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9.RA 6969 HAzardous Wastes
9.RA 6969 HAzardous Wastes
Reporters:
DEODORA V. CARILLO
ELEAZAR C. VANGUARDIA
VAN CHRISTIAN TORRALBA
OUTLINE OF PRESENTATION
Background (Why regulate Toxic Substances & Hazardous
Wastes including their Health Effects)
Title II: Chemical Management
PICCS
SQI
PMPIN
PCL
CCO
Title III: Hazardous Wastes Management
Specific Requirements (HWGs, Transporters, TSDFs)
Basel Convention on the Trans-boundary Movement of
Hazardous Wastes and their Disposal
Other relevant issues
CORE OF CHEMICAL SAFETY
Risk:
1.) possibility that a harm (death, injury or loss) would
occur as a result of exposure to a chemical;
2.) expected frequency of occurrence of a harmful
event (death, injury or loss) arising from exposure
to a chemical.
Why do we need to manage toxic chemicals and
hazardous wastes?
Health Effects
Why do we need to manage toxic chemicals and
hazardous wastes?
Health Effects
Pregnancy and Lead
POISON
Enters blood stream
Causes illness first
Usually prolonged
cumulative
ACUTE vs CHRONIC EFFECTS
ACUTE EFFECTS CHRONIC EFFECTS
Acetone Methanol (wood
irritation of the eyes alcohol)
(possible corneal
damage), and
dermatosis
digestive tract and
respiratory tract; possibility of
headache
depression of the
dizziness
central nervous
system: headache, vision disorders
nausea, vomiting, digestive
loss of coordination, disturbances
dizziness, narcosis insomnia.
(severe intoxication).
PROLONGED EXPOSURES: Some Chronic Health Effects
Carcinogenic
Teratogenic
Mutagenic
HEALTH EFFECTS OF COMMON INORGANIC
CONTAMINANTS
CONTAMINANT SOURCE PATHWAYS HEALTH EFFECTS
Arsenic Pesticides Air, water Gastrointestinal disorder,
Ore smelting/refining lower-limb disorder
Asbestos Heat/flame resistant Air Asbestosis (scarring of lungs)
applications
Cadmium Electroplating, battery Air, biota, Joint pain, lung, kidney
manufacturing water disease
Lead Gasoline, batteries, Air, biota, Impairs nervous system, red
solder, radiation water blood cell synthesis
shielding
Mercury Electrical goods, chlor- Water, biota Inorganic: disorder of central
alkali plants nervous system, psychoses
(inorganic); fungicides, Organic: numbness, impaired
slimicides (Organic) speech, deformity, death
HEALTH EFFECTS OF COMMON ORGANIC
CONTAMINANTS
CONTAMINANT SOURCE PATHWAYS HEALTH EFFECTS
DDT(dichlorodiphe Application of Water, food Bioaccumulates in fatty
nyltrichloroethane pesticide worldwide chain tissues, nervous disorders,
persistent
Contaminated Soil
Contact with Water
Contaminated
ground water
Ground Water Flow
BIOACCUMULATION/BIOMAGNIFICATION
*Bioaccumulation has increased POPs Concentration
100 million times (ppb)
Fish-eating
birds 3,530,000
Plankton 1,880
Sediments 150
COVERAGE of RA 6969
PICCS
PMPIN
PCL
CCO
PICCS
Philippine Inventory of Chemicals & Chemical
Substances
It is a list of all existing chemicals & chemical
substances used, sold, distributed, imported,
processed, manufactured, stored, exported, treated or
transported in the Philippines
It serves as a guide for manufacturers and importers of
chemicals
Importation of chemicals not listed in the PICCS must
be covered by a Small Quantity Importation
Clearance (SQI) - limited to 1000 Kg/Annum
PMPIN
Pre-Manufacturing & Pre-Importation Notification
M - manufacture
I - importation
PMPIN: Types of Notification
There are two types of PMPIN for new substances manufactured or
imported with volume(>=1,000kg/y): abbreviated form and detailed
form.
Users/Importers/Manufacturers/Distributors of
chemicals included in the PCL are required to register
their hazardous wastes & chemical substances &
submit annual report (Prescribed Form) beginning Sept.
1996 on production and management information
CRITERIA for PCL
The following criteria has been established by DENR for PCL based
on the selection criteria used in other industrial nations such as
Australia, Japan, Canada and the United States:
environment
Salient Features of the CCO for Cyanide and
Cyanide Compounds
Limitation of use to:
Electroplating industries;
Mining & metallurgical industries;
Steel manufacturing;
Synthetic fibers & chemicals;
Plastic production;
Other industry sub-sectors; and legitimately using
cyanide such as jewelry making.
Salient Features of the CCO for Cyanide and
Cyanide Compounds
Prohibitions:
Use or made available to the fishery sector
environment
Salient Features of the CCO for Asbestos
Limitation of use to:
Fire proof clothing;
Roofing felts or related products;
Asbestos cement roofing & flat sheets;
Friction materials & gaskets;
High temperature textile products;
Mechanical packing materials;
High-grade electrical paper;
Battery separators; and
Other high density products.
Salient Features of the CCO for Asbestos
Prohibitions:
Use of amosite (brown) & crocidolite (blue) asbestos
fibers;
Spraying of all forms of asbestos;
New use of asbestos in:
Toys, pipes & boiler laggings;
Low density jointing compounds;
Corrugated, commercial, & specialty papers;
Untreated textiles;
Flooring felt & coverings; and
Other low density products
Requirements for Asbestos Wastes
Management Service Provider (MC 2003-003)
Accomplished application form;
Environmental Permits (ECC, P/O air & water);
Business Permit & SEC Registration;
TSD/ACF Permits;
ACM Management Plan (housekeeping practices,
transport management plan, list of PPEs & equipment,
photo-documentation of operation);
Emergency Contingency Plan; and
Affidavit of undertaking on liabilities of parties to
compensate for damage to property or life
Salient Features of the CCO for ODS
Phase Out Schedule & Control of Importation
CFC-11 (new) 1998
CFC-11 (service) 2005
CFC-12 (new) 1998
CFC-12- (service) 2010
CFC-113 1996
CFC-114 1998
CFC-115 1998
Halon 1211 1998
Halon 1301 1998
Carbon Tetrachloride 1996
Methyl Chloroform 1996
Salient Features of the CCO of ODS
Prohibitions:
Back Conversion & installation of CFC-using systems
Sale & use of small disposable containers (less than 1 kg) with
CFCs
Importation or manufacturing or placing in the market of
products or equipment containing Halons or CFCs,
except metered dose inhalers
Use of CFC-11 as blowing agent for foam manufacturing
Use of CFCs in Mobile Air Conditioners (MAC) starting 2006 in
motor vehicles manufactured and/or initially registered
from 1999 onwards, and starting 2012 in all motor vehicles
Intentional release/venting of ODS when servicing equipment
and flushing with ODS
Salient Features of the CCO for PCB
Coverage
PCB Equipment (PCB > 500 ppm)
PCB-contaminated Equipment (50 ppm < PCB> 500ppm)
Non-PCB Equipment (PCB < 50 ppm)
PCB-Free Material (PCB < 2 ppm)
PCB Wastes – discarded materials that contains PCB or have
been contaminated with PCBs, that are without any safe
commercial, industrial, agricultural or economic usage)
PCB Articles- any material, other than PCB wastes, whose
surface has been in direct contact with PCBs.
PCB packaging – any container or pressurized receptacle
that
contains and secures PCB articles and PCB wastes
PCB-
Contam'd Non-PCB PCB- PCB-
Activities PCB-Equip Equip PCB-article wastes Packaging PCBs
Equip
Stop upon No longer Stop upon Stop upon Stop upon Stop upon
Stop upon effective effective effective effective effective
1. Importation effective date allowed 3
date yrs after date date date date
the
effective
Stop upon date (Y Stop upon Stop upon Stop upon Stop upon
2. Trade/ Sale/ Stop upon effective 2007) effective effective effective effective
Distribution effective date date date date date date
No longer
allowed Stop upon
3. Domestic after 10 effective
Production Stop upon effective date
yrs date
(2014)*
Stop upon
effective date -
No longer Can be No longer use in open-
No longer allowed used until allowed
ended and
5. Recycling/ Use
as raw mats Stop upon effective date
*Consult EMB Memorandum Circular 2015-004: Clarification to the CCO for PCBs
EMB Memorandum Circular 2015-004:
Clarification to the CCO for PCBs
All PCB owners who have not yet registered pursuant
to DAO 2004-01 (CCO for PCB) must register online
through the EMB Online PCB Database (
www.emb.gov.ph/philpcbtracker);
Those who were previously registered shall review and
update the required information through the same
online database not later than April 9, 2015;
Those who were previously registered shall review and
update the required information through the same
online database not later than April 9, 2015;
Salient Features of the CCO for Lead
(Pb) and Lead Compounds
Prohibited use in the following production/
manufacturing:
Packaging for food and drinks
Fuel additives
Water pipes
School supplies
Cosmetics
Paints (with more than 90 ppm threshold limit)
2013-2016: architectural, decorative, household
2013-2019: industrial applications
Salient Features of the CCO for Arsenic
and Arsenic Compounds
Prohibited use in the following production/
manufacturing:
Fertilizers
Pesticides and Wood Preservatives
Chemical Weapons
HAZARDOUS WASTE
HAZARDOUS WASTE
_______________________
CLASS: HW SUB-CATEGORY:
______________
CHARACTERISTIC: HW #:
_ _ __ _ ___ __ __ _ F
VOLUME/WEIGHT: ORM:
___________
OF
DATE START
ACCUMULATION:
DATE CONTAINER FILLED:
_SHIPPING
___________________________ DATE:
___ __
_________________
CONTAINER’S CAPACITY:
CONTAINER’S MATERIAL:
GENERATOR’S HW ID #:
COMPANY_____________ NAME:
___________________________
ADDRESS:
_____________________________
CONTACT #/s:
____
________________________________
_CONTACT PER
______ SO
H_A_ND_L_E_WITH
N:
C_A_RE
“RULE OF THUMB”
EMB
9 Hazard Categories
Generator Transporter Treater
Corrosive
Reactive
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 2.1 Classification of Hazardous Wastes
WASTE
CLASS DESCRIPTION NUMBER
D: Wastes with Inorganic Chemicals
Chromium Compounds* Includes all wastes with a total Cr concentration D405
> 5 mg/L based on analysis of an extract
Lead compounds* Includes all wastes with a total Pb concentration D406
> 1 mg/L based on analysis of an extract.
Mercury and mercury Includes all wastes with a total Hg concentration
compounds > 0.1 mg/l based on analysis of an extract. D407
These also includes organomercury compounds.
Refer to CCO.
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 2.2 Exempted Wastes
Household wastes such as garbage under RA 9003
except special
wastes
Treated industrial or commercial wastewater that are disposed of on-
site through the sewerage system
Industrial & commercial solid wastes that do not contain hazardous
wastes as identified in Table 2.1
Materials from building demolition except those that contain asbestos
Septic tank effluents & associated sullage wastewaters
Untreated spoils from mining, quarrying & excavation works but not
materials in the nature of tailings, commercially treated materials and
mine facility consumables
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 3.1 Categories of Hazardous Wastes Generators
Hazardous Large Medium Small
Waste No. Waste Type Kg/yr Kg/yr Kg/yr
A101 Waste with Cyanide
L403 ODS
L404 PCB Wastes >10,000 10,000- <5000
M502 Asbestos Wastes 5,0000
M501 Pathological or Infectious Wastes
M503 Pharmaceuticals and Drugs
???In case of establishments generating two types of wastes, the establishment is classified as
a large generator. The Bureau may from time to time update the categories of waste
generators, once data becomes available.
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 3.2 Compliance Requirements of Hazardous Wastes
Generators
Category Reporting Storage Time Limit
Large quantity generators Quarterly 6 months
Table
Type 6.1 Appropriate Containers
Content per Type of Wastes
Polyethylene Drums Acids and bases
Metal Drums Flammables, solvents, and paints
Fiber Drums Granular materials
Sec. 6.2 Labeling Requirements
6.2.1 Form of labels attached to vessels, containers,
tanks and containment buildings
a. Minimum label size is 20cm x 30cm readable 5 meters away
b. Color of the label is yellow for background and black for
letters
conspicuously marked in paint or other permanent form of
marking
c. Material of the label should be scratch proof and resistant to
tampering and weathering.
d. The basic form is provided in Figure 6.2
e. Label is accompanied by a placard corresponding to characteristics of
the hazardous waste contained in the vessel, container, tank
or containment building as specified in Sec. 6.3 of this Guideline
Shipping date Date on which waste must be removed from the storage
excludes importation of
tanker sludge
DENR Administrative Order No. 06, Series of 2010:
Guidelines on the Use of Alternative Fuels and Raw
Materials in Cement Kilns
HW Materials Acceptable for Co-
processing:
It qualifies as alternative fuel or raw
material as defined;
Its use in the cement kiln complies with
applicable environmental standards
provided for in RA 8749 and RA 6969;
It should pass waste acceptance criteria
based on calorific value, mineral oxides,
heavy metal content and other
substances, and impacts on kiln
operation, clinker and cement quality.
DENR Administrative Order No. 06, Series of 2010:
Guidelines on the Use of Alternative Fuels and Raw
Materials in Cement Kilns
Hazardous Waste Materials Not
Acceptable for Co-processing
Health care wastes
Asbestos-containing wastes
All types of batteries
Electronic assemblies and scraps
Explosives
Cyanide wastes
Mineral acids
Radioactive wastes
Unsegregated Municipal solid wastes
Joint DENR-DOE Administrative Order (JAO) 2013-09-0001
Lighting Industry Waste Management Guidelines
Lighting products contain mercury, arsenic, and other
compounds that are toxic to human and aquatic life even at low
concentrations.
Regulates the end-of-life disposal of lighting products to control
the dispersion of these toxic substances into the environment to
avoid these adverse consequences for the protection of the
environment and public health.
Defines “lighting” (those covered by this JAO)
Joint DENR-DOE Administrative Order (JAO) 2013-09-0001
Lighting Industry Waste Management Guidelines
Obligations of Stakeholders
All producers shall jointly work together in coming up with a
Lamp Waste Management Plan and in setting-up a Lamp Wastes
Management System Operator as defined in this Order. The
producers and Lamp Wastes Management System Operator are
responsible for the preparation, implementation, and review
and monitoring of the Lamp Management System Plan.
Site Inspection
Interviews
Update CSM
Implementation of RemAP
Secure Regulatory Procurement
Prepare Work Plan
Permits Process
Site Validation
Recommendation(s) on further
Sampling Activities Site Management and Long
term Monitoring (if required)
Violation of any of the provisions on the Governing Rules and Regulations 10,000.00
In addition to the above stated penalties, violation of any of the provisions
on any of the Governing Rules and the rules covering the Contingency
Program shall result in the immediate suspension of the Permit issued to
said violator
Chapter 11. Prohibited Acts and Penalties (con’t.)
Administrative Violation Fines (PhP)
Waste Generators
a) Failure to submit a completed copy of the Hazardous Waste Manifest Form to 50,000.00
the DENR
Performs the functions of a TSD Facility without the appropriate TSD Facility Permit 50,000.00
Waste Transporters
a) Conveys or transports hazardous wastes without the proper manifest forms 50,000.00
Conveys or transports hazardous wastes without the proper labels and placards 50,000.00
Conveys or transports hazardous wastes in transports not suitable for the 50,000.00
hazardous waste being transported
TSD Facilities
a) Accepts hazardous wastes without the proper manifest 50,000.00
Stores, recycles, reprocesses, treats or disposes of hazardous wastes at a TSD 50,000.00
facility without the appropriate TSD facility permit
Failure to notify the DENR of the residuals generated as a consequence of its 50,000.00
recycling, reprocessing or treatment activities
Importers and Exporters
a) Importing recyclable materials containing hazardous substances without 50,000.00
securing import clearance from the DENR
Exporting hazardous wastes or materials containing hazardous substances without 50,000.00
securing an export clearance from the DENR
Chapter 13. Schedule of Fees
HAZARDOUS WASTE GENERATORS, TRANSPORTERS AND TSD FACILITIES
Registration of hazardous waste generators PhP1,000.00/generator