Chem 3 ICE Exercises c!

e-γoT 2010

1. NO (g) and O2 (g) were mixed in a container of fixed volume kept at 1000 K. Their initial
concentrations were 0.0200 M for NO and 0.0300 M for O2. When the reaction:
2NO (g) + O2(g)  2NO2(g)
had come to equilibrium, the concentration of NO2 was 2.20 x 10-3 M. Calculate a) the
concentration of NO at equilibrium, b) the concentration of O2 at equilibrium, c) the KEQ
for the reaction

2. At 460C, KP for the reaction:

N2O4 (g)  2NO2(g)
is 0.66. Compute the percent dissociation of N2O4 at 460C and a total pressure of 380
torr in a 1 liter flask. What are the partial pressures of N2O4 and NO2 at equilibrium?

3. At 900C, the following equilibrium is established:

H2(g) + S(s)  H2S(g)
where KEQ = 6.8 x 10 . If 0.20 mol of hydrogen and 1.0 mol of sulfur are heated to 900C
-2

in a 1.0 vessel, what will be the partial pressure of H2S at equilibrium?

4. Given the reaction:

N2O4 (g)  2NO2(g)
Initially, 1.0 mole of NO2 and 1.0 mole of N2O4 are placed in a 1.0-L vessel. At
equilibrium, 0.75 mole of N2O4 is present in the flask. What is the value of KEQ for the
reaction?

5. At 270C and 1.00 atm, N2O4 is 20.0% dissociated into NO2. Find (a) KP (b) the percent
dissociation at 270C and a total pressure of 0.10 atm. (c) What is the extent dissociation
in a 69-g sample of N2O4 confined in a 20-L vessel at 270C?

6. Phosgene is a poisonous gas that dissociates at high temperature into two other
poisonous gases, carbon monoxide and chlorine. The equilibrium constant Kp = 0.0041
at 600°K. Find the equilibrium composition of the system after 0.124 atm of COCl2 is
allowed to reach equilibrium at this temperature.

7. The equilibrium constant of the reaction:

2H+ (aq) + Cu(s)  H2 (g) + Cu2+ (aq)
is 4.7x10-12 at 25oC. Suppose that a strip of pure copper is placed in 100.0 ml of 1.0M
HCl which contains no Cu2+ ions. Assuming that the reaction above actually reaches
equilibrium, calculate the number of grams of Cu which dissolved, assuming P of H2 is
1.0 atm.