Nama: .................................................... Tingkatan: ..............................

SULIT
4541/2
Chemistry
Paper 2
MEI
2008
2 ½ jam
BAHAGIAN SEKOLAH
KEMENTERIAN PELAJARAN MALAYSIA
PEPERIKSAAN PERTENGAHAN TAHUN 2008

FORM 5 CHEMISTRY

Paper 2

Dua jam tiga puluh minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Tuliskan nama dan tingkatan pada

ruang yang disediakan. Bahagian Soalan Markah Markah
2. Jawab semua soalan daripada penuh diperoleh
Bahagian A. Tuliskan jawapan anda 1 10
dalam ruang yang disediakan 2 10
3. Jawab satu soalan daripada Bahagian 3 10
B dan satu soalan daripada Bahagian
A 4 10
C.Jawapan kepada bahagian B dan
Bahagian C hendaklah ditulis pada 5 10
kertas tulis. 6 10
4. Anda diminta menjawab dengan lebih B 7 20
terperinci untuk Bahagian B dan
Bahagian C. Jawapan mestilah jelas
8 20
dan logik. Persamaan, gambar rajah, 9 20
jadual, graf dan cara lain yang sesuai C 10 20
untuk menjelaskan jawapan anda boleh
digunakan. Jumlah
5. Anda hendaklah menyerahkan kertas
tulis dan kertas tambahan, jika
digunakan bersama-sama dengan
kertas soalan.
6. Penggunaan kalkulator saintifik yang
tidak boleh diprogramkan adalah
dibenarkan.

Kertas soalan ini mengandungi 17 halaman bercetak

[lihat sebelah
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1. Figure 1 shows the location of seven elements A, D, E, G, J, L and M in the

Periodic Table. These are not the actual symbols of the elements.

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

A D E G
J
L

Diagram 1

Using the letters in the Periodic Table of the elements in the Diagram 1, answer
the following questions.

(a) (i) Which of the element is chemically unreactive?

………………………………………………………………………………
[1
mark]
(ii) Give one reason for your answer in a(i).

………………………………………………………………………
………
[1 mark]

(b) When a small piece of element A is put into water, alkaline solution is
formed and hydrogen gas is released.

(i) Write the chemical equation for the above statement.

………………………………………………………………………………
[1
mark]

(ii) State one precaution that must be taken while carrying out the experiment
using element A.

………………………………………………………………………………..
[1
mark]

(c) Arrange A, D, E, G, J and L according to the increase in size of the atom.

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………………………………………………………………………………………
[1
mark]
(d) Why are elements A and L placed in the same group?

………………………………………………………………………………………
[1
mark]
(e) Element D reacts with element E to form a compound.

(i) Write the chemical formula of this compound.

……………………………………………………………………
…………
[1
mark]

(ii) Draw the diagram of electron arrangement for the compound that is
formed between D and E.

[2
marks]

(iii) Why the compound in d (ii) cannot conduct electricity in any state.
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…………………………………………………………………………
….
[1 mark]

2. Graph 2.1 shows the temperature against time when solid naphthalene is heated.
Temperature / 0C

Q R
T1

T0 P

Time/s
Graph 2.1

(a) State the melting point of naphthalene.

........................................................................................................................

[ 1 mark]
(b) What is the physical state of naphthalene at:

(i) PQ

.......................................................................................................................
.

(ii) RS
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.......................................................................................................................
.
[ 2 marks]

(c) Explain why there is no change in temperature from Q to R.

.............................................................................................................................
.

.............................................................................................................................
.
[ 2 marks]

(d) State how the movement of naphthalene particles changes between R and S
during heating.

………………………………………………………………………………............
[ 1 mark]

(e) Table 2.2 shows four substances and their respective formulae.

Substances Chemical formula

Iodin I2
Copper Cu
Naphthalene C10H8
Copper(II) sulphate CuSO4

Table 2.2

Use information from table 2.2 to answer the following questions.

(i) State one substance which exist as a molecule.

...........................................................................................................
............
[ 1 mark]

(ii) Which substance can conduct electricity in the solid state?

.................................................................................................................
.......
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[ 1 mark]
(iii) What type of particle presents in copper(II) sulphate?

.......................................................................................................................
.
[ 1 mark]

(f) A few drops of liquid bromine are dropped into a gas jar. The brown
bromine vapour spreads to the upper part of the gas jar. The time taken is very
short.
Name the process occurs.

……………………………………………………………………………................
[ 1 mark]

3. Diagram 3 shows a flow chart for the industrial manufacture of compound Z

from sulphuric acid and ammonia.

Contact Process
Sulphuric acid

Reaction X
Compound Z

Haber Process Ammonia

Diagram 3

(a) (i) Ammonia is produced during Haber process.

Write the chemical equation for the formation of ammonia.

……………………..……………………………………………................
[1 mark]

(ii) What is the source of nitrogen used?

……………………..……………………………………………………....
[1
mark]
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(b) In the above diagram, sulphuric acid reacts with aqueous ammonia to form
compound Z.

(i) Name the reaction X.

...................……………………………………………………….................
[1 mark]

(ii) Write the chemical equation for reaction X.

……………………………………………………………………………....
[1
mark]

(iii) What is the use of compound Z in daily life?

……………………………………………………………………
…............
[1 mark]
(c) − Bronze and pewter are two example of an alloy.
− Bronze is made up of copper as a major component and
other elements.
− Bronze is harder than pure copper.

(i) Name the element added to copper to form bronze.

………………………………………………………………………………
[1 mark]

(ii) Draw an arrangement of the particles in:

pure copper

[1 mark]

bronze
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[1 mark]

(iii) Explain why bronze is harder than pure copper?

.......................................................................................................................
.

.......................................................................................................................
.

.......................................................................................................................
.
[2 marks]

4. A student carried out an experiment to investigate the purification of impure

copper rods.
(a) Draw a labelled diagram to show the apparatus set- up of to carry out this
experiment.
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[3
marks]

(b) The experiment was conducted for 30 minutes.

(i) What would be observed at the electrodes?
Anode:

.......................................................................................................................
.

Cathode:

.......................................................................................................................
[2
marks]
(ii) What happened to the concentration of the electrolyte? Explain.

.......................................................................................................................
.

.......................................................................................................................

.......................................................................................................................
[2
marks]

(c) Write the half equation for the reaction at the anode and the cathode.
i) Anode:

.......................................................................................................................
.
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ii) Cathode:

.......................................................................................................................
.
[2
marks]

(d) State another application of electrolysis.

………………………………………………………………………………………
[1 mark]

5. Table 5 shows the data of two experiments that have been carried out to determine
the rate of decomposition of hydrogen peroxide to water and oxygen gas by using
manganase (IV) oxide as a catalyst.

Experiment Volume of Concentration of hydrogen

hydrogen peroxide /cm3 peroxide /mol dm-3
I 20 2
II 20 4

Table 5
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(a) Write the chemical equation for decomposition of hydrogen peroxide.

…………………………………………………………………………………........
[1 mark]

(b) Calculate the volume of oxygen gas released in experiment I at room

condition. ( 1 mole of gas occupies 24 dm3 at room condition )

[3
marks]
(c) (i) Compare the rate of decomposition of hydrogen peroxide between
experiment I and II.

……………………………………………………………………………....
[1 mark]
(ii) Based on collision theory, explain your answer in (c) (i).

………………………………………………………………………………

………………………
…................................................................................

………………………………………………………………………………

………………………
…................................................................................
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[3
marks]

(d) Sketch the graph of volume oxygen gas against time for experiment I and
experiment II by using the same axis.

[2
marks]

6. Figure 6 shows the conversions of organic compound A to another substances,

C2H4(OH)2 and C2H5OH through Processes A and C.

Reagent B
C2H4(OH)2
Process A
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Compound A

Process C
C2H5OH
Steam
Diagram 6

(a) What is meant by organic compound?

………………………………………………………………………………............

………………………………………………………………………………............
[1
mark]

(b) (i) Write the molecular formula of compound A.

………………………………………………………………………............
[1
mark] (ii) Name the compound A.

………………………………………………………………………............
[1
mark]
(iii) Identify a functional group of compound A.

………………………………………………………………………............
[1
mark]

(c) Compound A reacts with Reagent B to produce substance C2H4(OH)2 through

Process A.
(i) Suggest Reagent B.
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……………………………………………………………………................
[1 mark]

(ii) Name Process A.

………………………………………………………………………............
[1
mark]
(iii) State the observation when the reaction occurs.

………………………………………………………………………............
[1
mark]

(d) Substance C2H5OH is produced when the compound A reacts with steam through
Process C.

(i) Write the equation to show the reaction.

………………………………………………………………………............
[1
mark]
(ii) State the homologous series represented by C2H5OH.

………………………………………………………………………............
[1
mark]
(iii) State one condition that must be used to carry out Process C.

………………………………………………………………………............
[1 mark]
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Section B ( 20 marks )
Answer any one question from this section.
The suggested time to answer section B is 30 minutes.

7. Diagram 7 shows the chemical symbols which represent three elements X, Y and Z
These letters are not the actual symbols of the elements.

23 35 12
X Y Z
11 17 6

Diagram 7

(a) What is meant by:

i) Ionic compound
ii) Covalent compound
[2
marks]
(b) Explain the formation of the bond that is formed between
i) element X and element Y.
ii) element Y and element Z.
[12
marks]

(c) The melting point of magnesium oxide is much higher than methylbenzene.
Explain why.
[6
marks]
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8. (a) What are meant by empirical formula and molecular formula.

[2
marks]

b) A carbon compound has an empirical formula of CH2 and a molar mass is

70 g mol-1, determine its molecular formula.
[Relative atomic mass : H=1 , C=12]
[3
marks]

(c) (i) Metal Z reactively react with oxygen to form Z oxide. Describe the
prosedure to determine the empirical formula of Z oxide. The
procedure
should included a precaution.
[10
marks]

(ii) Diagram 8 shows the result obtain in c(i).

Mass of crucible + lid, g = 46.30

Mass of crucible + lid + Z, g = 46.30
Mass of crucible + lid + Z oxide, g = 46.62

Diagram 8

Based on the information in Table 8, determine the values of the following :

[Relative atomic mass : O=16 , Z=65]

i) mass of lead
ii) number of moles of lead
iii) mass of oxygen
iv) number of moles of oxygen
v) empirical formula of lead oxide
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[5
marks]

Section C ( 20 marks )
Answer any one question from this section.
The suggested time to answer section C is 30 minutes.

9.(a) Write two balanced chemical equation to show the chemical properties of
an acid.
[2 marks]
Diagram 9 shows the structural formula of methanoic acid.

H C O H

Diagram 9

(b) (i) Explain why methanoic acid is a weak acid.

[2 marks]
(ii) Glacial methanoic acid does not conduct electricity but the aqueous
methanoic acid does. Explain.
[3 marks]
(c) You are required to prepare a dry zinc(II) sulphate using 100 cm3
sulphuric acid 0.1 mol dm-3.
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(i) Describe the laboratory experiment to prepare the dry of zinc(II)

sulphate
[7
marks]
(ii) Calculate the mass of dry zinc sulphate formed.
[Relative atomic mass: H=1, O=16, S=32, Zn=65]
[4 marks]
(d) Give two examples of salt and the uses in daily life.
[2 marks]
10. Diagram 10.1 shows how compound M is formed from ethanoic acid and
propanol.

ethanoic acid + propanol

Concentrated
H2SO4
Compound M

Diagram 10.1

(a) Based on the information given,

(i) what is the role of concentrated sulphuric acid, H2SO4 in this reaction.
(ii) name the reaction for the preparation of compound M.
(iii) write the chemical equation for the reaction of propanoic acid with ethanol
(iv) draw structural formula and give name for compound M.
(v) state two special characteristics for compound M.
(vi) draw the structures of the two isomers of propanol.
[10
marks]
(b) Table 10.2 shows the results of latex coagulation.

Procedure Observations

Latex is left under natural Latex coagulates

condition
Ammonia solution is added to Latex does not coagulate
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latex

Table 10.2

(i) Explain why there is a difference in this observation.

[6
marks]
(ii) Explain how vulcanization of rubber can improve the weakness of natural
rubber.
[4
marks]
END OF QUESTION PAPER