, particularly in section 6.7.1, the Environmental
Protection Agency (EPA) establishes air quality standards aimed at safeguarding public
health and the environment. The EPA has defined national air quality standards for six
common air pollutants: 1) carbon monoxide; 2) ground-level ozone; 3) nitrogen dioxide;
4) sulfur dioxide; 5) lead; and 6) particulate matter (also referred to as particle
pollution). Among these pollutants, particle pollution and ground-level ozone pose the
most prevalent health risks. The EPA categorizes these pollutants as "criteria" air
pollutants because it regulates them by formulating human health-based and/or
environmentally-based criteria (science-based guidelines) for determining permissible
levels. The standards based on human health considerations are termed primary
standards, while those aimed at preventing environmental and property damage are
known as secondary standards.
1. **Carbon Monoxide (CO):** Carbon monoxide is a colorless, odorless gas emitted during
combustion processes, particularly incomplete fuel combustion. In urban areas, mobile sources
predominantly contribute to ambient CO emissions. CO can lead to harmful health effects by
impeding oxygen delivery to vital organs like the heart and brain. At extremely high levels, CO
exposure can be fatal.
2. **Ground-level ozone (O3):** Ground-level ozone, a colorless gas with a faint sweet odor,
forms through the interaction of sunlight, heat, nitrogen oxides (NOx), and volatile organic
compounds (VOCs). It typically reaches unhealthy levels during hot, sunny days in urban settings.
Major sources of NOx and VOCs include emissions from industrial facilities, electric utilities,
motor vehicle exhaust, gasoline vapors, and chemical solvents.
3. **Nitrogen dioxide (NO2):** Nitrogen dioxide is among a group of highly reactive gases
known as "oxides of nitrogen" or "nitrogen oxides (NOx)." It appears as a yellowish-brown to
reddish-brown gas with a pungent odor and contributes significantly to smog and acid rain
formation. Nitrogen oxides form when atmospheric nitrogen and oxygen react at high temperatures
generated by combustion engines. In the United States, most emissions originate from vehicle
engines, electrical utilities, and industrial combustion processes.
4. **Sulfur Dioxide (SO2):** Primarily emitted from fossil fuel combustion in power plants
(73%) and industrial facilities (20%), sulfur dioxide belongs to the group of highly reactive
gases known as "oxides of sulfur."
5. **Lead (Pb):** Historically, major sources of lead emissions were motor vehicle fuels and
industrial activities. Regulatory efforts have significantly reduced lead emissions from
transportation (95% between 1980 and 1999). Current sources include ore and metal
processing, as well as piston-engine aircraft using leaded aviation gasoline.
6. **Particulate Material (PM):** Particulate pollution consists of solid particles and liquid
droplets suspended in the air. It includes various components like acids, organic chemicals,
metals, and allergens. Inhalable coarse particles (PM10) and fine particles (PM2.5) pose
health risks by penetrating deep into the lungs and bloodstream. Coarse particles originate
from road dust, while fine particles result from combustion processes.
Volatile Organic Compounds
Synthetic organic chemicals like benzene, toluene, formaldehyde, vinyl chloride, chloroform, and
phenols are widely used in various household products such as paints, varnishes, cleaning agents,
cosmetics, and fuels. These products release organic compounds during use and storage. The "new
car smell" associated with new vehicles results from a mix of dozens of VOCs. Indoor
concentrations of many VOCs can be significantly higher (up to ten times) than outdoor levels,
often contributing to sick building syndrome, an illness stemming from indoor pollution where the
specific cause is not easily identified.
Smog
Smog, a mixture of air pollutants like sulfur dioxide, nitrogen oxides, ozone,
and particulates, often blankets urban areas due to fossil fuel combustion. Coined from
"smoke" and "fog," smog creates a brownish haze, reducing visibility and impairing
breathing for some individuals. Two primary types exist: industrial and photochemical
smog. Industrial smog results from fossil fuel burning, generating carbon dioxide,
carbon monoxide, sulfur, and mercury. Sulfur reacts with atmospheric chemicals,
yielding sulfur dioxide and particulate matter. Photochemical smog forms when sunlight
triggers reactions between vehicle emissions and atmospheric compounds, resulting in
over 100 chemicals, including ground-level ozone.
Toxic pollutants
Toxic air pollutants, also known as hazardous air pollutants, are substances known or
suspected to cause cancer, reproductive issues, birth defects, or other serious health and
environmental problems. Examples include benzene in gasoline, perchloroethylene from dry
cleaning facilities, and methylene chloride used in various industries. Other examples are dioxin,
asbestos, toluene, and metals like cadmium, mercury, chromium, and lead compounds.
Most toxic air pollutants stem from human activities, including mobile sources like vehicles,
stationary sources such as factories and power plants, and indoor sources like building materials
and cleaning products. Some also arise from natural events like volcanic eruptions and forest fires.
While primarily inhaled, pollutants like mercury can deposit onto soils or waters, entering the food
chain and posing risks to animals and humans alike over time.
04
Indoor Pollution
Indoor air pollution poses a greater health risk than outdoor pollution
in both developed and developing nations. According to the World Health
Organization (WHO) and agencies like the Environmental Protection Agency
(EPA), indoor air generally contains higher concentrations of toxic pollutants
due to various sources like combustion, building materials, and household
products. People typically spend more time indoors, amplifying the health
effects of indoor pollution in workplaces, schools, and homes.
Immediate health effects of air pollution can manifest after a single exposure or repeated
exposures. Other health problems may emerge years later or after prolonged exposure.
The likelihood of immediate reactions to air pollutants is influenced by
several factors, including age and preexisting medical conditions.
Individuals with conditions like heart and lung diseases (e.g., heart failure,
asthma, emphysema), diabetes, older adults, and children are more
susceptible to air pollution-related health effects. Moreover, individual
sensitivity varies greatly among people, with some individuals becoming
sensitized to biological or chemical pollutants after repeated exposures.
This variability underscores the complex interplay between personal
health factors and environmental exposures.
06
Acid Rain
Acid rain is a form of precipitation, such as rain, snow, or fog, that contains elevated levels
of acidic compounds, primarily sulfuric acid (H2SO4) and nitric acid (HNO3). These acids
are formed when sulfur dioxide (SO2) and nitrogen oxides (NOx) emitted from industrial
activities, vehicle exhaust, and other sources react with water vapor, oxygen, and other
atmospheric components in the presence of sunlight.
The sources of acid rain are primarily human activities that release sulfur dioxide and
nitrogen oxides into the atmosphere, although natural sources such as volcanic eruptions
can also contribute to acid rain formation.
Environmental Effects of Acid Rain:
Similarly, in October 1948, Donora, Pennsylvania, experienced a thick cloud of air pollution
lingering for five days, which resulted in the deaths of 20 people and sickness in 6000
residents out of the town's population of 14,000.
One of the most infamous incidents occurred during the London fog of 1952, where acid
aerosols trapped in the lower atmosphere led to the deaths of approximately 4000 people.
These tragic events served as crucial wake-up calls regarding the serious threats that air
pollution poses to public health and underscored the urgent need for environmental
regulations and initiatives to mitigate its harmful effects.
Clean Air Act
In the United States, the response to air pollution began with the passage of the original
Clean Air Act in 1963, which allocated funds for studying and addressing air pollution issues.
However, it wasn't until 1970 that Congress enacted a much stronger version of the Clean Air Act in
response to growing environmental concerns.
In 1970, Congress also established the Environmental Protection Agency (EPA) and charged it with
the primary responsibility of implementing the Clean Air Act. Since its inception, the EPA has
overseen various programs aimed at reducing air pollution nationwide.
While the Clean Air Act is a federal law covering the entire country, a significant portion of the
implementation and enforcement occurs at the state, tribal, and local levels. These entities
collaborate with industries to reduce pollution, review and approve permit applications, and
undertake other measures to comply with the requirements of the Clean Air Act.
EPA's Role
The Environmental Protection Agency (EPA) is tasked with safeguarding public health
and the environment from air pollution across the United States. To fulfill its mission, the EPA
administers various programs under the Clean Air Act with the following objectives:
1. **Reducing Ambient Air Pollutants:** The EPA focuses on lowering outdoor concentrations of
pollutants such as smog, haze, and acid rain, which can have detrimental effects on health and the
environment.
2. **Controlling Toxic Air Pollutants:** The EPA works to minimize emissions of toxic air
pollutants, which are known or suspected to cause serious health issues including cancer.
3. **Protecting the Ozone Layer:** Another priority is phasing out the production and use of
chemicals that harm the stratospheric ozone layer, which shields the Earth from harmful UV
radiation.
Under the Clean Air Act, the EPA establishes limits on specific air pollutants, dictating
the maximum allowable concentrations throughout the country. The EPA also has the authority to
regulate emissions from various sources such as chemical plants, utilities, and industrial facilities.
While individual states or tribes may enact stricter air pollution laws, they cannot adopt weaker
pollution limits than those set by the EPA.
Additionally, the EPA collaborates with state, tribal, and local agencies to develop and implement
plans for reducing air pollution. If a state or tribal plan fails to meet the required standards, the EPA
can impose sanctions and, if necessary, assume enforcement responsibilities. The EPA supports
these agencies by providing research, expertise, engineering designs, and financial assistance to
advance clean air initiatives. Since 1970, significant funding has been allocated by Congress and
the EPA to support these efforts at the state, local, and tribal levels.
State and Local Governments' Role
Indeed, assigning responsibility for implementing the Clean Air Act to state and local air
pollution agencies is logical and effective. These agencies possess the local expertise needed to
address pollution issues effectively, considering factors such as local industries, geography,
housing, and commuting patterns.
State, local, and tribal governments play critical roles in the enforcement of Clean Air
Act regulations. They monitor air quality, conduct inspections of facilities within their jurisdictions,
and ensure compliance with regulatory standards. Moreover, states are required to develop State
Implementation Plans (SIPs), which detail the strategies for controlling air pollution in accordance
with the Clean Air Act. SIPs encompass a range of regulations, programs, and policies aimed at
improving air quality in polluted areas. Importantly, the development of SIPs involves public
participation and input from industries through hearings and opportunities for feedback. This
inclusive approach ensures that the strategies outlined in SIPs are well-informed and address the
specific needs and concerns of affected communities and industries.
Outcomes of the Clean Air Act
For more than forty years, the Clean Air Act has cut pollution as the U.S.
economy has grown. The combined emissions of the six criteria pollutants has
continued to decrease while population, gross domestic product, energy
consumption, and vehicle miles travelled have all continued to increase (Figure
6.14). The following is a summary of some of the accomplishments of the Clean
Air Act:
Clean Air Act programs have lowered levels of the six criteria pollutants -
particulates, ozone, lead, carbon monoxide, nitrogen dioxide and sulfur dioxide -
as well as numerous toxic pollutants.
- Between 1970 and 2012, national emissions of the six common pollutants decreased by
an average of 72 percent, even as the gross domestic product increased by 219 percent.
This substantial progress is the result of collaborative efforts involving state, local, and
tribal governments, the EPA, private sector companies, environmental groups, and other
stakeholders.
- The reductions in emissions have resulted in significant improvements in air quality
nationwide.
- These improvements have allowed many regions to achieve compliance with national air
quality standards established to safeguard public health and the environment. For instance,
all 41 areas previously designated as having unhealthy levels of carbon monoxide in 1991
now meet the health-based national air quality standard. This achievement is largely
attributable to cleaner motor vehicles, which comply with emissions standards mandated
by the Clean Air Act.
- Airborne lead pollution, once a widespread health concern, now meets national air quality
standards across most areas of the country, thanks to the EPA's phased elimination of lead
in motor vehicle gasoline under Clean Air Act regulations.
THANK
MEMBERS:
S!
GRANTOS, JUSTIN
DOTADO, GEM CASSANDRA
ENRIQUEZ, JHON MARK
SUYAT, LAWRENCE
ESPINOSA, ANDREW