ITM Vocational University, Vadodara

Infrared
Spectroscopy

Faculty’s Name – Pavan Karkare

Batch Name – B.Sc(IC)_Batch 2019-22
Session No – II

Infrared Spectroscopy
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 ITM Vocational University, Vadodara

Learning Outcomes

 Infrared spectroscopic instrumentation.

 The working knowledge of spectroscopic
instruments.
 Additionally, it prepares graduates with knowledge
and experience in analytical chemistry for industrial
applications, laboratory analysis and research
studies.

Infrared Spectroscopy
03/18/2
 ITM Vocational University, Vadodara

Energy Diagram

Infrared Spectroscopy
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 ITM Vocational University, Vadodara

Molecular Vibrations:
 Vibrational and rotational energies
increased.
1) Stretching vibrations.
2) Bending vibrations.
1) Stretching vibrations: There is increase or
decrease in bond length between two
atoms, called stretching process and
vibrations arise due to this process is
called stretching vibration.

Operating Systems
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 ITM Vocational University, Vadodara

 Stretching vibrations are of two types:

 a) Symmetrical stretching.
 b) Asymmetrical stretching.

A B A
B B B
Symmetrical stretching Asymmetrical stretching
Infrared Spectroscopy
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 ITM Vocational University, Vadodara

 Bending vibrations: Change in bond angle

with respect to common atom.
 Bending vibrations are of four types:
 a) Scissoring bending
 b) Rocking bending
 c) Wagging bending
 d) Twisting bending

Infrared Spectroscopy
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 ITM Vocational University, Vadodara
Scissoring bending Rocking bending

Bonds come close to each other or

away to each other simultaneously Motion of both bonds in same
there by change in angle. direction.

Wagging bending Twisting bending

With respect to central atom both With respect to central atom, one
atoms move behind or above the atom moves behind plane and
plane simultaneously. another moves above plane.
Infrared Spectroscopy
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 ITM Vocational University, Vadodara

References

 G. H. Jeffery, J. Bassett, J. Mendham and R. C. Denney, Vogel’s

textbook of qualitative chemical analysis, John Wiley & Sons, 1989.
 H. H. Willard, L. L. Merritt, J. Dean and F. A. Settoe, Instrumental
methods of analysis, 7th Ed. Wadsworth publishing company Ltd.,
Belmont, USA, 1988.
 G. D. Christian, Analytical Chemistry, 6th Ed. John Wiley & Sons, New
York, 2004.
 S. M. Khopkar, Basic concepts of Analytical Chemistry, New age,
international publisher, 2009.
 P. S. Kalsi, Spectroscopy of organic compound, New Age international
publishers. 6. R. M. Silverstain, G. C. Bassler and T. C. Morrill,
Spectroscopic identification of organic compounds, John Wiley,
1991.

Infrared Spectroscopy
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 ITM Vocational University, Vadodara

Infrared Spectroscopy
03/18/2