Sn 118.71 Fe 55.845 96500 2.

303
CATODO
Sn(+2a) + 2e- = Sn
T deltaH deltaS deltaG K E vs. SHE
K kJ J/K kJ V
298.150 8.786 -62.763 27.499 1.520E-005 -0.143
318.150 9.851 -59.303 28.718 1.926E-005 -0.149
368.150 12.129 -52.656 31.514 3.375E-005 -0.163

𝐸^° th calc=(−∆𝐺)/𝑛𝐹
T ºC/ºK Eºth, V
F(Kj/v.mol) 96.485
𝑛_(𝑒^ 2 Catodo
−) 25/298.15 -0.14250481
Sn= 30 g/L 45/318.15 -0.14882091
[Sn]= 0.2527167046 95/368.15 -0.16331046

Fe= 0.005 g/L -0.124835405

𝐸_𝑡ℎ=𝐸_𝑡ℎ^°+2.303𝑅𝑇/𝑛𝐹 𝑙
[Fe]= 8.953353E-05 +2.303𝑅𝑇/𝑛𝐹 𝑙𝑜𝑔[([𝛾_𝑜𝑥])/
T ºC pE

Catodo
25/298.15 -2.409E+000
45/318.15 -2.358E+000
95/368.15 -2.236E+000
Constantes A y B
TºC A B
25 0.5092 0.3283
45 0.52820 0.33150 0.5
95 0.58860 0.3388

Radio Ionico aparente a0

Zn++ 6
Fe++ 6
〖𝐿𝑜𝑔 (γ1) 〗 ^(𝑆𝑛−𝐹𝑒)
TºC γ Sn-Fe
25 -0.643101261 0.2274567
45 -0.667097577 0.21522981
95 -0.743380601 0.18055911

Metacovid20 Sn++/Fe
pH 0
Sn++ 30 g/L
Na F 25 g/L
NaH4HF2 36 g/L
NaCl 80 g/L
HCO3- 0.14
Fe++ 5
Pb++ 1
As+++ 0.1
Cr++ 0.5
 1000 8.314 298.15 318.15 368.15
ANODO
Fe (+2a) + 2e-=Fe
T deltaH deltaS deltaG K E vs. SHE
K kJ J/K kJ V
298.150 92.257 2.456 91.525 9.202E-017 -0.475
318.150 92.716 3.947 91.460 9.608E-016 -0.474
368.150 93.904 7.394 91.182 1.153E-013 -0.473

Eºth, V Eºth, V
Soluciones Ideales Soluciones Reales
Anodo C.C Catodo Anodo C.C Catodo Anodo C.C
0.47429568 0.33179087 -0.12483859 0.3545816 0.22974301 -0.16152359 0.45527691 0.29375332
0.47395905 0.32513814 -0.12996963 0.3462145 0.21624487 -0.16987273 0.45290722 0.28303449
0.47251703 0.30920657 -0.14149654 0.32469634 0.1831998 -0.19045637 0.44537112 0.25491475
+2.303𝑅𝑇/𝑛𝐹 𝑙𝑜𝑔[([𝑂𝑥])/([𝑅𝑒𝑑)]
𝐹 𝑙𝑜𝑔[([𝛾_𝑜𝑥])/([𝛾_𝑟𝑒𝑑 )]
pE pE
Soluciones Ideales Soluciones Reales
Anodo C.C Catodo Anodo C.C Catodo Anodo C.C
-8.018E+000 5.609E+000 -4.43307642 -8.31674495 3.88366853 -2.7306199 -8.33961255 5.60899265
-7.509E+000 5.151E+000 -4.38169658 -7.8073689 3.42567232 -2.69123823 -7.84223466 5.15099644
-6.469E+000 4.233E+000 -4.25986285 -6.7678403 2.50797745 -2.607546 -6.84084757 4.23330157

a=coef*concentracion
CELDA COMPLETA
Sn(+2a) + Fe = Sn + Fe(+2a)
T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
298.150 -83.471 -65.219 -64.026 1.652E+011 11.218
318.150 -82.865 -63.250 -62.742 2.004E+010 10.302
368.150 -81.775 -60.051 -59.668 2.928E+008 8.467
 Ions MW(g/mol) conc(g/L) concentracion (mol/L) Z CiZi2
Sn++ 118.71 30 0.2527167045742 2 1.01086682
Na + 23 25 1.0869565217391 1 1.08695652
F- 18.9 25 1.3227513227513 1 1.32275132
NaH4+ 27 36 1.3333333333333 1 1.33333333
HF2- 38.8 36 0.9278350515464 1 0.92783505
Na+ 23 80 3.4782608695652 1 3.47826087
CL- 35.5 80 2.2535211267606 1 2.25352113
HCO3- 61 0.14 0.0022950819672 1 0.00229508
Fe++ 55.8 5 0.089605734767 2 0.35842294
Pb++ 207 1 0.0048309178744 2 0.01932367
As+++ 74.9 0.1 0.0013351134846 3 0.01201602
Cr++ 52 0.5 0.0096153846154 2 0.03846154
11.8440443

Fuerza ionica 5.9220221482

Ions MW(g/mmol) conc(mg/L) concentracion (mol/L) Z CiZi2

Sn++ 118.71 30 0.0002527167046 2 0.00101087
Na + 23 25 0.0010869565217 1 0.00108696
F- 18.9 25 0.0013227513228 1 0.00132275
NaH4+ 27 36 0.0013333333333 1 0.00133333
HF2- 38.8 36 0.0009278350515 1 0.00092784
Na+ 23 80 0.0034782608696 1 0.00347826
CL- 35.5 80 0.0022535211268 1 0.00225352
HCO3- 61 0.14 2.295081967E-06 1 2.29508E-06
Fe++ 55.8 5 8.960573477E-05 2 0.00035842
Pb++ 207 1 4.830917874E-06 2 1.93237E-05
As+++ 74.9 0.1 1.335113485E-06 3 1.2016E-05
Cr++ 52 0.5 9.615384615E-06 2 3.84615E-05
Fe++ 0.0895335303071 2 0.35813412
Sn++ 0.2527167045742 2 1.01086682
1.38084498

Fuerza ionica 0.6904224919 I > 0.1 Ecuacion de Davis

√𝐼 0.8309166576
〖𝑙𝑜𝑔𝛾〗 _𝑖=−𝐴𝑧_𝑖^2
𝐼=1/2 ∑_𝑖▒𝑀𝑖𝑍2i (√𝐼/(1+√𝐼)−0.2𝐼)
Constantes A y B
TºC A B
25 0.5092 0.3283 TºC 〖𝐿𝑜𝑔 (γ1)γ〗 ^(𝑆𝑛−𝐹𝑒)
Sn-Fe
45 0.52820 0.33150 25 -0.64310126 0.2274567
95 0.58860 0.3388 45 -0.66709758 0.2152298
95 -0.7433806 0.1805591
Radio Ionico aparente a0
Zn++ 6
Fe++ 6
 5mg/L
0.005G/L

𝑧_𝑖^2
2𝐼)

) 〗 ^(𝑆𝑛−𝐹𝑒)