FACT

REACCION 3CuO(s)+2CO2(g)+1H2O(l) + 1Cu3(CO3)2(O

8.314 1/T T ∆H J/mol ∆S j/mol*K ∆G kj/mol
2.303 0.00333333 300 -3303059.8 -1,097.254 -2973883.4
0.00285714 350 -3299934.7 -1,087.672 -2919249.7
0.0025 400 -3295815.7 -1,076.693 -2865138.5
0.00222222 450 -3291128.1 -1,065.661 -2811580.9
0.002 500 -3286112.9 -1,055.097 -2758564.5
0.00181818 550 -3280908.4 -1,045.178 -2706060.4
0.00166667 600 -3275591.3 -1,035.926 -2654035.5
0.00153846 650 -3270196 -1,027.290 -2602457.5
0.00142857 700 -3264723.9 -1,019.180 -2551297.7
0.00133333 750 -3259143.2 -1,011.481 -2500532.6
0.00125 800 -3253380.3 -1,004.044 -2450145.2
0.00117647 850 -3247299.1 -996.673 -2400127.1
0.00111111 900 -3240658.9 -989.086 -2350481.4
0.00105263 950 -3233037.1 -980.850 -2301229.1
0.001 1000 -3232391 -980.152 -2252238.7
0.00095238 1050 -3235828 -983.501 -2203151.5
0.00090909 1100 -3236684.5 -984.304 -2153950.3
0.00086957 1150 -3236480.1 -984.124 -2104737
0.00084402 1184.81 -3236024.8 -983.735 -2070481.7
0.00084402 1184.81 -3244127.7 -990.574 -2070481.7
0.00083333 1200 -3242980.1 -989.611 -2055446.6
Promedio -3260262.17 -1,018.480
Desvest 24550.2694 38.6761976
%error 0.753% 3.797%
 l𝑜𝑔⁡〖𝐾 _(𝑇_2 ) 〗 =log⁡〖𝐾 _(𝑇_1 ) 〗−
FACT (Δ_𝑟 𝐻^0)/(2.303∗𝑅) (1/𝑇_2 −1/𝑇_1 )

2(g)+1H2O(l) + 1Cu3(CO3)2(OH)2(g)
DCp°(J/mol*°K) K logK Log K´ %Error
4.82E+05 1.00E+304 304 378.585008 0.24534542
7.43E+05 1.00E+304 304 328.45356 0.08043934
8.91E+05 1.00E+304 304 290.854974 0.04324022
9.76E+05 1.00E+304 304 261.611629 0.13943543
1.03E+06 1.51E+292 292.177969 238.216953 0.18468544
1.05E+06 9.86E+260 260.993683 219.075855 0.16060859
1.07E+06 1.12E+235 235.048481 203.12494 0.13581684
1.09E+06 1.35E+213 213.130784 189.628011 0.11027395
1.10E+06 2.37E+194 194.375371 178.059215 0.08394148
1.13E+06 1.41E+178 178.148171 168.032926 0.05677995
1.18E+06 9.42E+163 163.974032 159.259922 0.02874913
1.26E+06 3.09E+151 151.490127 151.519037 0.00019084
1.41E+06 2.60E+140 140.414957 144.63825 0.03007723
1.66E+06 3.37E+130 130.527204 138.481756 0.06094172
-4.10E+05 4.38E+121 121.64191 132.940912 0.09288741
-3.47E+05 3.96E+113 113.598024 127.927767 0.1261443
-3.81E+04 1.91E+106 106.279986 123.370363 0.16080522
1.03E+05 3.96E+99 99.59775 119.209255 0.1969071
1.55E+05 1.90E+95 95.2785478 116.519659 0.22293697
7.69E+05 1.90E+95 95.2785478 116.519659 0.22293697
7.43E+05 2.94E+93 93.4690116 115.394905 0.23457928
l𝑜𝑔⁡〖𝐾 _(𝑇_2 ) 〗 =log⁡〖𝐾 _(𝑇_1 ) 〗−
(Δ_𝑟 𝐻^0)/(2.303∗𝑅) (1/𝑇_2 −1/𝑇_1 ) -(dDG°/dT)P (d(D G°/T)/d(
%Error %Error 1/T)P
∆H°/R
∆S° Jmol/°K ∆H° KJ/mol
Log K´´
304 -1.10E+03 -3.30E+06
-126.048213615588 1.13E+05 -4.05E+07
-18.536160211691 2.55E+05 -9.24E+07
53.1385420575736 3.95E+05 -1.50E+08
91.4888027820683 5.23E+05 -2.08E+08
96.793456052014 6.38E+05 -2.67E+08
98.2149581334228 7.42E+05 -3.25E+08
97.3485725565459 8.39E+05 -3.83E+08
95.133475488278 9.34E+05 -4.45E+08
92.1385278899597 1.04E+06 -5.12E+08
88.7155950782942 1.15E+06 -5.93E+08
85.0856235317401 1.31E+06 -6.97E+08
81.3887312457978 1.55E+06 -8.48E+08
77.714265904792 1.92E+06 -1.09E+09
74.1102655063021 -4.95E+05 2.84E+08
70.5932027107754 -4.35E+05 2.57E+08
67.1846940140099 -5.06E+04 2.72E+07
63.9020484922213 1.37E+05 -9.05E+07
72.2060871504719 2.11E+05 -1.40E+08
95.2785478337758 1.06E+06 -6.84E+08
83.8204125103388 1.03E+06 -6.72E+08
 ∆G°simplific ∆Gsimp +
%Error %Error %Error
ado(J) aporte ∆Cp

-2919249.7 -2.92E+06
-2864387 2.75E+07
-2809524.3 8.22E+07
-2754661.6 1.41E+08
-2699798.9 2.00E+08
-2644936.2 2.58E+08
-2590073.5 3.17E+08
-2535210.8 3.76E+08
-2480348.1 4.37E+08
-2425485.4 5.04E+08
-2370622.7 5.85E+08
-2315760 6.89E+08
-2260897.3 8.43E+08
-2206034.6 1.08E+09
-2151171.9 -2.89E+08
-2096309.2 -2.62E+08
-2041446.5 -3.27E+07
-1986583.8 8.42E+07
-1948388.39 1.34E+08
-1948388.39 6.79E+08
-1931721.1 6.67E+08
 DG = A + B*T
A B DG = DH - DS*T
-1115.454868 0.12253386
0.12253386226 -1115.45487 Hallando el valor de DH y DS
0.01004032311 8.46297725 DH kj/mol
0.88686563102 13.3468644 DS j/mol*K
148.941892209 19
26532.3282366 3384.63698
R^2 =

logK= A' + B' *(1/T)

A' B' 𝐥𝐧⁡(𝑲)=(−𝑯)/𝑹∗(𝟏/𝑻)+
27.664871 105276.041 (𝑺)/𝑹
105276.041104 27.664871
9403.8311287 15.5782315 Hallando el valor de DH y D
0.86835576474 30.1186596 DH kj/mol
125.328385994 19 DS j/mol*K
113689.596887 17235.5394
R^2 =