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    jimena Bautista
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    This document summarizes the construction of the ternary system CO2(g)-CO(g)-SnO(g). It provides the equilibrium constants (K) and mole fractions (x) for the reactions SnO2 + CO(g) = SnO(g) + CO2(g) and SnO(g) + CO(g) = Sn + CO2(g) over a range of temperatures from 1000°C to 1400°C. The equilibrium constants and mole fractions were calculated using the Gibbs free energy values provided for each reaction at each temperature.

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    PARTE 3

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    This document summarizes the construction of the ternary system CO2(g)-CO(g)-SnO(g). It provides the equilibrium constants (K) and mole fractions (x) for the reactions SnO2 + CO(g) = SnO(g) + CO2(g) and SnO(g) + CO(g) = Sn + CO2(g) over a range of temperatures from 1000°C to 1400°C. The equilibrium constants and mole fractions were calculated using the Gibbs free energy values provided for each reaction at each temperature.

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    © All Rights Reserved
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    2 views2 pages

    Parte 3

    Uploaded by

    jimena Bautista
    This document summarizes the construction of the ternary system CO2(g)-CO(g)-SnO(g). It provides the equilibrium constants (K) and mole fractions (x) for the reactions SnO2 + CO(g) = SnO(g) + CO2(g) and SnO(g) + CO(g) = Sn + CO2(g) over a range of temperatures from 1000°C to 1400°C. The equilibrium constants and mole fractions were calculated using the Gibbs free energy values provided for each reaction at each temperature.

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    CONSTRUCCION DEL SISTEMA TERNARIO CO2(g)-CO(g)-SnO(g)

    𝒙𝑪𝑶
    𝑃𝑆𝑛𝑂 𝑃𝐶𝑂2 𝑥𝑆𝑛𝑂 𝑥𝐶𝑂2
    PARA LA REACCION: 𝒙𝑪𝑶𝟐 𝐾= = 𝑃𝑇
    𝑃𝐶𝑂 𝑥
    SnO2 + CO(g) = SnO(g) + CO2(g) 𝐾 ∗ 𝑥𝐶𝑂 𝐶𝑂
    0,05 0,11 0,18 0,25 𝑥𝑆𝑛𝑂 =
    T deltaG K 0,2 ∗ 𝑥𝐶𝑂2
    ºC kcal 𝒙𝑺𝒏𝑶
    1000,0 21,042 2,441E-004 0,0 0,1 0,1 0,2 𝑃𝑇 = 𝑃𝐶𝑂 + 𝑃𝐶𝑂2 + 𝑃𝑆𝑛𝑂 = 0,039
    1100,0 17,119 1,884E-003 0,3 0,5 0,9 1,2 𝑃𝐶𝑂2 𝑥𝐶𝑂2
    𝐾= =
    1200,0 13,239 1,086E-002 1,5 3,1 4,9 7,0 𝑃𝐶𝑂 𝑃𝑆𝑛𝑂 𝑥𝐶𝑂 𝑥𝑆𝑛𝑂 𝑃𝑇
    1300,0 9,400 4,943E-002 6,7 14,1 22,4 31,7 𝑥𝐶𝑂2
    𝑥𝑆𝑛𝑂 =
    1400,0 5,600 1,855E-001 25,0 52,8 83,9 118,9 0,2 ∗ 𝐾 ∗ 𝑥𝐶𝑂

    𝒙𝑪𝑶𝟐
    PARA LA REACCION: 𝒙𝑪𝑶
    SnO(g) + CO(g) = Sn + CO2(g)
    4,00 3,00 2,33 1,50 1,00 0,67 0,43 0,25 0,11
    T deltaG K
    ºC kcal 𝒙𝑺𝒏𝑶
    1000,0 -27,149 4,58E+004 0,2 0,2 0,1 0,1 0,1 0,0 0,0 0,0 0,0
    1100,0 -23,902 6,38E+003 1,6 1,2 0,9 0,6 0,4 0,3 0,2 0,1 0,0
    1200,0 -20,679 1,17E+003 8,8 6,6 5,1 3,3 2,2 1,5 0,9 0,5 0,2
    1300,0 -17,479 2,68E+002 38,2 28,7 22,3 14,3 9,6 6,4 4,1 2,4 1,1
    1400,0 -14,301 7,38E+001 138,9 104,2 81,0 52,1 34,7 23,1 14,9 8,7 3,9

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