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  • Constante de Equilibrio Termodinamico

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    Jeff Jimmy TP
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    This document contains thermodynamic data and calculations for the reaction: CO + 3H2 → CH4 + H2O. It provides: 1) Heat capacity data for the reactants and products as a function of temperature. 2) Standard enthalpy and entropy of formation values for the reactants and products at 298K. 3) Calculated equilibrium constants, standard enthalpy and entropy changes for the reaction at various temperatures from 298K to 900K. 4) A comparison to experimental data from a 1994 journal article on calculating equilibrium constants and reaction enthalpies at different temperatures.

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    This document contains thermodynamic data and calculations for the reaction: CO + 3H2 → CH4 + H2O. It provides: 1) Heat capacity data for the reactants and products as a function of temperature. 2) Standard enthalpy and entropy of formation values for the reactants and products at 298K. 3) Calculated equilibrium constants, standard enthalpy and entropy changes for the reaction at various temperatures from 298K to 900K. 4) A comparison to experimental data from a 1994 journal article on calculating equilibrium constants and reaction enthalpies at different temperatures.

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    8 views7 pages

    Constante de Equilibrio Termodinamico

    Uploaded by

    Jeff Jimmy TP
    This document contains thermodynamic data and calculations for the reaction: CO + 3H2 → CH4 + H2O. It provides: 1) Heat capacity data for the reactants and products as a function of temperature. 2) Standard enthalpy and entropy of formation values for the reactants and products at 298K. 3) Calculated equilibrium constants, standard enthalpy and entropy changes for the reaction at various temperatures from 298K to 900K. 4) A comparison to experimental data from a 1994 journal article on calculating equilibrium constants and reaction enthalpies at different temperatures.

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    of 7

    ALUMNO: TACUNAN PAUCAR JEFF JIMMY E.A.P.

    :
    CÓDIGO: 2014200501A

    CONSTANTE DE EQUILIBRIO TERMODINÁMICO EN

    REACCION REACTANTES
    QUIMICA CO + H₂

    COEFICIENTES 1 3

    CAPACIDAD CALORIFICA Cp (J/mol K)


    N⁰ COMP. α β
    97 CO 3.087E+01 -1.285E-02
    75 H₂ 2.714E+01 9.274E-03
    C 0.000E+00 0.000E+00
    116 CH₄ 1.925E+01 5.213E-02
    77 H₂O 3.224E+01 1.924E-03
    C 0.000E+00 0.000E+00
    Δ -6.080E+01 3.908E-02

    T = 298 K
    (J/mol)
    N⁰ COMP. ΔH (form)* ΔG (form)*
    97 CO -1.106E+05 -1.374E+05
    75 H₂ 0.000E+00 0.000E+00
    C 0.000E+00 0.000E+00
    116 CH₄ -7.490E+04 -5.087E+04
    77 H₂O -2.420E+05 -2.288E+05
    C 0.000E+00 0.000E+00
    Δ 298 -2.063E+05 -1.423E+05

    T,K ΔH⁰ KJ/mol ΔG⁰ KJ/mol K


    298 -2.063E+05 -1.423E+05 8.6807886E+24
    300 -2.064E+05 -1.418E+05 4.9822119E+24
    350 -2.087E+05 -1.309E+05 3.440103E+19
    400 -2.108E+05 -1.196E+05 4.2159588E+15
    450 -2.128E+05 -1.081E+05 3569551272147
    500 -2.146E+05 -9.641E+04 11817881732
    550 -2.163E+05 -8.451E+04 106300101.084
    600 -2.178E+05 -7.246E+04 2035171.80585
    650 -2.193E+05 -6.029E+04 69978.1392412
    700 -2.206E+05 -4.801E+04 3824.97232621
    750 -2.217E+05 -3.564E+04 303.754715238
    800 -2.227E+05 -2.320E+04 32.7471169691
    820 -2.231E+05 -1.821E+04 14.4592202858
    840 -2.235E+05 -1.321E+04 6.62926738679
    860 -2.238E+05 -8.199E+03 3.1479990647
    880 -2.241E+05 -3.181E+03 1.54471797594
    900 -2.244E+05 1.844E+03 0.78161593185

    COMPARACION CON DATOS EXPERIMENTALES:

    PRACTICAL CALCULATION OF THE EQUILIBRIUM CONSTANT AND THE ENTHALPY OF REACT


    Knud Andersen
    University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen O, Denmark

    J. Chem. Educ. 1994 , 71 , 6 , 474


    Fecha de publicación : 1 de junio
    de 1994

    https://doi.org/10.1021/ed071p474
    INGENIERIRA QUIMICA

    UILIBRIO TERMODINÁMICO EN FUNCIÓN DE LA TEMPERATURA

    ANTES PRODUCTOS
    + C → CH₄ + H₂O + C

    0 1 1 0

    RIFICA Cp (J/mol K)
    ϒ δ
    2.789E-05 -1.272E-08
    -1.381E-05 7.645E-09
    0.000E+00 0.000E+00
    1.197E-05 -1.132E-08
    1.055E-05 -3.596E-09
    0.000E+00 0.000E+00
    3.606E-05 -2.513E-08

    ΔH₀ (J/mol)
    -1.902E+05

    IR (J/mol K)
    1.793E+02

    R (J/mol K)
    8.314

    lnK
    57.4231546046 VARIACION DE LA ENTALPIA CON LA TEMPERATURA
    56.8679161787 -1.950E+05
    44.9846181852 250 350 450 550 650 750 850 950

    35.9776534357 -2.000E+05
    28.9034610097
    23.1928796223 -2.050E+05
    ΔH⁰ (KJ/mol)

    18.4817767942
    -2.100E+05
    14.5260907988

    -2.150E+05

    -2.200E+05
    -2.050E+05

    ΔH⁰ (KJ/mol)
    -2.100E+05

    11.1559381757
    -2.150E+05
    8.24930651126
    5.71622051795 -2.200E+05
    3.48881492673
    2.67133229313 -2.250E+05
    1.89149429836 T(K)
    1.14676703345
    0.43484135384
    -0.2463917948

    AND THE ENTHALPY OF REACTION AT DIFFERENT TEMPERATURES

    nhagen O, Denmark
    MPERATURA

    850 950

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