Observed Result Absence of Monomer Table 1 Variation of Oxidant

OBSERVED RESULT
Absence of Monomer
Table 1
Variation of Oxidant
[LA] = 0.02 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]= 5 mol. dm-3
Temperature = 300c & 300c.
-3
Ce(IV) (mol. dm )
10-4 [-d [Ce(IV)/dt] mol. dm-3. Sec-1

30oC
30oC
0.003135
6.9079
5.3289
0.00418
7.6974
7.5
0.00523
8.2895
8.8816
0.06627
8.8816
10.8553
0.00732
0.00784
10.0658
10.8553
12.2368
12.4342
Table 2
Variation of Reductant
[LA] = 0.02 mol.dm-3
= 1.1 mol.dm-3
-3
[LA]Mol.dm
10-7(-d[ce(IV)/dt mol.dm-3s-1
30oC
35oC
0.02
14.013
14.605
0.03
15.395
15.395
0.04
15.987
16.974
0.05
16.579
17.961
0.06
17.566
19.145
0.07
17.961
20.132
34
Table 3
[LA] = 0.02 mol.dm-3
= 1.1 mol.dm-3
[LA]
-1
106 [-d [Ce(IV)/dt] mol. dm-3. Sec-1

30oC
30oC
50
0.7136
0.6847
33.33
0.6496
0.6496
25
0.6255
0.5891
20
0.6032
0.5568
16.67
0.5693
0.5223
14.29
0.5568
0.4967
Table 4
Variation of H2SO4
= 1.1 mol.dm-3
Ce(IV) = 0.02 mol.dm-3

[LA] = 5 mol. dm-3
[H2SO4]

30oC
35oC
20
1.2992
1.1783
3.33
1.1259
1.1014
1.818
1.034
1.0555
1.25
0.9559
0.9744
0.952
0.8587
0.9212
0.769
0.7795
0.8587
36
Variation of Monomer in -CD
Table 5
[LA] = 0.02 mol.dm-3
= 1.1 mol.dm-3
[M] x 10
-d [Ce]/dt x 10-3
-3
30oC
35oC
0.4
1.3613
1.2169
0.5
1.4438
1.3406
0.6
1.485
1.4438
0.7
1.5263
1.485
0.8
1.815
1.5263
0.9
2.0419
1.65
Variation of Oxidant in -CD
Table 6
[Ce(IV)]
= 0.02 mol.dm-3
[H2SO4]
= 5 mol. dm-3
Ce
= 1.1 mol.dm-3
-d [Ce]/dt x 10-3
4+
30oC
35oC
0.0031
1.1963
1.155
0.0042
1.2168
1.485
0.0052
1.2994
1.5469
0.0063
1.485
1.8769
0.0073
1.7119
1.9181
0.0078
1.8769
2.0625
38
Variation of Reductant - in -CD
Table 7
[Ce(IV)]= 0.02 mol.dm-3
= 1.1 mol.dm-3
[LA]
-d [Ce]/dt x 10-3
30oC
35oC
0.02
2.5369
2.6606
0.03
2.64
2.7844
0.04
2.7019
2.805
0.05
2.9494
2.9081
0.055
3.0525
2.9494
0.06
3.1969
3.0938
Variation of Reductant in -CD
Table 8
[Ce(IV)]= 0.02 mol.dm-3
= 1.1 mol.dm-3
[LA]
-d [Ce]/dt x 103
-1
30oC
35oC
50
0.3942
0.3759
33.33
0.3788
0.3591
25
0.3701
0.3565
20
0.3391
0.3439
18.18
0.3276
0.3391
16.67
0.3128
0.3232
40
Table 9
[LA] = 0.02 mol.dm-3
= 1.1 mol.dm-3
[LA]
-d( [M]/dt)-1 x 107
-1
30oC
30oC
50
0.2298
0.5546
33.33
0.804
0.5188
0.6702
0.4874
20
0.5744
0.4347
18.18
0.5361
0.4021
16.67
0.4347
0.3574
25
Variation of H2SO4 in -CD
Table 10
[Ce(IV)]= 0.02 mol.dm-3
= 1.1 mol.dm-3
[LA] = 0.2 mol. dm-3

-d( [M]/dt)-1 x 10-3
-1
[H2SO4]
30oC
35oC
20
0.3818
0.375
3.33
0.3618
0.373
1.818
0.3513
0.3488
1.25
0.3298
0.3463
0.952
0.3211
0.3414
0.769
0.3128
0.3298
42
Table 11
= 1.1 mol.dm-3
[LA] = 0.02 mol.dm-3

M
= 0.02 mol. dm-3

-d( [M]/dt)-1 x 107
-1
[H2SO4]
30oC
35oC
20
0.8042
0.8935
3.33
0.6993
0.5026
1.818
0.6434
0.4468
1.25
0.5188
0.383
0.952
0.4731
0.3497
0.769
0.4124
0.2978
Variation of Oxidant without -CD
Table 12
= 1.1 mol.dm-3
[Ce(IV)]= 0.02 mol.dm-3

[M
]= 0.02 mol. dm-3

104 [-d [Ce(IV)/dt] (mol. dm-3. Sec-1)-7
Ce(IV)
30oC
30oC
0.4
4.5375
3.5063
0.5
5.1563
4.125
0.6
6.1875
5.775
0.7
8.25
7.2188
0.8
8.6625
10.519
0.9
9.9
12.375
44
Table 13
[Ce(IV)] = 0.02 mol.dm-3
= 1.1 mol.dm-3
[LA]
-1

30oC
35oC
0.02
1.2581
1.1756
0.03
1.485
1.4025
0.04
1.65
1.6913
0.05
1.8768
1.8767
0.06
2.1038
2.0213
0.07
2.3719
2.145
Variation of Reductant without - CD
Table 14
[Ce(IV)] = 0.02 mol.dm-3
= 1.1 mol.dm-3
[LA]
-1

30oC
35oC
50
0.7948
0.8506
33.33
0.6734
0.713
25
0.6061
0.5913
20
0.5328
0.5328
18.18
0.4753
0.4947
16.67
0.4216
0.4662
46
Variation of Reductant without -CD
Table 15
[LA] = 0.02 mol.dm-3
= 1.1 mol.dm-3
Ce(IV)

30oC
35oC
0.4
4.5375
3.5063
0.5
5.1563
4.125
0.6
6.1875
5.775
0.7
8.25
7.2188
0.8
8.6625
10.519
0.9
9.9
12.375
Variation of H2SO4 without -CD
Table 16
[LA] = 0.02 mol.dm-3
= 1.1 mol.dm-3
-1
[H2SO4]
10-4 [-d [Ce(IV)/dt] (mol. dm-3. Sec-1)-7

30oC
35oC
20
0.1128
0.9507
3.33
0.1077
0.9148
1.818
0.0989
0.8815
1.25
0.0882
0.8359
0.952
0.0822
0.8081
0.769
0.0758
0.782
48
Table 17
= 1.1 mol.dm-3

[M]
= 0.02 mol. dm-3

[LA]

-1
30oC
35oC
50
0.9756
0.1088
33.33
0.9788
0.0783
25
0.1224
0.0653
20
0.0559
0.0544
18.18
0.0515
0.0445
16.67
0.035
0.0384
Variation of H2SO4 without -CD
Table 18
= 1.1 mol.dm-3

[LA]
= 0.02 mol. dm-3

-1
[H2SO4]

30oC
35oC
20
0.5292
0.4166
3.33
0.4895
0.3996
1.818
0.4351
0.3765
1.25
0.3996
0.356
0.952
0.3497
0.3435
0.769
0.3376
0.3108
50
Methyl acrylate
Variation of oxidant
Table 19
[LA] = 0.2 mol.dm-3
= 1.1 mol.dm-3

-3
Ce(IV) (mol. dm )
Without -CD
With -CD
0.003165
2.6813
11.963
0.00418
2.9188
12.168
0.00523
5.5688
12.994
0.00627
7.2188
14.85
0.00732
8.0438
17.119
0.00784
9.6938
18.769
Table 20
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3
[M]
= 0.02 mol.dm-3
-1
-3 -1
[CE(IV)] (mol. dm )

Without -CD
With -CD
0.003135
3.5063
11.55
0.00418
4.125
14.85
0.00523
5.775
15.469
0.00627
7.2188
18.769
0.00732
10.5188
19.181
0.00784
12.375
20.625
52
Table 21
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3

-3
[LA] (mol. dm )
Without -CD
With -CD
0.02
1.2581
2.5369
0.03
1.485
2.64
0.04
1.65
2.7019
0.05
1.8769
2.9494
0.06
2.1038
3.0525
0.07
2.3719
3.1969
VARIATION OF REDUCTANT
Table 22
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3
-3
[LA] mol. dm

Without -CD
With -CD
0.02
1.1756
2.6606
0.03
1.4025
2.7844
0.04
1.6913
2.805
0.05
1.8769
2.9081
0.06
2.0213
2.9494
0.07
2.145
3.0938
54
Table 23
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3
-1
-3
[LA] mol. dm
Without -CD
With -CD
50
0.7948
0.3942
33.33
0.6734
0.3788
25
0.6061
0.3701
20
0.5328
0.3391
16.67
0.4753
0.3276
14.29
0.4216
0.3128
Table 24
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3
-1
RP X 10-8
-3
[LA] mol. dm
Without -CD
With -CD
50
0.8506
0.3759
33.33
0.713
0.3591
25
0.5913
0.3565
20
0.5328
0.3439
16.67
0.4947
0.3391
14.29
0.4662
0.3232
56
Table 25
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3

107[-d [Ce(IV)/dt]-1 (mol. dm-3. sec-1)-1
-3
[LA] mol. dm
Without -CD
With -CD
50
9.756
0.2298
33.33
9.788
0.8042
25
1.224
0.6702
20
0.559
0.5744
16.67
0.515
0.5361
14.29
0.35
0.4347
Table 26
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3
-3
[LA] mol. dm

Without -CD
With -CD
50
1.088
0.5546
33.33
0.783
0.5188
25
0.653
0.4874
20
0.544
0.4347
16.67
0.445
0.4021
14.29
0.384
3574
58
VARIATION OF MONOMER
Table 27
[LA]
= 0.2 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3

10-4[-d [Ce(IV)/dt]-1 (mol. dm-3. sec-1)-1
[M] mol dm-3
Without -CD
With -CD
0.4
4.5375
13.613
0.5
5.1563
14.438
0.6
6.1875
14.85
0.7
8.25
15.263
0.8
8.6625
18.15
0.9
9.9
20.419
Table 28
[LA]
[H2SO4]
= 1.1 mol.dm-3
= 0.2 mol.dm-3
= 5 mol. dm-3

-3
[M] mol dm
Without -CD
With -CD
4.18
0.825
12.169
5.22
2.475
13.406
6.27
7.2188
14.438
7.31
9.6938
14.85
8.36
10.3125
15.263
9.4
11.3438
16.5
60
Variation of H2SO4
Table 29
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[LA]
= 0.2 mol. dm-3
-1
-3 -1
[H2SO4] (mol. dm )

Without -CD
With -CD
20
8.8688
26.194
3.33
9.2813
27.638
1.818
10.1063
28.463
1.25
11.3438
30.319
0.952
12.1688
31.144
0.769
13.2
31.968
Table 30
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[LA]
= 0.2 mol. dm-3
-1
-3 -1
[H2SO4] (mol. dm )

Without -CD
With -CD
20
10.519
26.606
3.33
10.931
26.813
1.818
11.344
28.669
1.25
11.963
28.875
0.952
12.375
29.288
0.769
12.788
30.319
62
Variation of H2SO4
Table 31
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[LA]
= 0.2 mol. dm-3
-1
-3 -1
[H2SO4] (mol. dm )

Without -CD
With -CD
20
0.5292
0.8042
3.33
0.4895
0.6993
1.818
0.4351
0.6434
1.25
0.3996
0.5188
0.952
0.3497
0.4731
0.769
0.3376
0.4124
Table 32
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[LA]
= 0.2 mol. dm-3
-1
-3 -1
[H2SO4] (mol. dm )

Without -CD
With -CD
20
0.4166
0.8935
3.33
0.3996
0.5026
1.818
0.3765
0.4468
1.25
0.356
0.383
0.952
0.3435
0.3497
0.769
0.3108
0.2978
64
Methylacrylate
Variation Of Oxident
Table 33
= 1.1 mol.dm-3

[M] = 0.02 mol.dm-3
-3

RP x 10-7
-3
[Ce](IV) x 10 (mol. dm )
Without -CD
With -CD
0.003135
2.3952
2.2171
0.00418
2.5932
2.3858
0.00523
2.8505
2.5062
0.00627
2.8901
2.5544
0.00732
3.0682
2.7713
0.00784
3.1672
2.8918
Table 34
[H2SO4]
[M]
= 5 mol. dm-3
= 0.02 mol.dm-3
[Ce](IV) x mol. dm-3
= 1.1 mol.dm-3
[-CD]= 0.02 mol.dm-3
Rp x 10-7
Without -CD
With -CD
0.003135
3.088
2.0002
0.00418
3.1672
2.1689
0.00523
3.286
2.2652
0.00627
3.3652
2.3375
0.00732
3.4443
2.3858
0.00784
3.5037
2.5303
66
Variation Of Redutant
Table 35
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3
Temperature = 300C & 300C.

RP X 10-8
-3
[LA] mol. dm
Without -CD
With -CD
0.02
0.3973
1.687
0.03
0.396
4.8198
0.04
3.1673
5.7836
0.05
6.9283
6.7474
0.06
7.5223
7.2297
0.07
11.0853
8.9163
Table 36
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[H2SO4]
= 5 mol. dm-3
[LA] mol. dm-3
Without -CD
RP X 10-8
With -CD
0.02
3.563
6.9887
0.03
4.9486
7.4706
0.04
5.9386
7.9525
0.05
7.1263
8.9163
0.06
8.7099
9.6395
0.07
10.0956
10.8443
68
Table 37
[Ce(IV)]
[H2SO4]
= 0.0209 mol.dm-3
= 5 mol. dm-3
= 1.1 mol.dm-3
RP-1 X 108
-3
[LA] mol. dm
Without -CD
With -CD
50
2.5171
0.5928
33.33
2.5253
0.2075
25
0.3157
0.1729
20
0.1443
0.1482
16.67
0.1329
0.1383
14.29
0.0902
0.1122
Table 38
[Ce(IV)]
[H2SO4]
= 0.0209 mol.dm-3
= 5 mol. dm-3
[LA] mol. dm-3
= 1.1 mol.dm-3
RP-1 X 108
Without -CD
With -CD
50
0.2807
0.1431
33.33
0.2021
0.1339
25
0.1684
0.1257
20
0.1408
0.1122
16.67
0.1148
0.1037
14.29
0.0991
0.0922
70
Table 39
[LA]
[H2SO4]
= 1.1 mol.dm-3
RP X 10-7
= 0.2 mol.dm-3
= 5 mol. dm-3
[M] mol dm-3
Without -CD
With -CD
0.4
3.187
2.0243
0.5
3.3652
2.2411
0.6
3.4047
2.2893
0.7
3.4641
2.3375
0.8
3.4839
2.4099
0.9
3.5631
2.5544
Table 40
[LA]
[H2SO4]
= 1.1 mol.dm-3
RP X 10-7
= 0.2 mol.dm-3
= 5 mol. dm-3
[M] mol dm-3
Without -CD
With -CD
0.4
2.7317
1.4218
0.5
2.8901
1.8074
0.6
3.0682
2.0484
0.7
3.2662
2.2652
0.8
3.3256
2.5544
0.9
3.4443
2.699
72
Table 41
Variation of H2SO4
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[LA]
= 0.2 mol. dm-3
-1
RPx 108
-3 -1
[H2SO4] (mol. dm )
Without -CD
With -CD
20
0.1365
0.2075
3.33
0.1263
0.1804
1.818
0.1123
0.166
1.25
0.1031
0.1339
0.952
0.0902
0.122
0.769
0.0871
0.1064
Table 42
Variation of H2SO4
[Ce(IV)]
= 0.0209 mol.dm-3
= 1.1 mol.dm-3
[LA]
= 0.2 mol. dm-3
-1
RPx 108
-3 -1
[H2SO4] (mol. dm )
Without -CD
With -CD
20
0.1075
0.2305
3.33
0.131
0.1297
1.818
0.0971
0.1153
1.25
0.0919
0.0988
0.952
0.0886
0.0902
0.769
0.0802
0.0768
74

Observed Result Absence of Monomer Table 1 Variation of Oxidant

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Observed Result Absence of Monomer Table 1 Variation of Oxidant

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OBSERVED RESULT

[LA] = 0.02 mol.dm-3

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 300c.

10-4 [-d [Ce(IV)/dt] mol. dm-3. Sec-1

[LA] = 0.02 mol.dm-3

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

[LA] = 0.02 mol.dm-3

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

106 [-d [Ce(IV)/dt] mol. dm-3. Sec-1

Ce(IV) = 0.02 mol.dm-3

Temperature = 300c & 350c.

Variation of Monomer in -CD

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

Variation of Oxidant in -CD

Variation of Reductant - in -CD

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

Variation of Reductant in -CD

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

Variation of Reductant in -CD

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

-d( [M]/dt)-1 x 107

Variation of H2SO4 in -CD

[LA] = 0.2 mol. dm-3

Temperature = 300c & 350c.

Variation of H2SO4 in -CD

[LA] = 0.02 mol.dm-3

= 0.02 mol. dm-3

Temperature = 300c & 350c.

Variation of Oxidant without -CD

[Ce(IV)]= 0.02 mol.dm-3

]= 0.02 mol. dm-3

Temperature = 300c & 350c.

Variation of Reductant in -CD

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

10-3 [-d [Ce(IV)/dt] mol. dm-3. Sec-1

Variation of Reductant without - CD

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

103 [-d [Ce(IV)/dt] mol. dm-3. Sec-1

Variation of Reductant without -CD

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 300c.

10-4 [-d [Ce(IV)/dt] mol. dm-3. Sec-1

Variation of H2SO4 without -CD

[H2SO4]= 5 mol. dm-3

Temperature = 300c & 350c.

10-4 [-d [Ce(IV)/dt] (mol. dm-3. Sec-1)-7

Variation of H2SO4 in -CD

Ce(IV) = 0.02 mol.dm-3

= 0.02 mol. dm-3

Temperature = 300c & 350c.

Variation of H2SO4 without -CD

Ce(IV) = 0.02 mol.dm-3

= 0.02 mol. dm-3