PHYSICS

PART-A
Q.1 A
Q.2 D
Q.3 A
Q. 4 C
Q. 5 C
Q.6 A
O.7 C
Q. 8 A
Q.9 C
Q.10 A
Q.11 D
Q.12 B
Q.13 D
Q.14 A
Q. 15 A,B,C,D
Q.16 A,C
Q.17 A,B,C,D
Q.18 A,B,C
PART-B
Q.1 (A) PQRT,
(B) Q ,
(C) P ,
(D) RS
PART-C
Q.1 0008
Q.2 0003
Q.3 0002
Q.4 0002
CHEMISTRY
PART-A
Q.1 B
Q.2 C
Q.3 A
Q.4 B
Q.5 C
Q.6 B
Q.7 D
Q.8 D
Q. 9 A
Q. 10 B
Q.11 C
Q.12 B
Q.13 AB
Q.14 BD
Q.15 AD
Q.16 ABD
PART-B
Q.1 (A) PT;
(B) PRT;
(C) PQT;
(D) PQST
PART-C
Q.1 0002
Q.2 0006
Q.3 0009
Q.4 0004
Q.5 0007
Q.6 0009
Q.7 0011
MATHS
PART-A
Q.1 B
Q.2 A
Q.3 C
Q.4 B
Q.5 C
Q.6 B
Q.7 A
Q.8 B
Q.9 D
Q.10 C
Q.11 ABCD
Q.12 ABCD
Q.13 ABC
Q.14 CD
Q.15 ABCD
PART-C
Q.1 0000
Q.2 0003
Q.3 0060
Q.4 0004
Q.5 0007
Q.6 0040
Q.7 0002
Q.8 0004
FULL SYLLABUS TEST
ANSWER KEY
[1]
CHEMISTRY
PART-A
Q.1, 2, 3
[Sol. Let the rate of loss of optical activity is n times the rate of loss of radioactivity of substrate.
For pure 2
N
S reaction,
Rate recemization =2x rate of loss of radioactivity = 2 rate of 2
N
S reaction.
For pure 1
N
S reaction,
Rate of racemization = Rate of loss of radioactivity = Rate of 1
N
S reaction.
Let the rate of 2
N
S and 1
N
S reactions are x & y respectively..
Total rate of loss of radioactivity = (y + x)
Total rate of loss of racemization = (y + 2x)
According to the problem,
(y + 2x) = n (y + x)
y + 2x = ny + nx
(2n) x = (n1) y
( )
( )
x
n
n
y
1
2

=
; % of reaction 2
N
S reaction
100
y x
x
+
=
( )
( )
100
1
1
2

(

=
n
n
x
x
100
1
1 2
1

+
=
n
n n
100
1
1

=
n
= (1.75 1) 100 = 75
(A) ]
Q.7
[Sol: Let the oxide of chlorine be represented as Cl
y
O
x
.
Cl
y
O
x
(g)
) g ( Cl
2
y
2
+
) g ( O
2
x
2
Initial volume 30 ml _ _
Final volume 3030 = 0
ml
2
y 30
|
.
|

\
|

ml
2
x 30
|
.
|

\
|
30 +
2
x 30
+
2
y 30
= 75
Caustic soda absorbs all Cl
2
gas.

30 +
2
y 30
= 60, y = 2
2
x 30
= 15, x = 1
87
M
60
3
2
/ 400
40 / 300
M
M
r
r
x
O Cl
X
x
O Cl
2
2
=

= =
;
M
X
=
16
87 9

~
49
(D)]
[2]
CHEMISTRY
Q.8
[Sol. E = 0.8 0.059 log
3
1
3
1
1
= 0.8 0.059 log
3
1
3
2
= 0.5 0.059 0.301
= 0.7823 V ]
Q. 9
[Sol. E
ep
=
( )
2
E E
0
Ce / Ce
0
Fe / Fe
3 4 2 3 + + + +
+
=
2
8 . 0 64 . 1 +
= 1.22 V ]
Q. 10
[Sol. K
( ) 059 . 0 / E E
0
2
Fe /
3
Fe
0
3
Ce /
4
Ce
10
+ + + +

=
059 . 0 / 84 . 0
10 K = ]
Q.11, 12
[Sol.
(i) ]
(ii) ]
[3]
CHEMISTRY
Q.13, 14
[Sol: pO
2
= 760
100
20
= 152 mm Hg
pO
2
= K
H

2
O
X
152 = 3.04 10
7

2
O
X
2
O
X = 5 10
6
2
O
X =
O H O
O
2 2
2
n n
n
+
, 5 10
6
=
O H
O
2
2
n
n
=
56 . 55
n
2
O
2
O
n = 2.778 10
4
[O
2
] = 2.778 10
4
M]
PART-C
Q.1
[Sol: 3XeF
4
+ 6 H
2
O 2Xe + XeO
3
+ 12HF + 3/2 O
2
(n
f
= 2) (n
f
= 4)
Moles of XeF
4
=
3 . 207
2 . 829
= 4; Moles of O
2
liberated = 4/2 = 2]
Q.2
[Sol: t
1/2
=
k
693 . 0
=
231 . 0
693 . 0
= 3 ; t
3/4
= 2t
1/2
= 2 3 = 6 min. ]
Q.4
[Sol: ROH + + HCl
Molar mass : M M 1 + 43 = M + 42
For a compound containing only oneOH group, the molar mass increases by 42 units, on reaction with
acetyl chloride. For a compound containing n OH groups, the increase in molar mass will be 42 n.
334 = 166 + 42n ; n =
42
168
= 4]
Q.5
[Sol:
3
NH 3 . LiCl (s)
3
NH . LiCl (s) + 2 NH
3
(g)
1.5 a
1.5 1.5 1.5 = 0 a 3
K
p
= ( )
2
NH
3
p = 16
3
NH
p = 4 atm
a 3 = 4
298 082 . 0
436 . 24

a 3 = 4, a = 7]
[4]
CHEMISTRY
Q.6
[Sol: Let the number of moles of air initially present in the vessel of volume V L at 300 K be n.
Number of moles of air at 459 K = (n 3).
Volume of vessel at 459 K = 1.02 V
Since, pressure is constant,
1
1 1
V
T n
=
2
2 2
V
T n
V
300 n
=
( )
V 02 . 1
459 3 n
n = 9]
Q.7
[Sol: AlCl
3

O H
2
Al
3+
+ 3Cl

0.05 0.05 = 0 0.05 0.05 3

Al
3+
+ 6 H
2
O [Al(H
2
O)
6
]
3+
0.05 0.05 0.05
= 0
[Al(H
2
O)
6
]
3+
(aq) + H
2
O(l) [Al(H
2
O)
5
(OH)]
2+
(aq) + H
3
O
+
(aq)
Initial Conc. 0.05
Conc. at equilibrium 0.05 x x x
K
a
=
x 05 . 0
x
2

2 10
5
~
05 . 0
x
2
, x = 1 10
3
[H
3
O
+
] = 1 10
3
M
pOH = 14 3 = 11 ]
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. ab = b b = 0 or a = 1 but b = 0 a = 1
a + b = a 2a + b = 0 (a, b) = (1, 2)
x
2
+ x 2 =
2
4
1
2
1
x
2

|
.
|

\
|
+
>
4
9
. Ans.]
Q.2
[Sol. Here,
Tr.(A) = a
11
+ a
22
+ a
33
= e
2
+ e
4
+ e
6
= e
2
+ e + 1 = 0 Ans. ]
Q.3
[Sol. x + y
dx
dy
= 3x
} }
= dx x 2 dy y

2
y
2
= x
2
+ c
Now, (1, 2) satisfy it, 2 1 = c, c= 1, so y
2
= 2x
2
+ 2
or 2x
2
y
2
+ 2 = 0. Ans.]
Q.4
[Sol. n(S) = 1296 36 = 2 2 3 3 ways
n(A) = 1433 12 ways
1236 24 ways
1166 6 ways
2233 6 ways
Total = 48 ways
Probability =
1296
48
=
216
8
=
27
1
Hence p + q = 28 Ans. ]
Q.5
[Sol. I
1
=
( ) ( )
}

=
(

0
3
0
3
2 3
49
12
x 2 1
1
4
1
x 2 1
dx
E =
49
12

2
2 12
=
7
12
=
4 3
4 3
+
a = 3, b = 4
2 2
b a + = 5. Ans.]
MATHEMATICS
Code-A Page # 2
Q.6
[Sol. Let x = 3h + 2 and v = k
h =
3
2 x
and k = v
As (h, k) lies on x
2
+ y
2
= 1, so h
2
+ k
2
= 1

9
) 2 x (
2

+ v
2
= 1
Locus is
9
) 2 x (
2

+ y
2
= 1,
which is an ellipse with centre (2, 0) and eccentricity = e =
9
1
1
=
3
2 2
Ans.]
Paragraph for question nos. 7 to 10
Q.7, 8, 9, 10
[Sol.
(i)
dx
dy
=
t 6
t 9
2

1
= tan u 9t
2
6t u + tan
2
u = 1 + tan
2
u
(3t tan u)
2
= sec
2
u, 3t = tan u sec u. Ans.
(ii) 2 = 1 3t
2
t = 1 2 = t 3t
2
t = 1
dx
dy
=
6
8
=
3
4
equation of tangent y 2 =
3
4
(x + 2)
t 3t
3
2 =
3
4
(1 3t
2
+ 2) = 4 (1 t
2
)
3t
3
+ 4t
2
t 2 = 0 (3t
2
+ t 2) (t + 1) = 0
(3t 2) (t + 1)
2
= 0 t =
3
2
Q =
27
8
3
3
2
,
9
4
3 1
Q =
|
.
|

\
|
9
2
,
3
1
. Ans.
(iii)
4
3
4
4 1
dx
dy
3
2
t
=

=
=
as m
1
m
2
= 1. Ans.
(iv) y = t (1 3t
2
) = tx x = 1
2
2
x
y 3
2
2
x
y 3
= (1 x) y =
( )2
1
x 1
3
x

so
( )
} }

=
1
0
1
0
2
1
dx
3
x x 1
dx y
so }
= =
1
0
15
4
5
2
3
2
dx y 3
. Ans.]
MATHEMATICS
Code-A Page # 3
Q.11
[Sol. c =
}

10
10
dx ) x ( f
1
c ) x ( f
) x ( ' f
=
+
ln ( ) c ) x ( f + = x + c
1
f(x) = ke
x
c
c =
( )
}

10
10
x
c ke
= k(e
10
e
10
) 20 c
c =
( )
10 10
e e
21
k

f(x) = k
( )
(

21
e e
e
10 10
x
f '(x) = ke
x
, f "(x) = ke
x
. Ans.]
Q.12
[Sol. S
1
: x
2
+ y
2
6x = 0 (x 3)
2
+ y
2
= 9
S
2
: x
2
+ y
2
+ 4x = 0 (x + 2)
2
+ y
2
= 4
Now, sinu =
10
2
=
5
1
tanu =
24
1
=
12
P

6
6
6 2
12

l
1
l
2
(0,0) (3,0)
x
y
(-12,0)
P
(-2,0)
u
5
12
x

=
l
3
p =
6
(A) Area of triangle =
2
1
12 2p =
6 12
(B) Equation of transverse common tangent is x = 0 i.e., y-axis.
(C) Equation of direct common tangent having positive y-intercept, is (y 0) =
6 2
1
(x + 12)
x 2
6
y + 12 = 0
(D) Equation of circle circumscribing the triangle formed by the direct common tangent and chord of
contact of point of intersection of direct common tangent with respect to S
2
is (x + 12) (x + 2) + y
2
= 0
x
2
+ y
2
+ 14x + 24 = 0. ]
Q.13
Sol. Given x
2
ab b = 0
o |
Now, o| = b
| o| | = | b | < 1 | b | < 1
Now, Let f(x) = x
2
ax b
So, f(1) > 0 a + b < 1
Also, f(1) > 0 b a < 1 ]
MATHEMATICS
Code-A Page # 4
Q.14
[Sol. x f (x) = x + C
f (1) = 1 + C C = 1
f (x) =
x
1 x +
f (x) = 1 +
x
1
; f '(x) =
2
x
1
f is always derivable and decreasing in its domain monotonic
also f is not bounded.
The graph of y = f (x) is as shown
y =1 and x = 0 are the two asymptotes and range is R {1}
Only C and D are correct. ]
Q.15
[Sol. We know that
r
1
r
2
+ r
2
r
3
+ r
3
r
1
=
r
r r r
3 2 1
= s
2
= 144
4 (r
2
+ r
3
) + r
2
r
3
= 2r
2
r
3
= 144
r
2
r
3
= 72
Also, r
2
+ r
3
= 18
r
2
= 6, r
3
= 12
As,
2
1
s
a s
r
r
1
=

=
a = 6 (As, s = 12)
Similarly, b = 8 and c = 10
AABC is right angled at C.
Now,

=
90 sin
10
A sin
6
sin A =
5
3
10
6
=
B
A C
a=6
c =10
b = 8
Also, R =
2
AB
= 5. Ans.]
PART-C
Q.1
[Sol. Let y = mx be the directrix and (h, k) be the focus
FA = AM
( )
2
2 2
m 1
m
k 1 h
+
= +
FB = BN
( )
2
2 2
m 1
1
1 k h
+
= =
M
N
x' x
F(h,k)
A(1,0)
B(0,1)
y
y' y=mx
h
2
= k
2
+ (h 1)
2
+ (k 1)
2
= 1
2h
2
+ 2k
2
2h 2k + 1 = 0
h
2
+ k
2
h k +
2
1
= 0
0
2
1
k
2
1
h
2 2
=
|
.
|

\
|
+
|
.
|

\
|

Point circle. Ans.]
MATHEMATICS
Code-A Page # 5
Q.2
[Sol. sin x + cos x = 15 sin x cos x ...........(1)
squaring
1 + 2 sin x cos x = 15 (sin x cos x)
2
sin x cos x = t
15t
2
2t 1 = 0
15t
2
5t + 3t 1 = 0
(3t 1) (5t + 1) =0
t =
3
1
or
5
1
sin2x =
3
2
or
5
2
If sin 2x =
3
2
2x
~

40 or 140
x
~

20 or 170
which satisfy (1) ( 2 solution from here)
If sin 2x =
5
2
2x
~

(t + 25) or (2t 25)

x
~

103 (Rejected) or 167

As does not satisfy (1)
Total 3 solutions.]
Q.3
Sol. Given f ''(x) f '(x) s 0 x > 0
dx
d
(f '(x) .e
x
) s 0 x > 0
f '(x) . e
x
is a f : x x > 0
f '(x) e
x
s f '(0) s 0
f '(x) s 0
But f '(x) > 0 x > 0 given
f '(x) = 0 f (x) = C But f(0) = 5
f(x) = 5
I =
}
2
23
2
1
dx 5 = 5 12 = 60 Ans.]
MATHEMATICS
Code-A Page # 6
Q.4
[Sol. Taking 'O' as the origin, let the position vectors of A, B and C be b , a

and
c

respectively. Then the

position vector G
1
, G
2
, G
3
are
3
a c
,
3
c b

+ +
and
3
b a

+
respectively. So,
v
1
=
| | c b a
6
1

and v
2
= | |
3 2 1
OG OG OG
v
2
=
| | b a a c c b
27
1

+ + +
=
| | c b a
27
2

=
1
v 6
27
2
1
2
v
v 9
=
6
27
2
9
= 4. Ans.]
Q.5
Sol. For z = 1,
1
1 z
1 z
5
=
|
.
|

\
|

+
= e
i2kt
5
k 2
i
e
1 z
1 z
t
=

+
where k = 2, 1, 1, 2, z
k
=
|
|
.
|

\
|

+
t
t
1 e
1 e
5
k 2
i
5
k 2
i
z
k
=
5
k
i
5
k
i
5
k
i
5
k
i
e e
e e
t

t
t

+
= i cot
|
.
|

\
| t
5
k
where k = 2, 1, 1, 2
z
1
z
2
z
3
z
4
= i
4
cot
|
.
|

\
| t
5
cot
|
.
|

\
| t
5
cot
|
.
|

\
| t
5
2
cot
|
.
|

\
| t
5
2
.
Q.6
[Sol. Middle terms of the given series are a
5
and a
6
.
Now, a
i
a
11i
= 3 5 a
5
a
6
= 3 5
ab = 3 5 .......(1)
B (0, b)
F
(ae, 0)
F'
(ae, 0)
30
x
y
Since AFBF' is an equilateral triangle, so
tan 30 =
b
ae

2
2
a
b
=
4
3
.......(2)
From (1) and (2), we get
a
2
= 10, b
2
=
2
15
Also e
2
= 1
2
2
a
b
= 1
10 2
15

=
20
5
e =
2
1
As we know that quadrilateral formed by tangents at ends of latus rectum of ellipse is a rhombus whose
area =
e
a 2
2
=
2
1
10 2
= 40 sq. units Ans.]
MATHEMATICS
Code-A Page # 7
Q.7
Sol. Since system has non-trivial solution
D = 0
0
42 b a
c 23 a
c b 13
=
R
1
R
1
R
2
and R
2
R
2
R
3
0
42 b a
42 c b 23 0
0 23 b a 13
=

(13 a) [(23 b) 42 b (c 42)] + (b 23) a (c 42) = 0
by (a 13) (b 23) (c 42)
0
23 b
b
13 a
a
42 c
42
=

0
23 b
23
1
13 a
13
1
42 c
42
=
|
.
|

\
|

+ +
|
.
|

\
|
+
+ +

2
42 c
42
23 b
23
13 a
13
=

Absolute value is 2.
Q.8
[Sol. A = diag (a
1
, a
2
, a
3
)
A
2
= I
a
k
2
= 1 a
k
= 1 k = 1, 2, 3
number of diagonal matrix = 2
3
= 8 = m
a + b + c = a
2
+ b
3
+ c
4
, a = 0
a = 1, b
0
1
, c
0
1
Number of three digit number = 1 2 2 = 4 = n
m n = 8 4 = 4. Ans.]