Chng 8

DN XUT HALOGEN ANCOL PHENOL

I. Cu hi, bi tp t lun 1. Vit phng trnh ho hc ca cc phn ng xy ra theo s sau :
+H2O

A B
+KOH/C2H5OH

C 2 H4

+Cl2

to,xt

(polime)

2. Vit phng trnh ho hc ca cc phn ng xy ra theo s sau :

NaHCO 3 Mg / ete CO2 HCl CH3Cl + X + Y + Z + CH3COONa

3. Thc hin dy chuyn ho sau bng phng trnh ho hc, cc phn ng din ra theo t l mol 1:1, cc cht sau phn ng u l sn phm chnh.
+Br 2 Fe

KOH C to cao ; p cao KOH/C2H5OH to Br2/H2O KOH/H2O to

C3H7-C6H5
+Br 2 as

4. Vit cu to tt c cc ancol bc ba c cng thc C6H13OH. Gi tn 5. T but-1-en vit cc phng trnh ho hc iu ch 3-metylheptan-3-ol. 6. Tm cng thc cc cht hu c ng vi cc ch ci trong s sau v vit cc phng trnh ho hc gii thch.
600 C HCl Than + vi B A D E F than
2 4 NaOH I H 170oC o

+ Cl2 G

H SO

Bit cht E khng cha oxi, khi t chy hon ton E cn 3,808 dm 3 O2 (ktc), sn phm nhn c c 0,73 gam HCl, cn CO 2 v H2O to ra theo t l th tch VCO2 : VH2O = 6 : 5 (cng iu kin). 7. Vit phng trnh ho hc thc hin dy bin ho sau (ghi r iu kin phn ng) : C2H5Cl C2H5OH C2H5ONa 8. Vit cc phng trnh ha hc v ghi r iu kin (nu c) khi cho glixerol ln lt tc dng vi tng cht : Na, axit HNO 3, Cu(OH) 2.

9. C hn hp 3 cht hu c : C 6H6 ; C2H5OH ; CH 3COOC2H5, nu phng php tch ring tng cht, vit cc phng trnh ha hc. 10. Vit phng trnh ho hc ca cc phn ng xy ra chng t rng : a) T etilen iu ch c poli (vinyl clorua). b) C th dng Cu(OH) 2 phn bit etanol v etylen glycol. 11. a) Vit cng thc cu to thu gn ca cc cht sau : isopropyl bromua, propan-2-ol, isopropylbenzen, -naphtol. 12. Vinyl clorua, ancol etylic, phenol l nhng cht quan trng trong cng nghip ho cht. Vit cc phng trnh ho hc iu ch chng t cc hirocacbon thch hp. 13. Nu hin tng v vit phng trnh ho hc gii thch trong cc trng hp sau : a) Nh dung dch brom vo alyl clorua. b) Nh tng git dung dch axit clohiric vo dung dch natri phenolat. c) B mt mu nh natri vo ng nghim ng glixerol d) Lc dung dch kali pemanganat vi stiren. 14. a) Vit cng thc cu to v gi tn ca cc ancol thm v phenol c cng thc C7H8O. b) Vit phng trnh ho hc ca phn ng xy ra (nu c) ca cc cht trn vi NaOH, CuO (nung nng nh). 15. C bn l ng 4 cht lng : alyl clorua, phenyl clorua, phenol, ancol benzylic. Trnh by phng php ho hc phn bit chng. 16. Cho cc cht sau : C 2H5OH, C 6H5OH, dung dch CH 3COOH, dung dch C 6H5ONa, dung dch CH 3COONa, dung dch NaOH, dung dch Na 2CO3. Nhng cp cht no tc dng c vi nhau ? Vit cc phng trnh ha hc. 17. Vit cc phng trnh ha hc cho cc phn ng sau : C 6H5OH tc dng vi dung dch NaOH, vi nc brom. 18. Vit cc phng trnh ho hc ca phn ng chng t phenol c tnh axit, nhng l axit yu. 19. Nu hin tng v vit phng trnh ho hc gii thch trong cc trng hp sau : a) Lc stiren vi dung dch thuc tm (d). b) Nh tng git dung dch Na 2CO3 vo phenol (rn). c) Nh mt git dung dch natri phenolat ln mu giy qu tm. d) un benzyl clorua vi dung dch NaOH. 20. Vit cng thc cu to v gi tn cc hp cht thm c cng thc C 7H8O.

21. C bn l ng 4 cht lng : toluen, phenyl clorua, phenol, ancol benzylic. Trnh by phng php ho hc phn bit chng, vit cc phng trnh ho hc. 22. Bng nhng phn ng ho hc no chng minh c phenol c tnh axit, nhng rt yu. Vit cc phng trnh ho hc ca cc phn ng . 23. t chy hon ton a gam mt ancol n chc, mch h ri dn sn phm ln lt qua bnh ng H 2SO4 c v bnh ng KOH. Kt thc phn ng thy bnh ng axit tng 4,5 gam, bnh ng kim tng 8,8 gam. Tnh a v xc nh cng thc phn t ca ancol. 24. T 0,5 tn tinh bt cha 5% tp cht tr, ngi ta sn xut c 270 lt etanol tinh khit (D = 0,8 g/ml). Tnh hiu sut chung ca qu trnh sn xut ? 25. Cho 11,5 gam Na vo cc cha 12,4 gam hn hp hai ancol n chc, k tip nhau trong dy ng ng, kt thc phn ng trong cc cn li 23,6 gam cht rn. Xc nh cng thc phn t ca hai ancol. 26. Hn hp X gm 2 ancol n chc thuc cng mt dy ng ng. t chy m gam hn hp X thu c 4,4g CO 2 v 2,7g H2O. Xc nh cng thc phn t v vit cng thc cu to ca hai ancol, bit trong X hai ancol c s mol bng nhau. 27. Mt hn hp gm C 2H5OH v mt ankanol A. t chy cng s mol ca mi ancol th lng nc sinh ra t ancol ny bng 5/3 lng nc sinh ra t ancol kia. Nu un nng hn hp cc ancol trn vi H 2SO4 m c 180 0C th ch thu c hai olefin. Xc nh cng thc phn t ca A v cng thc cu to ca hai ancol. 28. un hn hp ba ancol X, Y, Z (u c phn t khi ln hn 32) vi H 2SO4 c 1700C thu c hn hp hai olefin l ng ng lin tip. un hn hp gm X, Y vi H2SO4 c 140 0C c 1,32 gam hn hp ba ete. Mt khc lm bay hi 1,32 gam ba ete ny c th tch ng bng th tch ca 0,48 gam oxi (o cng iu kin). Xc nh cng thc cu to ca ba ancol X, Y, Z. 29. Hn hp A cha gilxerin v hai ancol no n chc k tip nhau trong dy ng ng. Cho 8,75 g hn hp A tc dng vi natri d thu c 2,52 lt H 2 (ktc). Mt khc 14,00 gam hn hp A ho tan va ht 3,92 gam Cu(OH) 2. Xc nh cng thc phn t ca hai ancol n chc trong hn hp A. 30. Hn hp A gm phenol v ancol benzylic. Cho m gam A tc dng vi Na , d thy thot ra 0,336 lt kh hiro (ktc). Mt khc, m gam A tc dng ht vi dung dch brom, thu c 6,62 gam kt ta trng. Vit phng trnh ho hc ca cc phn ng xy ra v tnh m.

II. Cu hi, bi tp trc nghim khch quan 1. Dy cht c xp theo th t tng dn nhit si l A. CCl4 ; CHCl3 ; CH 3Cl ; CH 3F ; CH 4 B. CH 3Cl ; CHCl ; CCl 4 ; CH 3F ; CH 4 C. CH 4 ; CH 3F ; CH 3Cl ; CHCl 3 ; CCl4 D. CH 4 ; CCl4 ; CHCl ; CH 3Cl ; CH 3F 2. nhn bit cc cht CH 3 CH2 Cl ; CH 3 CH2 Br ; CH 3CH2I, ngi ta dng A. bt Mg (xc tc : ete khan). . C. dung dch NaOH B. dung dch AgNO 3. D. dung dch HBr.

3. phn bit ba l ng ba cht l butyl clorua; anlyl clorua, m-iclobenzen, ngi ta dng A. dung dch AgNO 3. B. dung dch NaOH v dung dch brom. C. dung dch NaOH v dung dch AgNO 3. D. dung dch brom. 4. Teflon l mt polime bn vi nhit ti trn 300 oC nn c dng lm lp che ph chng bm dnh cho xoong, cho, thng cha. Teflon c tng hp t A. CH 2 = CHCl. B. CHF = CHF. C. CH 2 = CHF. D. CF 2 = CF 2.

5. Phng php iu ch no di y gip ta thu c 2clobutan tinh khit hn c? A. Butan tc dng vi Cl 2, chiu sng, t l 1:1. B. But2en tc dng vi hiro clorua C. But1en tc dng vi hiro clorua D. Buta1,3ien tc dng vi hiro clorua D. Ch c mt cht c kh nng lm mt mu dung dch brom. 6. Hi c bao nhiu cht ring l c thnh phn C3H5Cl v c mt lin kt i (k c cc ng phn hnh hc)? Vit cng thc cu to ca phn t cc cht A. 1 cht B. 4 cht C. 3 cht D. 2 cht 7. Hi c th thu c bao nhiu anken khi tch hiroclorua ra khi tt c hp cht ng phn c thnh phn C 4H9Cl ? A. 1 anken B. 2 anken C. 3 anken D. 4 anken

8. Hi 1,1-ibrombutan tc dng hon ton vi dung dch ancol ca kali hiroxit to nn hp cht hu c g? A. CH 3 CH2CH2CH2OH C. CH C CH2CH3 A. 2. B. 3. B. CH 3 CH2CH2CHO D. CH 3 CH= CH CH3 C. 4. D. 5.

9. C bao nhiu ng phn mch h cng c cng thc phn t C 4H9Br? 10. Khi cho pentan tc dng vi clo thu c A. hai dn xut monoclo ng phn ca nhau. B. ba dn xut monoclo ng phn ca nhau. C. bn dn xut monoclo ng phn ca nhau. D. nm dn xut monoclo ng phn ca nhau. 11. Khi buta-1,3-ien tc dng vi brom (trong CCl 4) thu c my ng phn c cng thc phn t C 4H6Br2? A. 1. B. 2. C. 3. D. 4. 12. Khi penta-1,3-ien tc dng vi brom (trong CCl 4) thu c my ng phn c cng thc phn t C 5H8Br2? A. 1. A. etanol. B. 2. B. propan-1-ol. C. 3. C. propan-2-ol. D. 4. D. propilen. 13. Khi un nng 2-clopropan vi dung dch NaOH to ra 14. Kh nng phn ng th nguyn t halogen ca cc cht gim dn theo th t A. CH 3CH2CH2I < CH 3CH2CH2Br < CH 3CH2CH2Cl < CH 3CH2CH2F. B. CH 3CH2CH2Cl > CH 3CH2CH2Br > CH 3CH2CH2I > CH 3CH2CH2F. C. CH 3CH2CH2F < CH 3CH2CH2Cl < CH 3CH2CH2Br < CH 3CH2CH2I. D. CH 3CH2CH2Cl > CH 3CH2CH2Br > CH 3CH2CH2I > CH 3CH2CH2F. 15. Cho cc cht CH 3Cl, CH 3Br, C2H5Br v C 2H5I. Chiu tng dn nhit si ca cc cht l A. CH 3Cl > CH 3Br > C2H5Br > C2H5I. B. CH 3Cl < CH 3Br < C2H5Br < C2H5I. C. CH 3Br < C2H5Br < CH3Cl < C2H5I. D. C2H5I > C2H5Br > CH 3Br > CH3Cl. 16. Cho cc cht sau y: C 2H5Br, CH 2=CHCH 2Br, C6H5Br v CH 2=CHBr. Kh nng tham gia phn ng th nguyn t brom ca cc cht tng dn theo dy cht no di y? A. CH 2=CHCH 2Br < C2H5Br < CH 2=CHBr < C6H5Br .

B. C2H5Br < CH 2=CHCH 2Br < C6H5Br < CH 2=CHBr. C. C2H5Br > CH 2=CHCH 2Br > C6H5Br > CH 2=CHBr. D. CH 2=CHBr < C6H5Br < C2H5Br < CH 2=CHCH 2Br. 17. Khi cho but-1-en tc dng vi HBr thu c sn phm chnh l A. 1-brombutan. C. 3-brombutan. B. 2-brombutan. D. hn hp 1-brombutan v 2-brombutan.

18. un nng 3,57 gam hn hp A gm propyl clorua v phenyl clorua. vi dung dch NaOH long, va , sau thm tip dung dch AgNO 3 n d vo hn hp sau phn ng thu c 2,87 gam kt ta. Khi lng phenyl clorua c trong hn hp A l A. 1,00 gam. B. 1,57 gam. C. 2,00 gam. D. 2,57 gam. 19. un si hn hp gm C 2H5Br v KOH d trong C 2H5OH, sau khi phn ng xy ra hon ton, dn kh sinh qua dung dch brom d, thy c 8 gam Br 2 tham gia phn ng. Khi lng C 2H5Br em phn ng l A. 1,400 gam B. 2,725 gam C. 5,450 gam D. 10,900 gam 20. un nng 2,740 gam CH 3CHBrCH 2CH3 vi KOH d trong C 2H5OH, sau khi phn ng xy ra hon ton thu c hn hp kh X gm hai olefin trong sn phm chnh chim 80%, sn phm ph chim 20%. t chy hon ton X thu c bao nhiu lt CO2 (ktc)? A. 0,448 lt B. 0,896 lt C. 1,120 lt D. 1,792 lt 21. X l dn xut monoclo ca mt ankan. Trong phn t X, phn trm khi lng clo bng 45,22%. X c cng thc phn t l A. CH 3Cl. B. C 2H5Cl . C. C3H7Cl. D. C4H9Cl. 22. Khi thy phn dn xut monoclo X ca mt ankan thu c ancol Y. T khi hi ca X so vi Y xp x bng 1,31. Cng thc phn t ca X l A. C2H5Cl. B. C3H7Cl. C. C4H9Cl. D. C3H5Cl. 23. un dn xut clo X vi dung dch kali hiroxit trong etanol thu c anken Y. t chy 2,24 lit Y (ktc) thu c 8,80 gam kh CO 2. Cng thc phn t ca X l A. C2H5Cl. B. C 3H7Cl. C. C4H9Cl. D. C3H5Cl. 24. un si 6,45 gam mt dn xut monoclo X trong dung dch NaOH d n khi phn ng hon ton. Axit ha dung dch bng axit HNO 3 sau thm vo dung dch mt lng d AgNO 3 thy c 14,35 gam kt ta. Cng thc phn t ca X l A. CH 3Cl. B. C 2H3Cl. C. C2H5Cl. D. C 3H7Cl. 25. Theo danh php IUPAC, hp cht (CH 3)2C=CHCH 2OH c tn gi l A. 3metylbut2en1ol. C. pent2en1ol. B. 2metylbut2en 4ol. D. ancol isopent2en1ylic.

26. Cht hu c X c cng thc phn t C 4H10O. S lng cc ng phn ca X c phn ng vi Na l A. 4. B. 5. C. 6 D. 7 27. Ch dng cc cht no di y c th phn bit hai ancol ng phn c cng cng thc phn t C 3H7OH? A. Na v H 2SO4 c. C. CuO v dung dch AgNO 3/NH3 A. 2. B. 3. B. Na v CuO. D. Na v dung dch AgNO 3/NH3 C. 4. D. 5.

28. C bao nhiu ng phn ancol bc 2 c cng cng thc phn t C 5H12O? 29. C bao nhiu ng phn c cng cng thc phn t C 5H12O khi oxi ha bng CuO (t 0) to sn phm c phn ng trng gng? A. 2. B. 3. C. 4. D. 5. 30. Etanol b tch nc 140 0C (xc tc H 2SO4 c) thu c sn phm chnh c cng thc l A. C2H5OC2H5. C. CH 2=CHCH=CH 2. B. C2H4. D. C2H5OSO3H.

31. Mt ancol no, a chc X c cng thc tng qut: C xHyOz (y=2x + z). X c t khi hi so vi khng kh nh hn 3 v khng tc dng vi Cu(OH) 2. X ng vi cng thc no di y? A.HOCH 2CH 2OH. C. CH 2(OH)CH(OH)CH 2(OH) B. CH 2(OH)CH(OH)CH 3. D. HOCH 2CH2CH2OH.

32. Chiu gim dn linh ng ca nguyn t H (t tri qua phi) trong nhm OH ca ba hp cht C 6H5OH, C2H5OH, H2O l A. HOH, C 6H5OH, C2H5OH. C. C2H5OH, C6H5OH, HOH. B. C6H5OH, HOH, C 2H5OH. D. C2H5OH, HOH, C 6H5OH.

33. Khi un nng CH3CH2CHOHCH 3 (butan2ol) vi H 2SO4 c, 170 oC th sn phm chnh thu c l cht no sau y? A. but 1 en. C. ietyl ete. 34. Cho s phn ng sau:
H2SO4 d c,180 C HBr NaOH But-1- en X Y Z H2O
0

B. but 2 en. D. but1en v but2en c t l th tch l 1:1.

Bit X, Y, Z u l cc hp cht hu c v l nhng sn phm chnh ca tng giai on. Cng thc ca X, Y, Z ln lt l
H 3C CH Br CH 2 CH3 ; H3 C CH OH CH2 CH3 ; H 3 C CH CH CH3

A.

H 2C

CH 2 CH 2 CH 3

; H 2C
OH

CH 2

CH2

CH 3

; H 2C

CH

CH2

CH3

B.

Br

H 3C

CH Br

CH 2 CH 3

; H 3C

CH OH

CH2

CH 3

; H 2C

CH

CH 2

CH 3

C.

CH2 H 3C CH Br CH 2 CH 3

CH 3 CH 3

; H 3C

CH OH

CH 2 CH 3

; H 3C

CH

CH

D.

CH 2 CH 3

35. Cho dy chuyn ha sau:

H2SO4 , d c170 C H2O,H2SO4l CH3CH2CH2OH X Y
0

Bit X, Y l sn phm chnh. Vy cng thc cu to ca X v Y ln lt l A. CH 3CH=CH 2, CH 3CH2CH2OH. C. CH 3CH=CH 2, CH 3CH(OH)CH 3. B. CH 3CH=CH 2, CH 3CH2CH2OSO 3H. D. C3H7OC3H7, CH 3CH2CH2OSO3H.

36. Khi cho etanol i qua hn hp oxit ZnO v MgO 450 oC th thu c sn phm chnh c cng thc l A. C2H5OC2H5. C. CH 2=CHCH 2CH 3. B. CH 2=CHCH=CH 2. D. CH 2=CH2.

37. Cht X c cng thc phn t C 4H10O. Bit khi oxi ho X bng CuO (to) th thu c cht hu c Y c kh nng tham gia phn ng trng gng. Mt khc khi cho anken to ra t X hp nc (H+) th cho mt ancol bc 1 v mt ancol bc 2. X c cng thc cu to no di y
OH H 3C C CH 3 CH 3

H 2C

CH 2

CH 2

CH3

A.
H 3C

B.
CH 2 CH3

OH

CH OH

H 3C

CH CH 3

CH 2

OH

C.

D.

38. Cht hu c X cha cc nguyn t C, H, O. Cho X tc dng vi H 2 d c mt Ni, un nng, thu c cht hu c Y. un Y vi H 2SO4 c 170 oC thu c cht hu c Z. Trng hp Z thu c poliisobutilen. Cng thc cu to ca X l A. CH 2=CHCH(CH 3)OH. C. CH 3CH(CH 3)CH 2OH. B. CH 2=C(CH 3)CH 2OH. D. CH 2=CHCH 2CH2OH.

39. un nng 2,3imetylpentan2ol vi H 2SO4 c, 170 oC, sau phn ng thu c sn phm chnh l cht no sau y? A. CH 2=CHCH(CH 3)CH(CH 3)2.B. CH 3CH=C(CH 3)CH(CH 3)2. C. C2H5CH(CH 3)C(CH 3)=CH 2. D. (CH 3)2C=C(CH 3)CH 2CH3. 40. t chy hon ton mt ete n chc thu c H 2O v CO 2 theo t l s mol 4: 3. Ete ny c th c iu ch t ancol no di y bng mt phng trnh ha hc? A. CH 3OH v CH 3CH2CH2OH. C. CH 3OH v CH 3CH2OH. B. CH 3OH v CH 3CH(CH 3)OH. D. C2H5OH v CH 3CH2CH2OH.

41. Khi cho 2,2imetylpropanol tc dng vi HCl thu c sn phm chnh l cht no sau y? A. 1Clo2,2imetylpropan. C. 2Clo3metylbutan. B. 3Clo2,2imetylpropan. D. 2Clo2metylbutan.

42. Mt trong nhng cch phn bit bc ca cc ancol l s dng thuc th Lucas. Thuc th l hn hp ca: A. dung dch CuSO 4 v NaOH. C. HCl c v ZnCl 2 khan. B. dung dch AgNO 3/NH3 d. D. H 2SO4 m c v ZnCl 2 khan.

43. Phng php tng hp ancol etylic trong cng nghip thch hp nht l phng php no sau y?
+ Cl (askt) H (Ni, t ) + H 2 O (OH ) A. C2H4 + C2H6 C2H 5Cl C2H5OH
2 0

+ H (Pd, t ) + H O (t , p) B. CH 4 t C2H2 C 2 H 4 C2H 5OH

0

H O (H , t , p) C. C2H4 + C 2H 5OH
2 0

+ NaOH, t C 2H 5 Cl D. C2H4 +HCl C 2 H5 OH

0

44. Cho cc ancol sau: CH3CH 2CH2OH (1) CH3CH(OH)CH 3 CH3CH(OH)C(CH 3)3 (2) (4) D. (2), (3). CH3CH(OH)CH 2OH (3) A.(1), (2). A. 2. A. 2.

Dy gm cc ancol khi tch nc ch cho 1 olefin duy nht l B. (1), (2), (3). B. 3. B. 3. C. 4. C. 5. C. (1), (2), (4). D. 5. D. 7. 45. C bao nhiu ancol mch h ng phn ca nhau c cng cng thc phn t C 4H10O? 46. Ancol 2-metylbutan-1-ol c my ng phn cng chc? 47. Trong cc ancol ng phn ca nhau c cng thc phn t C 5H12O, c my ancol bc mt?

A. Hai.

B. Ba.

C. Bn.

D. Nm.

48. Ancol no mch h. n chc c phn trm khi lng oxi bng 26,67%. Cng thc phn t ca X l A. C2H6O. B. C3H8O . C. C2H4O2. O H ... O H C2H5 C2H5 O H ... O H H H D. C4H10O. 49. Trong hn hp etanol v nc, kiu lin kt hiro no l bn nht? O H ... O H C2H5 H O H ... O H H C2H5

A.

B.

C.

D.

50. Khi butan-2-ol tch nc sinh ra my anken ng phn (cu to v lp th) ca nhau? A. Hai. B. Ba. C. Mt. D. Bn. 51. Trong s cc ancol ng phn ca nhau c cng thc phn t C 4H10O2 c my cht tc dng c vi Cu(OH) 2? A. Hai cht. B. Ba cht. C. Bn cht. D. Nm cht. 52. Khi tch nc ca ancol X C 5H12O thu c hn hp 2 anken ng phn cu to ca nhau c mch cacbon khng nhnh. Tn ca X l A. pentan-1-ol. C. 2-metylbutan-2-ol. B. penta-2-ol. D. 3-metylbutan -2-ol

53. Khi un hn hp 3 ancol vi axit H 2SO4 c c th sinh ra bao nhiu ete khc nhau v cng thc phn t? A. Ba cht. B. Bn cht. C. Nm cht. D. Su cht. 54. TBME l t vit tt ca mt ete dng trong nhin liu (tn gi y l tert-butyl metyl ete). Cng thc cu to no di y l ca TBME? A. CH3OCH(CH 3)2 C. CH3OC(CH 3)3 B. CH 3OCH2CH2CH3 D. CH 3OCH2CH2CH2CH3

55. un nng ancol no mch h X vi hn hp KBr v H 2SO4 c (ly d) thu c cht hu c Y (cha C, H, Br). Bit 12,3 gam Y c th tch bng th tch ca 2,8 gam N 2 cng iu kin. X c cng thc cu to l A. CH 3OH C. CH 3CH(OH)CH 3. B. C2H5OH. D. CH 2=CHCH 2OH.

56. Cho 28,4 gam hn hp X gm 2 ancol n chc, l ng ng k tip nhau tc dng va vi Na to ra 46 gam cht rn v V lt kh H 2 (ktc). V c gi tr l A. 22,4 lt B. 11,2 lt C. 17,92 lt D. 8,96 lt

57. un nng m 1 gam ancol no, n chc X vi H 2SO4 c nhit thch hp thu c m 2 gam cht hu c Y. T khi hi ca Y so vi X bng 0,7. Hiu sut ca phn ng t 100%. X c cng thc phn t l A. C2H5OH. B. C3H7OH. C. C4H9OH. D. C5H11OH. 58. un nng ancol no, n chc A vi hn hp KBr v H2SO4 c thu c cht hu c Y (cha C, H, Br), trong Br chim 73,4% v khi lng. Cng thc phn t ca X l A. CH 3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. 59. un nng m 1 gam ancol no, n chc A vi H 2SO4 c nhit thch hp thu c m 2 gam cht hu c B. T khi hi ca B so vi A bng 1,4375. Hiu sut ca phn ng t 100%. Cng thc phn t ca A l A. CH 3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. 60. X, Y l hai ancol no, n chc, k tip nhau trong dy ng ng. Cho hn hp gm 1,6 gam X v 2,3 gam Y tc dng ht vi Na thu c 1,12 lt H 2 ( ktc). X, Y c cng thc phn t ln lt l? A. CH 3OH v C 2H5OH C. C3H7OH, C4H9OH B. C2H5OH, C3H7OH D. C4H9OH, C5H11OH.

61. un 13,28 gam hn hp 3 ancol no, n chc vi H 2SO4 c 140 0C thu c hn hp cc ete c s mol bng nhau v c khi lng l 11,12 gam. S mol ca mi ete trong hn hp l gi tr no sau y? A. 0,01 mol B. 0,02 mol C. 0,03 mol D. 0,04 mol 62. t chy hon ton m (g) hn hp X gm hai ancol A v B thuc cng dy ng ng thu c 67,2 lt CO 2 v 76,5 gam H 2O. Mt khc khi cho m (g) hn hp X tc dng vi Na d thu c 28 lt H 2. Bit t khi hi ca mi cht so vi hiro u nh hn 40, cc th tch kh o ktc. A v B c cng thc phn t ln lt l A. C2H6O, CH 4O. C. C2H6O2, C3H8O2 B. C2H6O, C3H8O. D. C3H6O, C4H8O.

63. Hn hp X gm ancol metylic v ancol no, n chc A. Cho 0,76 gam X tc dng vi Na d thu c 0,168 lt H 2 (ktc), mt khc oxi ha hon ton 0,38 gam X bng CuO (t 0) ri cho ton b sn phm thu c tc dng vi dung dch AgNO 3/NH3 d thu c 1,08 gam kt ta. Cng thc phn t ca A l A. C2H5OH. C. CH 3CH(CH 3)OH. B. CH 3CH2CH2OH. D. CH 3CH2CH2CH2OH.

64. Hn hp X gm ancol metylic v mt ancol no, n chc A, mch h. Cho 1,38 gam X tc dng vi Na d thu c 0,336 lt H 2 (ktc), mt khc oxi ha hon ton 2,76

gam X bng CuO (t 0) thu c hn hp anehit. Cho ton b lng anehit ny tc dng vi dung dch AgNO 3/NH3 d thu c 19,44 gam cht kt ta. Cng thc phn t ca A l A. C2H5OH. C. CH 3CH(CH 3)OH. B. CH 3CH2CH2OH. D. CH 3CH2CH2CH2OH.

65. Hn hp X gm 2 cht hu c k tip nhau trong cng dy ng ng, phn t ca chng ch c mt loi nhm chc. Chia X lm 2 phn bng nhau. Phn 1: em t chy hon ton ri cho ton b sn phm chy (ch c CO 2 v hi H 2O) ln lt qua bnh (1) ng dung dch H 2SO4 c, bnh (2) ng dch Ca(OH) 2 d, thy khi lng bnh (1) tng 4,32 gam, bnh (2) c 14 gam kt ta. Phn 2: cho tc dng ht vi Na d th th tch kh H 2 (ktc) thu c l bao nhiu? A. 4,48 lt B. 0,448 lt C. 1,12 lt D. 2,24 lt 66. un hn hp X gm 2 ancol A, B no, n chc, l ng ng k tip nhau vi H 2SO4 c 170 oC thu c hn hp 2 olefin c t khi so vi X bng 0,66. X l hn hp 2 ancol no di y? A. CH 3OH v C 2H5OH C. C3H7OH v C 4H9OH B. C2H5OH v C 3H7OH D. C4H9OH v C 6H11OH

67. X l ancol no, a chc, mch h. Khi t chy hon ton 0,1 mol X cn 0,35 mol O 2. Vy cng thc ca X l A. C3H6(OH)2. B. C3H5(OH)3. C. C4H7(OH)3. D. C2H4(OH)2. 68. Cho 6,9 gam hn hp ancol propylic v ancol n chc B tc dng vi Na d, sau phn ng thu c 1,68 lt H 2 (ktc). B l ancol no di y? A. CH 3OH B. C2H5OH C. C3H7OH D. C3H5OH 69. Cho m gam hn hp X gm 2 ancol no, n chc k tip nhau trong cng dy ng ng tc dng vi Na d thu c 0,448 lt H 2 (ktc). t chy hon ton m gam X thu c 2,24 lt CO 2 (ktc). Cng thc phn t ca hai ancol l A. CH 3OH v C 2H5OH C. C3H5OH v C 4H7OH B. C2H5OH v C 3H7OH D. C3H7OH v C 4H9OH

70. Khi un hn hp 2 ancol no n chc k tip nhau trong dy ng ng vi axit H2SO4 thu c hn hp 3 ete. Ete c phn t khi ln nht c t khi so vi ancol c phn t khi nh hn gn bng 2,31. Hai ancol l A. metanol v etanol. C. metanol v propanol. B. etanol v propanol. D. propanol v butanol.

71. Khi un nng ancol X no, n chc. mch h vi axit H 2SO4 c thu c cht hu c Y. T khi hi ca X so vi Y bng 1,32. Cng thc phn t ca X l

A. CH 4O.

B. C2H6O.

C. C3H8O.

D. C4H10O.

72. Cho cht hu c Y c cng thc phn t C 8H10O. Y phn ng vi CuO un nng to thnh hp cht c kh nng phn ng trng gng v Y tha mn s chuyn ha sau:
( 2) Y (1) Y1 Polistiren

Cng thc cu to ca Y l.
CH2 CH2 OH H3C CH OH

A.

CH2 OH

B.
O CH 2 CH 3

CH 3 C. D. 73. C hai ng nghim mt nhn cha tng cht ring bit l dung dch ancol but 1ol (ancol butylic) v dung dch phenol. Nu ch dng mt ha cht nhn bit hai cht trn th ha cht l

A. H 2O

B. dung dch brom. C. qu tm.

D. natri kim loi.

74. C bao nhiu ng phn l hp cht thm c cng thc phn t C 8H10O tc dng c vi Na, khng tc dng vi NaOH v khng lm mt mu dung dch Br 2? A. 4 A. 2 B. 5 B. 3 C. 6 C. 4 D. 7 D. 5 75. C bao nhiu ng phn l hp cht thm c cng thc phn t C 7H8O? 76. X l hp cht thm c cng thc phn t C 7H8O. S ng phn ca X c phn ng vi NaOH l A. 2 B. 3 C. 4 D. 5 77. C bn ng nghim mt nhn ng ring bit cc cht lng khng mu gm NH4HCO3; NaAlO 2; C6H5ONa; C 2H5OH. Ch dng mt ha cht no sau y phn bit bn dung dch trn? A. Dung dch NaOH. C. Kh CO 2. B. Dung dch HCl. D. Dung dch BaCl 2.

78. C 3 cht lng khng mu ng trong cc l mt nhn: ancol etylic, phenol, axit fomic. nhn bit 4 dung dch trn c th dng cc thuc th no di y? A. Qu tm v dung dch NaOH. B. Dung dch NaHCO 3 v Na.

C. Qu tm v dung dch NaHCO 3. 79. Phenol l mt hp cht c tnh A. baz yu. A. benzen. B lng tnh. B. toluen.

D. Cu(OH) 2 v Na. C. axit mnh. D. axit yu.

80. Trong cng nghip, phenol c iu ch t C. isopropylbenzen. D. stiren.

III. Hng dn gii p n 1. - Cc phng trnh ho hc

H C2H4 + H 2O CH3CH2OH
+

CH2=CH 2 + Cl2 CH2Cl-CH 2Cl

C2H5OH,t CH2Cl-CH 2Cl + KOH CH2=CHCl + KCl + H 2O
o

nCH2=CHCl

p, to,xt

CH2 - CH n Cl

2. - Cc phng trnh phn ng ho hc :

ete CH3Cl + Mg CH3MgCl

CH3MgCl + CO 2 CH 3-CO-OMgCl CH3COOMgCl + HCl CH3COOH + MgCl 2 CH3COOH + NaHCO 3 CH3COONa + CO 2 + H 2O 3. Cc phng trnh ha hc :
CH2 (A) CH2 CH3 + Br 2
Fe, o t

Br

CH2 (B)

CH2

CH3 + HBr

Br

CH2 (B)

CH2

CH3 + KOH

HO

CH2 (C)

CH2

CH3 + KBr

as C6H5CH 2CH 2CH 3 + Br 2 C6H5CHBrCH 2CH3 + HBr

(A)

(D)
KOH /C H OH

2 5 C6H5CHBrCH2CH3 + KOH C6H5CH=CHCH3 + KBr + H2O to

(D)

(E)

 C6H5CHBrCHBrCH 3 C6H5CH=CHCH 3 + Br2 (E) (F) C6H5CH(OH)CHBrCH 3 + KBr C6H5CHBrCHBrCH 3 + KOH (F) (G) R' | 4. Ancol bc ba c dng R C R '' . Tng R + R + R l C5H13 c hai kh nng: | OH (CH 3 + C2H5 + C2H5) hoc (CH 3 + CH 3 + C3H7), trong C3H7 thng v C3H7 isoVy, c ba ancol bc ba: CH3 CH3 CH3 | | | CH3 CH2 C CH2 CH3 ; CH3 C CH2 CH2 CH3 v CH3 C CH CH3 | | | | OH CH3 OH OH 3-metylpentan-3-ol
+

2-metylpentan-2-ol

2, 3- imetylbutan-2-ol

H 5. CH2=CHCH 2CH 3 + H 2O CH3CH(OH)CH 2CH3 as CH3 CH(OH) CH 2CH3 + Cl2

CH3 C(OH) CH2 CH3 + HCl | Cl

OH | CH3 C(OH) CH2 CH3 CH C CH2 CH3 + Mg | 3 | Cl MgCl

peoxit CH2=CHCH 2CH 3 + HCl CH3CH2CH2CH2Cl

OH | CH3 C CH2 CH3 + CH 3CH2CH2CH2Cl | MgCl CH3 | CH3 CH2 C CH2 CH2 CH2 CH3 + MgCl2 | OH 6. nO2 = 0,17 (mol) v nHCl = 0,02 (mol). Theo gi thit, cht E cha 3 nguyn t C, H, Cl nn oxi c trong CO 2, H 2O bng lng oxi tham gia phn ng (theo nh lut bo ton khi lng). Nu coi nCO2 = 6a th nH2O = 5a, ta c:

6a.2 + 5a = 0,17.2 = 0,34 a = 0,02

nCO2 = 0,12 nC = 0,12 nH2O = 0,1

cn nCl = 0,02 T l C : H : O = 0,12 : 0,22 : 0,02 = 6 : 11 : 1 Theo s cho, cng thc ca E l C 6H11Cl vi cu to nH = 0,2 + 0,02 = 0,22

Cl
Cl

A : CH

CH ; B :
OH

; D:

; F:

; G: Cl

H: OH

; I:

hoc

7.

- Cc phng trnh phn ng :

t C2H5Cl + NaOH C2H5OH + NaCl H2SO4 C H Cl + H O C2H5OH + HCl khan 2 5 2
o

C2H5OH + Na C2H5ONa +

1 H2 2

C2H5ONa + H 2O C2H5OH + NaOH 8. Cc phng trnh ha hc : CH2 2CH CH2 CH2 CH CH2 OH OH OH OH OH OH + 3HNO 3
H2SO 4 to

CH2 + 6Na
to

ONa ONa ONa CH2 CH CH2 ONO2 ONO2 ONO2 + 3H2O + 3H2

2CH CH2

H CH2 2CH CH2 OH OH OH + Cu(OH) 2 CH2 CH CH2 O O OH Cu H O O HO CH2 CH CH2 + 2H2O

9. Cho hn hp vo lng nc d, C 2H5OH tan trong nc, hn hp C 6H6 ; CH 3COOC2H5 khng tan, phn lp. Chit ly hn hp C 6H6 ; CH 3COOC2H5. Phn dung dch C2H5OH trong nc em chng ct ri lm kh bng CuSO 4 khan thu c C 2H5OH. Hn hp C 6H6 v CH 3COOC2H5 cho vo dung dch NaOH ly d, CH 3COOC2H5 tan theo phn ng x phng ho : CH3COONa + C 2H5OH. CH3COOC2H5 + NaOH Chit ly C 6H6, cn li l dung dch CH 3COONa v C 2H5OH. em chng ct ly C2H5OH ri lm kh bng CuSO 4 khan. C cn dung dch thu ly CH 3COONa khan ri cho phn ng vi H 2SO4 c thu c CH 3COOH ; sau cho phn ng vi C2H5OH theo phn ng ho este thu c CH 3COOC2H5.
2 4 CH 3COOC2H5 + H 2O. CH3COOH + C 2H5OH o

H SO t

10. a) - iu ch PVC t etilen : CH2=CH 2 + Cl2 CH2Cl-CH 2Cl

C CH2Cl-CH 2Cl 500 CH2=CHCl + HCl
o

nCH2=CHCl

p, to,xt

CH2 - CH n Cl
H Cu CH2 - O H O - CH2

b) Etylen glicol ho tan c Cu(OH) 2 trong mi trng kim mnh :

CH2OH 2 CH2OH + Cu(OH)2 OHCH2 - O O - CH2 + 2H2O

11. Cng thc cu to cc cht :

CH3CHCH3 Cl isopropyl bromua CH3CHCH3 OH propan-2-ol
CH3 CH CH3 OH

isopropylbenzen

-naphtol

12. iu ch vinyl clorua t axetilen (hoc etilen) :

CHCH + HCl

xt ,t CH 2=CHCl

iu ch ancol etylic t etilen

o

xt ,t CH2=CH 2 + H 2O CH 3CH2OH

iu ch phenol t cumen :
CH3 CH CH3
+ O2/ OH130oC

CH3 C O -O -H CH3

+H2SO4
60oC

CH3 OH + O=C CH3

13. a) Dung dch brom b mt mu : CH2=CHCH 2Cl + Br 2 CH 2Br-CHBrCH 2Cl b) Dung dch vn c do phenol tch ra dng nh tng, sau phn thnh hai lp : C6H5ONa + HCl C6H5OH + NaCl c) C bt kh hiro thot ra trn b mt vin natri : 2C3H5(OH)3 + 6Na 2C3H5(OH)3 + 3H 2 d) Mu tm nht dn ri bin mt, c kt ta nu en : 3C6H5CH=CH 2 + 2KMnO 4 + 4H 2O 3C 6H5CHOH-CH 2OH + 2MnO 2 + 2KOH 14. a) C7H8O c 3 ancol v 1 ete :
OH CH3 CH3 CH3 OH OH CH2OH

b) Ch c phenol phn ng vi NaOH : CH3C6H4OH + NaOH CH3C6H4ONa + H2O - Ch ancol tc dng vi CuO :
t C6H5CH2OH + CuO C6H5CHO + Cu + H 2O
o

15. Dng dung dch brom, nhn ra phenol v alyl clorua : CH2=CHCH 2Cl + Br 2 CH2Br-CHBr-CH 2Cl
OH OH Br Br

+ 3Br2
Br
tr ng

+ 3HBr

Phn bit ancol benzylic v phenyl clorua bng Na, ch c ancol phn ng :

C6H5CH2OH + Na C6H5CH2ONa + 16. Nhng cp cht tc dng c vi nhau :

1 H2 2

C2H5OH vi CH 3COOH ; C 6H5OH vi NaOH ; CH 3COOH vi NaOH ; CH3COOH vi Na 2CO3 ; CH 3COOH vi C 6H5ONa.
H2SO4 ,t CH3COOH + C 2H5OH CH3COOC2H5 + H 2O
o

C6H5OH + NaOH CH3COOH + NaOH 2CH3COOH + Na 2CO3 CH3COOH + C 6H5ONa 17. C6H5OH + NaOH C6H5OH + 3Br 2

C6H5ONa + H2O CH3COONa + H 2O 2CH 3COONa + CO 2 + H 2O CH3COONa + C 6H5OH

C6H5ONa + H2O C6H2Br3OH + 3HBr

18. Phenol c tnh axit v c phn ng vi baz, v d NaOH : C6H5ONa + H 2O C6H5OH + NaOH Phenol l axit yu (yu hn c axit cacbonic): C6H5OH + NaHCO 3 C6H5ONa + CO 2 + H 2O 19. a) Mu tm ca dung dch nht dn, c kt ta nu en, lp stiren mng dn v bin mt : 3C6H5CH=CH 2 + 2KMnO 4 + 4H 2O 3C 6H5CHOH-CH 2OH + 2MnO 2 + 2KOH b) Mu phenol tan ra : C6H5OH + Na 2CO3 C6H5ONa + NaHCO 3 c) Mu giy qu tm chuyn thnh mu xanh, do dung dch phenolat c mi trng kim : C6H5ONa C6H5O - + Na+ C6H5O - + H 2O D C 6H5OH + OH d) Hai lp dung dch tan vo nhau to dung dch ng nht :
t C6H5CH2Cl + NaOH C6H5CH2OH + NaCl
0

20. - Cng thc cu to v tn gi cc hp cht C 7H8O

OH O - CH3 CH2 - OH OH CH3 OH

CH3

CH3

metyl phenyl ete

ancol benzylic

o-cresol

p-cresol

m-cresol

21. - Dng dung dch NaOH (hoc Br 2) phenol : C6H5OH + NaOH C6H5ONa + H2O - Dng Na nhn ra ancol benzylic : C6H5CH2OH + Na C6H5CH2ONa + 1 H2 2

- Dng dung dch thuc tm nhn ra toluen : C6H5CH3 + 2KMnO 4 C6H5COOK +2MnO 2 + KOH + H2O - Cn li l phenyl clorua. 22. Dung dch phenol khng lm chuyn mu c qu tm, khng tc dng vi cc baz yu, tc dng c vi baz mnh : C6H5OH + NaOH C6H5ONa + H2O - Lc axit ca axit phenic yu hn c ca axit cacbonic : C6H5ONa + CO 2 + H 2O C6H5OH + NaHCO 3 23. Bnh ng axit hp th nc, bnh ng KOH hp th CO 2, ta c : nH 2O = 0,25mol ; nCO2 = 0,20mol . nancol = nH 2O nCO2 = 0,25 0,20 = 0,05mol Khi lng ancol em t chy l : a = (0,20.12 + 0,25.2 + 0,05.16) = 3,7 gam Gi CTPT ca ancol l C nH2n + 2O, ta c : n = => CTPT ancol l C 4H10O. 24. - S phn ng :
nH 2O (C6H10O5)n + nC6H12O6 men 2nC2H5OH

0,5

V nH 2O > nCO2 nn ancol cho l no, n chc, mch h, suy ra : 0,5 0,5 0,20 =4 0,05 0,5

162n T 0,475 T

2n.46 T x T

- Theo bi cho ta c : + Khi lng tinh bt nguyn cht l : 0,5.0,95 = 0,475 T + Khi lng ancol thu c l : 270.0,8 = 216 kg = 0,216 T - Nu hiu sut t 100% th khi lng ancol thu c l : x= 0,475.2n.46 = 0,270 T 162n 0,216 .100% = 80% 0,270

- Vy hiu sut chung ca qu trnh sn xut ancol l : h=

25. - Gi cng thc chung 2 ancol l C n H 2 n+1OH , ta c phn ng : C n H 2 n+1OH + Na C n H 2 n+1ONa + 1 H2 2

- Khi lng hiro thot ra l : (11,5 + 12,4) - 23,6 = 0,3 g. - nNa = 11,5 0,3 = 0,5mol ; n2 ancol = 2nH 2 = 2. = 0,3mol => Na cn d. 23 2 12,4 = > n = 1,67 0,3

- Vy : M 2 ancol =14n +18 =

=> CTPT 2 ancol l CH 3OH v C 2H5OH 26. - Theo bi cho, tnh c : n H 2O = 2,7 4,4 = 0,15mol ; nCO2 = = 0,1mol 18 44

Nhn thy n H 2O > nCO2 nn hai ancol l no, n chc mch h. - Gi s nguyn t cacbon trung bnh trong 2 ancol l n v n, m ln lt l s nguyn t cacbon trong phn t hai ancol, ta c : 0,1 n= =2 n = 1 0,15 0,1 m = 3 n = n + m 2 - CTPT v CTCT hai ancol : CH3OH v CH 3CH2CH2OH hoc CH 3CHOHCH 3 27. - Gi CTPT ca ankanol l C nH2n+2O (n 3) Khi t th : C 2H6O 3H2O CnH2n+2O (n+1)H 2O

Theo cho ta c :

n +1 5 = n = 4 . Vy CTPT ca ankanol l C 4H10O. 3 3

- Khi tch nc ch cho 1 anken, nn CTCT ca ancol l : (CH 3)2CH-CH 2OH hoc (CH 3)2CH-CH 2OH hoc CH 3CH2CH2CH2OH 28. - Khi tch nc ancol to anken nn cc ancol l no, n chc mch h. - Gi cng thc phn t chung ca 3 ete l (C n H 2 n+1 ) 2 O , ta c : M 3ete = 1,32.32 = 88 => 28n + 18 = 88 n = 2,5 => Hai ancol ly l ng ng lin 0,48

tip ca nhau, CTPT ca X, Y l : C2H5OH v C 3H7OH - Cng thc cu to ca Y, X l : CH3CH2CH2OH v CH 3CHOHCH 3 29. - Gi cng thc chung ca 2 ancol l C n H 2 n+1OH . - Cc phn ng : C n H 2 n+1OH + Na C n H 2 n+1ONa + 1 H2 2 3 H2 2

C3H5(OH)3 + 3Na C3H5(ONa)3 +

2C3H5(OH)3 + Cu(OH) 2 [C3H5(OH)2O]2Cu + H 2O - Theo bi cho, ta c : nH 2 = nCu ( OH )2 = 2,52 = 0,1125mol 22,4

3,92 = 0,04mol 98

- 8,75 gam A ho tan ht s mol Cu(OH) 2 l : 8,75 .0,04 = 0,025mol => s mol glixerol l 0,025 mol. 14 => Khi lng glixerol l : 0,025.92 = 2,3 gam Khi lng 2 ancol l : 6,45 gam. - Gi x l s mol 2 ancol, ta c : 1 3 x + .0,025 = 0,1125 => x = 0,15. 2 2 Vy ta c phng trnh :

M 2 ancol =

6,45 = 43 0,15

=> 2 ancol l CH 3OH v C 2H5OH 30. s mol H2 = 0,015 ; - Phng trnh ho hc : C6H5OH + Na C6H5ONa + 1 H2 2 1 H2 2

C6H5CH2OH + Na C6H5CH2ONa +

C6H5OH + 3Br 2 C6H2Br3OH + 3HBr 0,02 6, 62 = 0,02 331 S mol phenol = 002 nn ancol benzylic = 0,03 0,02 = 0,01 mol - Khi lng hn hp : m = 0,02.94 + (94 + 14).0,01 = 2,96 gam p n cu hi, bi tp trc nghim khch quan Cu A Cu A Cu A Cu A Cu A 1 C 17 B 33 B 49 C 65 C 2 C 18 C 34 A 50 B 66 B 3 B C C B B 4 D D B B A 5 B 21 C 37 B 53 D 69 B 6 B 22 B 38 B 54 C 70 A 7 D 23 A 39 D 55 C 71 D 8 C C C D A 9 A A A B B 10 A 26 A 42 C 58 B 74 B 11 B 27 C 43 C 59 A 75 D 12 C 28 B 44 C 60 A 76 B 13 C 29 C 45 C 61 B 77 B 14 A 30 A 46 D 62 C 78 A 15 16 B D C C D D B B B C 31 32 47 48 63 64 79 80

Theo PTHH: tng s mol phenol v ancol benzylic = 0,015 2 = 0,03

19 20 35 36 51 52 67 68

24 25 40 41 56 57 72 73

IV. kim tra kim tra 15 pht s 1 (mi cu 1,0 im) 1. Gi tn hp cht sau :

C2H5 I Br

A. 3-brom- 4-etyl-5-iotxiclohex-1-en. B. 4-iot-5-etyl-6-bromxiclohex-1-en. C. 2-brom-6-iot-etylxiclohex-3-en. D. 5-iot-6-etyl-bromxiclohex-2-en. 2. S ng phn c cng thc phn t C 5 H11Cl l A. 6. B. 7. C. 8. D. 9. 3. Cho cc cht CH 3CH2CH2Cl, CH 3CH2Cl, CH 3Cl, CH 3CH2CH2 CH2Cl. Nhit si ca cc cht tng dn theo th t A. CH 3CH2CH2Cl < CH 3CH2Cl < CH 3Cl < CH 3CH2CH2 CH 2Cl. B. CH 3CH2CH2 CH 2Cl > CH 3CH2CH2Cl > CH 3CH2Cl > CH 3Cl. C. CH 3CH2CH2Cl > CH 3CH2Cl > CH 3Cl > CH 3CH2CH2 CH 2Cl. D. CH 3Cl < CH 3CH2Cl < CH 3CH2CH2Cl < CH 3CH2CH2 CH 2Cl. 4. Ancol X c cng thc phn t C 4H10O tc dng vi axit H 2SO4 c sinh ra hn hp hai anken ng phn cu to ca nhau. Tn ca X l A. butan-1-ol. C. butan-2-ol. B. ancol isobutylic. D. ancol tert-butylic.

5. ng vi cng thc phn t C 5H12O c bao nhiu ancol ng phn ca nhau khi tc dng vi CuO un nng to thnh anehit? A. Hai cht. B. Ba cht. C. Bn cht. D. Nm cht. 6. C 4 l mt nhn ng: etylen glicol, phenol, stiren, etanol. nhn bit 4 l trn c th dng A. dung dch NaOH v Na. B. Na v dung dch Cu(OH) 2. C. dung dch Br 2 v dung dch Cu(OH) 2. D. dung dch Br 2 v Na. 7. Cho dy chuyn ha sau:
H2SO4 , d c170 C H2O,H2SO4l CH3CH2CH2OH X Y
0

Bit X, Y l sn phm chnh. Vy cng thc cu to ca X v Y ln lt l A. CH 3CH=CH 2, CH 3CH2CH2OH. C. CH 3CH=CH 2, CH 3CH(OH)CH 3. B. CH 3CH=CH 2, CH 3CH2CH2OSO 3H. D. C3H7OC3H7, CH 3CH2CH2OSO3H.

8. t chy hon ton m gam hn hp hai ancol A v B thuc dy ng ng ca ancol

metylic ngi ta thu c 70,4 gam CO 2 v 39,6 gam H 2O. Vy m c gi tr no sau y? A. 3,32 gam B. 33,2 gam C. 16,6 gam D. 24,9 gam 9. Cho 3,04 gam hn hp hai ancol n chc l ng ng k tip nhau tc dng vi Na va , sau phn ng thu c 4,36 gam cht rn. Cng thc phn t ca hai ancol l A. CH 3OH v C 2H5OH. C. C3H5OH v C 4H7OH. B. C2H5OH v C 3H7OH. D. C3H7OH v C 4H9OH.

10. Cho Na tc dng vi dung dch A gm phenol v xiclohexanol trong hexan(lm dung mi) ngi ta thu c 313,6cm 3 kh (ktc).Mt khc nu cho nc brm phn ng vi cng mt lng dung dch A nh trn th thu c 59,58gam kt ta trng .Tnh % khi lng ca phenol v xiclohexanol trong dung dch A . A.33,84 g v 20 g . C. 16,92g v 16g. kim tra 15 pht s 2 (mi cu 1,0 im) 1. Cho ancol X c cng thc cu to CH3CHCH2CH2CHCH3 OH Tn ca X l A. 2-metylhexan-5-ol. C. isohexxanol. A. 1 cht. B. 4 cht. B. 5-metylhexan-2-ol. D. isoheptanol. C. 3 cht. D. 2 cht. CH3 B. 25,38 g v 15 g . D. 19,62 g v 19 g.

2. Hi c bao nhiu cht ring l c thnh phn C3H5Cl v c mt lin kt i? 3. C my dn xut C 4H9Br ng phn cu to ca nhau khi tc dng vi KOH trong etanol, mi cht ch to c mt anken duy nht? A. Mt cht. B. Hai cht. C. Ba cht. D. Bn cht 4. Cho cc cht CH 3CH2CH2Cl, CH 3CH2CH2Br, CH 3CH2CH2I, CH 3CH2CH2F. Nhit si ca cc cht tng dn theo th t A. CH 3CH2CH2Cl < CH 3CH2CH2Br< CH 3CH2CH2I < CH 3CH2CH2F. B. CH 3CH2CH2Cl > CH 3CH2CH2Br > CH 3CH2CH2I > CH 3CH2CH2F. C. CH 3CH2CH2F < CH 3CH2CH2Cl < CH 3CH2CH2Br < CH 3CH2CH2I. D. CH 3CH2CH2Cl > CH 3CH2CH2Br > CH 3CH2CH2I > CH 3CH2CH2F.

5. ng vi cng thc phn t C 5H12O c bao nhiu ancol ng phn ca nhau khi tc dng vi CuO un nng to thnh xeton? A. Hai cht. B. Ba cht. C. Bn cht. D. Nm cht. 6. phn bit : metanol, etylen glicol v phenol, ngi ta dng A. dung dch Br 2 d v dung dch Cu(OH) 2 . B. dung dch Cu(OH) 2 . C. dung dch Cu(OH) 2 v Na. D. dung dch Br 2 d v Na. 7. Cho dy chuyn ha sau:
H 2SO 4 ,170 C Br2 (dd) CH 3CH 2CHOHCH 3 E F
0

Bit E, F l sn phm chnh, cc cht phn ng vi nhau theo t l 1:1 v s mol. Cng thc cu to ca E v F ln lt l cp cht trong dy no di y? A. CH 3CH2CH=CH 2, CH 3CH2CHBrCH 2Br. B. CH 3CH=CHCH 3, CH 3CHBrCHBrCH 3. C. CH 3CH=CHCH 3, CH 3CH2CBr2CH3. D. CH 3CH2CH=CH 2, CH 2BrCH 2CH=CH 2. 8. t chy hon ton m gam hn hp hai ancol A v B thuc loi ancol no, n chc, k tip nhau trong cng dy ng ng thu c 4,48 lt CO 2 (ktc) v 4,95 gam nc. A, B ln lt l A. CH 3OH v C 2H5OH. B. CH 3[CH 2]2OH v CH 3[CH 2]4OH. C. C2H5OH v CH 3CH2CH2OH. D. CH 3[CH 2]3OH v CH 3[CH 2]4OH. 9. Cho 22,8 gam hn hp hai ancol n chc tc dng vi Na va , sau phn ng thu c 32,7 gam cht rn v bao nhiu lt H 2 (ktc)? A. 1,68 lt B. 3,36 lt C. 5,04 lt D. 6,72 lt 10. Cho m (gam) dung dch A gm phenol v xiclopentanol tc dng vi Na thu c 1456 ml H 2 (ktc). Mt khc nu cho m (gam) A qua nc Br 2 d thu c 26,48 gam kt ta trng. Phn trm khi lng ca phenol v xiclopentanol trong A l A. 75,12% ; 24,88%. C. 56,42% ; 43,58%. B. 63,62% ; 36,38%. D. 69, 92% ; 30,08%.

 kim tra 45 pht s 1 A. Trc nghim khch quan (3,0 im, mi cu 0,5 im) 1. Ancol isopentylic (thng c gi l ancol isoamylic) c cng thc cu to no di y? CH3CHCH2CH2OH CH3 CH3CH2CHCH2OH C. A. 7 A. etan. 4. Cho 4 ancol sau: C2H5OH, C2H4(OH)2, C3H5(OH)3 v HOCH 2CH 2CH2OH. Ancol no khng ho tan c Cu(OH) 2? A. C2H5OH v C 2H4(OH)2. B. C2H4(OH)2 v HOCH 2CH2CH 2OH. C. C2H5OH v HOCH 2CH2CH2OH. D. Ch c C 2H5OH. 5. Phenol tc dng c vi nhm cht no di y? A. Natri, natri clorua, natri hiroxit, nc brom. B. Natri, natri hirocacbonat, natri hiroxit. C. Natri, natri cacbonat, natri hiroxit, nc brom. D. Natri, natri sunfat, natri hiroxit. 6. Cho 7,20 gam ancol n chc, mch h X tc dng vi natri sinh ra 1,12 lt kh hiro (ktc). X tn ti di hai dng ng phn hnh hc. Cng thc cu to ca X l A. CH 2=CHCH 2CH2OH. C. HOCH 2CH=CHCH 3. B. Trc nghim t lun (7,0 im) 7. Hi 2 cht no v iu kin no phn ng vi nhau to nn nhng cht sau ( y khng ghi h s ca sn phm phn ng): B. HOCH=CHCH 2CH3. D. HOCH=C(CH 3)2. CH3 D. B. 8 B. propan. C. 5, C. butan. CH3CH2CH2CH2CH2OH CH3CH2CH2CHOH CH3

A.

B.

2. S ng phn cu to ca C 4H7Br (mch h) bng: D. 10 D. pentan. 3. Khi un nng etyl clorua vi natri trong ete khan thu c sn phm hu c l

a) butan-2-ol; b) butan-2-ol + KCl ; c) 2 - metylpropen + KCl + H2O Vit phng trnh y ca phn ng. 8. Nu phn ng ho hc phn bit : etyl clorua, metanol, etylen glicol v phenol. Vit cc phng trnh ho hc. 9. Mt hn hp ca ancol n chc, mch h v ng ng k tip ca phenol c khi lng 2,82 g c th phn ng vi 160 gam nc brom 3% to ra dn xut tribrom. Cng lng hn hp khi tc dng vi lng d natri gii phng 481ml hiro nhit 20 oC v p sut thng ca kh quyn. Xc nh cng thc phn t, cng thc cu to ca cc cht v phn khi lng ca chng trong hn hp. kim tra 45 pht s 2 A. Trc nghim khch quan (3,0 im, mi cu 0,5 im) 1. Ancol X c cng thc cu to CH3CH2CH2CHOH CH3 Tn ca X l A. 1-metylbutan-1-ol. C. 2-metylbutan-2-ol. A. 2 A. etan. B. 3 B. propan-1-ol. B. pentan-2-ol. D. 3-metylbutan -2-ol C. 4 C. propan. D. 5 D. propilen.

2. ng vi cng thc phn t C 3H6Br2 c bao nhiu ng phn ? 3. Khi un nng 2-clopropan vi dung dch kali hiroxit trong etanol to ra 4. Cht hu c X mch h, c ng phn cis trans c cng thc phn t C 4H8O, X lm mt mu dung dch Br 2 v tc dng vi Na gii phng kh H 2. X ng vi cng thc phn t no sau y? A. CH 2=CHCH 2CH2OH. C. CH 2=C(CH 3)CH 2OH O H ... O H C2H5 C2H5 B. CH 3CH=CHCH 2OH. D. CH 3CH2CH=CHOH. O H ... O H C2H5 C6H5

5. Trong hn hp etanol v phenol, kiu lin kt hiro no l bn nht?

A.

B.

C.

O H ... O H C6H5 C6H5

D.

O H ... O H C6H5 C2H5

6. Khi cho 7,60 gam hn hp hai ancol X v Y no n chc mch h k tip nhau trong dy ng ng tc dng vi natri d thy c 1,68 lt kh thot ra (ktc). Cng thc phn t ca X v Y l A. CH 4O v C 2H6O. C. C2H6O v C 4H10O. B. Trc nghim t lun (7,0 im) 7. Vit phng trnh ho hc ca cc phn ng xy ra (nu c) khi cho dung dch NaOH, HBr, dung dch Br 2 ln lt tc dng vi : etanol, etyl bromua, phenol. a) PVC; b) ancol etylic; c) phenol. B. C2H6O v C 3H8O. D. C3H4O v C 4H6O.

8. T metan v cc cht v c cn thit, vit cc phng trnh ho hc iu ch : 9. Mt hn hp ancol etylic v phenol tc dng vi Na d thot ra 6,72 lt H 2 (ktc). trung ha hon ton hn hp cn dng 25 ml dung dch KOH 40% (d = 1,4 g/ml). Tnh phn khi lng mi cht trong hn hp. V. p n v Hng dn gii kim tra kim tra 15 pht s 1 Cu A 1 A 2 C 3 D 4 C 5 C 6 C 7 C 8 D 9 B 10 C

kim tra 15 pht s 2 Cu A 1 B 2 B 3 C 4 C 5 B 6 A 7 B 8 C 9 C 10 B

kim tra 45 pht s 1 A. Trc nghim khch quan Cu 1 A A B. Trc nghim t lun
H 7. a) CH 2=CHCH2CH3 + H 2O
+

2 B

3 C

4 C

5 C

6 C

CH3 CH CH 2 CH3 | OH

b) CH 3CHClCH2CH3 + KOH

CH3 CH CH 2 CH3 + KCl | OH

Cl | C2 H5OH CH 2 = C CH 3 + KCl+ H 2O c) CH 3 C CH 3 + KOH | | CH 3 CH 3 8. Dng Na nhn ra phenol, etylen glicol v metanol: C6H5OH + Na C 6H5ONa + 1/2 H2 CH3OH + Na CH 3ONa + 1/2 H2 C2H4(OH)2 + 2Na C 2H4(ONa)2 + H 2 Nhn ra phenol bng nc brom C6H5OH + 3Br 2 C6H2Br3OH + 3HBr Nhn ra etylen glicol bng Cu(OH) 2: 2C2H4(OH)2 + Cu(OH)2 [C2H4(OH)O]2Cu + 2H2O 9. s mol H 2 = PV 1 0, 481 = = 0,02; Br 2 = 0,03 RT 0, 082 (273 + 20)

t cng thc ancol l R OH Phn ng vi Na: ROH 0,04 + Na R ONa + 1/2 H 2 0,02 CH3C6H4OH + Na CH 3C6H4ONa + 1/2 H 2 Ch c ng ng phenol phn ng vi nc brom: CH3C6H4OH + 3Br 2 CH 3C6HBr3OH + 3HBr 0,01 0,03 Theo PTHH: s mol ancol = 0,04 0,01 = 0,03 Ta c: (R + 17) 0,03 + 108 0,01 = 2,82 R = 58 ng vi C 3H5 Cu to ca ancol: CH 2=CH CH2OH vi khi lng = 003 58 = 1,74 g chim 61,7% Cu to ng ng phenol l meta-metylphenol ; khi lng chim 38,3%

 kim tra 45 pht s 2 A. Trc nghim khch quan Cu 1 A B B. Trc nghim t lun 7. Phn ng ca etanol : C2H5OH + HBr
xt, to

2 C

3 D

4 B

5 D

6 B

C2H5Br + H 2O

Phn ng ca etyl bromua :

t C2H5Br + NaOH C2H5OH + NaBr
o

Phn ng ca phenol : C6H5OH + NaOH C6H5ONa + H2O

OH OH Br Br

+ 3Br2
Br
tr ng

+ 3HBr

8.

a) iu ch PVC :
cao 2CH4 t C2H2 + 3H 2 o

, xt C2H2 + HCl t CH2=CHCl

nCH2=CHCl

to,xt

CH2 - CH Cl

b) iu ch ancol etylic :
, xt CHCH + H2 t CH2=CH2
o

, xt CH2=CH 2 + H 2O t CH 3-CH2OH

0,5 c) iu ch phenol :
, xt 3CHCH t C 6H6
o

, xt C6H6 + Br 2 t C6H5Br + HBr ,p C6H5Br + 2NaOH t C6H5ONa + NaBr + H 2O

o

C6H5ONa + CO 2 + H 2O C6H5OH + NaHCO 3

1,0

9. S mol H 2 = 0,3 ; KOH = 0,25 2C2H5OH + 2Na 2C2H5ONa + H 2 2C6H5OH + 2Na 2C6H5ONa + H 2 Theo PTHH: tng s mol ancol v phenol = 0,3 2 = 0,6 C6H5OH + KOH C6H5OK + H2O 0,25 0,25 Theo PTHH: s mol phenol = 0,25 ancol = 0,6 0,25 = 0,35 khi lng phenol = 94 0,25 = 23,5 gam v ancol = 46 0,35 = 16,1 gam Tng khi lng = 39,6 gam trong phenol chim 59,34% v ancol chim 40,66%