Bi 1t chay hoan toan 0,25 mol hn hp gm ankin A va anken B thu san ph!m l!

n l"t cho #ia $inh % &"ng '2(5 )", $inh %% &"ng *(+ )" th!y khi l"ng $inh % t,ng --,.g va $inh %% t,ng /0,0g1 2ac &inh cng th"c '3 cua a va B $i4t 5,ng A kem B - nguy4n t" 6 Bi 2hn hp +2, - ankan A, - ankin B1 em &t -00cm/ 2 &"c 2-0cm/ 6(21 74u nung n8ng -00cm/ 2 vi 7i 9uc tac chi c:n .0cm/ - hi)5ocac$on )uy nh!t a, inh A,B1 tinh ; theo h4 tich cac khi t5ong 2 <$i4t cac khi &o c=ng &k> $, 3inh th4 tich khi (2 c!n )ung &4 &t chay -00cm/ hh 2 Bi 3hon hop kh? 2 g@m +2, 62+2, 62+A1 c8 7i lBm 9Cc tDc thu )c 5,E lit hFn hGp kh? H c8 tI khJi hi &Ji vKi +2 $Lng -2,21 Jt chDy hoBn toBn hFn hGp 2 5@i hMp thN toBn $O sPn phQm chDy vBo )) 6a<(+>2 )" tRo kS tTa1 3?nh khJi l"Gng kSt tTa t54n1 Bi 4 U lBm sRch etilen c8 lVn a9etilen ta cho hFn hGp &i #ua )) nBo sau &!y Bi 5 A la hi&5ocac$on mach h, th4 khi <&kt>, $i4t A - mol A tac )ung &"c ti &a 2 mol B52 t5ong )ung )ich tRo 5a hGp chMt B <t5ong B $5om chiSm 00,00; vW khJi l"Gng1 X!y A co cng th"c ph!n t" la A1 65+01 A1 65+0 1 B1 62+21 B1 62+21 61 6A+E1 61 6/+A1 Y1 6/+A1 Y1 6A+E1 Bi 6 ZMy A gam mOt ankin 2 c8 thU lBm mMt mBu tJi &a -00 ml )ung )[ch B52 2\1 63'3 2 lB Bi 7 2 lB mOt hi&5ocac$on khng no mRch h], - mol 2 c8 thU lBm mMt mBu tJi &a 2 mol $5om t5ong n"Kc1 2 c8 ; khJi l"Gng + t5ong ph!n t^ lB -0;1 63'3 2 lB A1 62+21 B1 6/+A1 61 62+A1 Y1 6A+E Bi 8 +Fn hGp A g@m 62+2 vB +2 c8 )A_+2 ` 5,01 YVn A <&ktc> #ua $Ot 7i nung n8ng cho &Sn khi cDc phPn ang 9Py 5a hoBn toBn ta &"Gc hFn hGp B1 'hbn t5,m thU t?ch mFi kh? t5ong hFn hGp A vB )B_+2 lB A1 A0; +2c E0; 62+2c 2d1 61 E0; +2c A0; 62+2 c 2d1 B1 A0; +2c E0; 62+2 c -A,51 Y1 E0; +2c A0; 62+2 c -A,51

Bi 9 6ho -0 l?t hFn hGp kh? 6+A vB 62+2 tDc )Nng vKi -0 l?t +2 <7i, to>1 eau khi phPn ang 9Py 5a hoBn toBn thu &"Gc -E l?t hFn hGp kh? <cDc kh? &Wu &o ] c=ng &iWu kifn nhift &O Dp suMt>1 3hU t?ch cTa 6+A vB 62+2 t5"Kc phPn ang lB A1 2 l?t vB 0 l?t1 B1 / l?t vB . l?t1 61 0 l?t vB 2 l?t1 Y1 2,5 l?t vB .,5 l?t1 Bi 10 +Fn hGp 2 g@m p5opin vB mOt ankin A c8 tI lf mol -g-1 ZMy 0,/ mol 2 tDc )Nng vKi )ung )[ch Ag7(/_7+/ )" thu &"Gc AE,2 gam kSt tTa1 A lB A1 Buth-hin1 B1 Buth2hin1 61 A9etilen1 Y1 'enth-hin1 Bi 11 Jt chDy hoBn toBn mOt ankin 2 ] thU kh? thu &"Gc +2( vB 6(2 c8 ting khJi l"Gng lB 2/ gam1 7Su cho sPn phQm chDy &i #ua )ung )ich 6a<(+>2 )", &"Gc A0 gam kSt tTa1 6ng thac ph!n t^ cTa 2 lB A1 6/+A1 B1 62+21 61 6A+E1 Y1 65+01 Bi 12 +Fn hGp 2 g@m 62+2 vB +2 lMy c=ng sJ mol1 ZMy mOt l"Gng hFn hGp 2 cho &i #ua chMt 9Cc tDc th?ch hGp, &un n8ng &"Gc hFn hGp H g@m A chMt1 YVn H #ua $jnh &kng n"Kc $5om thMy khJi luGng $jnh t,ng -0,0 gam vB

thoDt 5a A,A0 l?t kh? l <&ktc> c8 tI khJi so vKi +2 lB 01 3hU t?ch (2 <&ktc> cbn &U &Jt chDy hoBn toBn hFn hGp H lB A1 //,E l?t1 B1 22,A l?t1 61 -E,0 l?t1 Y1 AA,0 l?t1 Bi 13 6ho -.,d2 l?t hFn hGp 2 g@m / hi&5ocac$on kh? lB ankan, anken vB ankin lMy theo tI lf mol -g-g2 lOi #ua $jnh &kng )) Ag7(/_7+/ lMy )" thu &"Gc dE gam kSt tTa vB hFn hGp kh? H c:n lRi1 Jt chDy hoBn toBn hFn hGp H thu &"Gc -/,AA l?t 6(21 BiSt thU t?ch &o ] &ktc1 *hJi l"Gng cTa 2 lB A1 -d,2 gam1 B1 -,d2 gam1 61 /,0A gam1 Y1 /0,A gam1 Bi 14 \Ot hFn hGp g@m 2 ankin khi &Jt chDy cho 5a -/,2 gam 6(2 vB /,E gam +2(1 3?nh khJi l"Gng $5om c8 thU cOng vBo hFn hGp t54n A1 -E gam1 B1 2A gam1 61 /2 gam1 Y1 A gam1 Bi 15 6ho can9i cac$ua km thunt <chI chaa 00; 6a62 nguy4n chMt> vBo n"Kc )", thj thu &"Gc /,/E l?t kh? <&ktc>1 *hJi l"Gng can9i cac$ua km thunt &o )=ng lB A1 d,E gam1 B1 A,0 gam 61 A,E gam1 Y1 -2 gam Bi 16 6ho hFn hGp 2 g@m 6+A, 62+A vB 62+21 ZMy 0,E gam 2 tDc )Nng hSt vKi )ung )[ch $5om <)"> thj khJi l"Gng $5om phPn ang lB A0 gam1 \pt khDc, nSu cho -/,AA l?t <] &ktc> hFn hGp kh? 2 tDc )Nng vKi l"Gng )" )ung )[ch Ag7(/ t5ong 7+/, thu &"Gc /E gam kSt tTa1 'hbn t5,m thU t?ch cTa 6+A c8 t5ong 2 lB A1 A0;1 B1 20;1 61 25;1 Y1 50;1 Bi 17 Jt chDy hoBn toBn - l?t hFn hGp kh? g@m 62+2 vB hi&5ocac$on 2 sinh 5a 2 l?t kh? 6(2 vB 2 l?t hi +2( <cDc thU t?ch kh? vB hi &o t5ong c=ng &iWu kifn nhift &O vB Dp suMt>1 6ng thac ph!n t^ cTa 2 lB A1 62+A1 B1 6+A1 61 62+E1 Y1 6/+01 Bi 18 +Fn hGp 2 c8 tI khJi so vKi +2 lB 2- g@m p5opan, p5open vB p5opin1 *hi &Jt chDy hoBn toBn 0,- mol 2, ting khJi l"Gng cTa 6(2 vB +2( thu &"Gc lB A1 -0,E0 gam1 B1 -0,dE gam1 61 20,A0 gam1 Y1 -E,00 gam Bi 19 Jt chDy hoBn toBn hFn hGp \ g@m mOt ankan 2 vB mOt ankin H, thu &"Gc sJ mol 6(2 $Lng sJ mol +2(1 3hBnh phbn ; vW sJ mol cTa 2 vB H t5ong hFn hGp \ lbn l"Gt lB A1 /5; vB E5;1 B1 .5; vB 25;1 61 20; vB 00;1 Y1 50; vB 50;1 Bi 20 \Ot hFn hGp 2 g@m 62+2, 6/+E, 6+A1 Jt chDy hoBn toBn --?t hFn hGp 2 thu &"Gc -2,E gam +2(1 7Su cho --,2 l?t hFn hGp 2 <&ktc> #ua )ung )[ch $5om )" thMy c8 -00 gam $5om phPn ang1 3hBnh phbn ; thU t?ch cTa 2 lbn l"Gt lB A1 50;c 25; c 25;1 61-E; c /2c 52;1 B1 25; c 25c 50;1 Y1 //,//;c //,//c //,//;1

Bi 21 YVn A,0/2 l?t <&ktc> hFn hGp kh? A g@m 62+2, 62+A, 6+A lbn l"Gt #ua $jnh - chaa )ung )[c Ag7(/ t5ong 7+/ 5@i #ua $jnh 2 chaa )ung )[ch B52 )" t5ong 66lA1 q $jnh - c8 .,2 gam kSt tTa1 *hJi l"Gng $jnh 2 t,ng th4m -,E0 gam1 3hU t?ch <&ktc> hFn hGp A lbn l"Gt lBg A1 0,E.2 l?tc -,/AA l?tc 2,0-E l?t1 61 2,0-Ec 0,0dE l?tc -,-2 l?t1 B1 0,E.2 l?tc 0,E.2 l?tc 2,E00 l?t1 Y1 -,/AA l?tc 2,0-E l?tc 0,E.2 l?t1

Bi 22+Fn hGp 2 g@m 0,- mol 62+2c 0,-5 mol 62+A c 0,2 mol 62+E vB 0,/ mol +21 un n8ng 2 vKi $Ot 7i 9Cc tDc - thri gian &"Gc hFn hGp H1 Jt chDy hoBn toBn hFn hGp H &"Gc sJ gam 6(2 vB +2( lbn l"Gt lB A1 /d,E vB 2/,A1 B1 /,dE vB /,/51 61 /d,E vB AE,01 Y1 /d,E vB --,E1 Bi 23 +Fn hGp $an &bu g@m - ankin, - anken, - ankan vB +2 vKi Dp suMt A atm1 un n8ng $jnh vKi 7i 9Cc tDc &U thkc hifn phPn ang cOng sau &8 &"a $jnh vW nhift &O $an &bu &"Gc hFn hGp H, Dp suMt hFn hGp H lB / atm1 3I khJi hFn hGp 2 vB H so vKi +2 lbn l"Gt lB 2A vB 91 siD t5[ cTa 9 lB A1 -01 B1 /A1 61 2A1 Y1 /2 Bi 24 +Fn hGp A g@m +2, 6/+0, 6/+A1 6ho tt tt -2 l?t A #ua $Ot 7i 9Cc tDc1 eau phPn ang &"Gc E l?t kh? )uy nhMt <cDc kh? &o ] c=ng &iWu kifn>1 3I khJi hi cTa A so vKi +2 lB A1 --1 B1 221 61 2E1 Y1 -/1 Bi 25 un n8ng hFn hGp 2 g@m 0,- mol 6/+A c 0,2 mol 62+A c 0,/5 mol +2 vKi $Ot 7i 9Cc tDc &"Gc hFn hGp H1 YVn toBn $O H #ua $jnh &kng )ung )[ch *\n(A )", thMy thoDt 5a E,.2 l hFn hGp kh? l <&ktc> c8 tI khJi so vKi +2 lB -21 Bjnh &kng )ung )[ch *\n(A t,ng sJ gam lBg A1 -.,21 A1 -A,A1 phPn ang lBg A1 2A,01 B1 A5,/1 61 /d,21 Y1 5-,21 B1 d,E1 B1 -0,01 61 .,21 61 -21 Y1 /,-1 Y1 5E,0 Bi 26 Jt chDy m gam hFn hGp 62+E, 6/+A, 6/+0, 6A+-0 &"Gc /5,2 gam 6(2 vB 2-,E gam +2(1 siD t5[ cTa m lB Bi 27Jt chDy - hi&5ocac$on A &"Gc 22,A l?t kh? 6(2 <&ktc> vB 2. gam +2(1 3hU t?ch (2 <&ktc> <l> tham gia