Professional Documents
Culture Documents
2019
Hydrogen Sulfide Safety
COURSE DESCRIPTION
H2S is formed naturally when bacteria break down the sulfur rich
proteins found in dead plants and animals.
H2S is largely associated with the oil and gas industry. It is important to
know what locations in your industry and more specifically at your
locations, where the gas can be found.
Areas
Wellheads or Wellbores
Vessels
Pits and low areas
Shacks, buildings, or containers
Piping systems
Tanks
Confined or enclosed spaces
Production facilities
CLOSED SYSTEMS
Vent Lines
Fittings
Seals
Flanges
Drain or sampling valves
Relief Valves
DRILLING OPERATIONS
Air
H2S
PROPERTIES AND
CHARACTERISTICS
Vapor Density
Flammability- H2S is a highly flammable gas when in
the correct mixture with air. It has a low auto-Ignition
temperature = 5180F (2600C) H2S will burn from 4.3%
to 46% concentrations with Air.
PROPERTIES AND
CHARACTERISTICS
Combustibility
H2S burns with a blue flame
and forms Sulfur dioxide,
another toxic and irritating gas.
Sulfur Dioxide is also heavier
than air and precautions must
be taken to protect against
exposure
ODOR
When discussing
concentrations we
must first consider
that concentration is
relative to the sample
size
5. EXPOSURE LIMITS
EXPOSURE LIMITS
Throat Irritation
Fluid
SIGNS AND SYMPTOMS
Nausea Excitement
Brain damage
Cardiac arrest
SIGNS AND SYMPTOMS
Eye irritation
Headaches
Respiratory tract
irritation
Anorexia
Corneal blistering
Chronic Toxicity
Nausea
Sleep disturbances
VARIABLES
There are many variables which will affect the speed of the onset of
symptoms. The primary variables are exposure concentration, exposure
duration, and individual variables.
Body mass
Age
Personal Biochemistry
Overall physical condition
smoker/non-smoker
Previous exposure to H2S
DRUGS AND ALCOHOL
• Containment
• Dispersion
7. DETECTION EQUIPMENT
DETECTION EQUIPMENT
Manufacturer’s recommendations
should be followed for the
installation, maintenance, calibration,
and repair of detection equipment.
An adequate number of fixed or
portable or both type detectors
should be provided for the safety of
personnel working.
DETECTION EQUIPMENT
Colormetric tubes
Chemical Specific
OXYGEN
SUPPLIED AIR
RESPIRATORS
There are three basic types of Supplied Air Respirators
(SAR).
There are many manufactures of fresh air equipment
on the market here are a few.
Scott and MSA are the two most common
manufacturers and most widely used.
• MSA
• Scott
• Draeger
• ISI
• SurviveAir
• Cairns
ESCAPE UNITS
The escape units are made to be donned very quickly and can
usually be applied using these few steps:
• If In a case , remove from the case
• Loop the strap over your neck or over your shoulder
• Slip hood over your head and tighten if the device has this
option
• Turn on the air cylinder
• Leave the area immediately !!!!
After use, you should clean and air dry the hood. Refill the
cylinder. Return the unit to its proper location. The location of
escape units should have signs alerting personnel to their location.
WORKLINE UNIT
Most newer SCBA’s will have a regulator the connects to the face piece. Face
piece mounted regulators have many benefits compared to belt mounted types:
• Communication is easier
• Less likely to cut or damage low pressure hose
• Easier to shut off air in non hazardous locations which saves air
• Here are a few photos of some face piece mounted regulators
REGULATOR ASSEMBLY
The regulator is equipped with a low air alarm to warn the user. This alarm can be
audible, visual, tactile, or a combination. Audible alarms are usually a bell or
whistle. Visual alarms are usually an LED display in the mask. Tactile alarms are
usually a vibration of the Regulator.
Low air alarms should be set at 25% or 1/4th of the cylinder capacity. They are not
set by minutes because of the varying capacities of cylinders.
REGULATOR ASSEMBLY