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Βαρέα μέταλλα στα θαλάσσια ιζήματα. Δείκτες ρύπανσης θαλασσίων ιζημάτων από βαρέα μέταλλα.
Βαρέα μέταλλα στα θαλάσσια ιζήματα. Δείκτες ρύπανσης θαλασσίων ιζημάτων από βαρέα μέταλλα.
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.
: 50
4
: 90764
: 29/03/2014
1. ............................................................................................................................... 2
2. , ......................................................... 3
2.1 ..................................................... 3
2.2 ................................................................. 4
3. ........................................... 8
4. ........................................................................................................ 10
5. .................................................................................................................... 12
6. ....................................................................................................................... 13
1 14
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1.
(Fe).
. . ,
,
. , , ,
(, 2007).
, .
, ,
()
(, 2003).
.
.
, , , ,
(Anon., n.d.).
, , ,
,
, ,
( 1),
(, et al., 2004).
1. . : (, et al., 2004)
(boulders)
(cobbles)
(mm)
256-1,024
(gravel)
64-256
(pebbles)
4-64
(granules)
2-4
2 14
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(sand)
(silt)
(clay)
(sand)
(mud)
0,062-2
0,004-0,062
< 0,004
:
)
, . :
, , , , , , , ,
.
)
: , , ,
(, et al., 2004).
(, et al.,
2004).
:
(Hg) > (Cu) > (Zn) > M (Pb) > (Cd)
> (Cr) > (Mn) (, 2000)
2. ,
2.1
,
(, 2007).
,
: ,
(.. ) (
,
) ,
3 14
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(, et al.,
2004).
(, 2007) (,
1988). , (Cd, Zn, Hg, Pb)
,
As, Se Cr
(, et al., 2002).
,
, Portman
. (
) . 1958 1991, 50
(Cesar, et al., 2009).
,
,
( ,
, ).
: ,
, , ,
(, 2007) (, 1988).
2.2
( )
.
, .
,
.
,
(Ansari, et al., 2004).
4 14
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( 1).
1. .
: (Ohman & Sjoberg, 1988):
, ,
, , (Abd El Wahab, et al., 2011).
,
, (, et al.,
2004).
,
,
, ,
5 14
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.
.
,
(.. ) .
,
,
,
. , , 50-70%
<2m, 5m
,
(Edwing, et al., 1973) (Dean, et al.,
1985).
(
).
(, et al.,
2004).
( 2)
.
6 14
50/_4/.
2. . : (, et al., 2004)
, (hydroxides),
(carbonates),
( sulfides)
(precipitation)
(Ksp)
pH -
pH -
Y Fe Mn
pH -
(coprecipitation)
pH -
pH -
(broken
bonds)
,
SI Al3,
A Al3
pH -
Fe Mn
pH -
( van
der Waals)
(Bitumen)
(Humic
substances)
(organic
residuals)
pH -
X (
COOH - OH - )
pH -
(complexation)
pH -
A
pH -
(Pseudomorfosis)
7 14
50/_4/.
3.
(pollution indices)
(C)
(Cb): C/Cb,
. (Cb)
, (, et
al., 2004).
( 3)
3. . : (, et al.,
2004)
Igeo
(Geoaccumulation Index)
Muller, 1979
P.L.I
S.E.F.
M.I.
(Micropollutant index)
M.P.I
. M.P.I.
P.L.I., M.I., S.E.F.
Igeo = log2(Cn/1,5xBn)
Cn: (<2m)
Bn:
.
1,5:
.
7 ( 4),
6 96
.
4. Igeo . : (, et al., 2004)
Igeo
0-1
1-2
2-3
3-4
4-5
>5
(MIgeo)
Sutherland (Sutherland, 2000) :
MIgeo = (Cn/1,5xBEn)
n,
.
CF (Contamination Factor)
. (Cn/Bn).
CF < = 1, ,
CF > 1 (Soares, et al., 1999).
9 14
50/_4/.
, EF (Enrichment Factor)
(Sinex & Helz, 1981).
EF = (/Fe) / (/Fe)
/Fe
.
EF
( 5) (Birth, 2003).
5. . : (Birth, 2003)
EF
1-3
3-5
5-10
10-25
25-50
> 50
4.
,
,
,
, pH (Butter, 1988).
, , .
10 14
50/_4/.
,
, ..
(Patterson, 1985)
6 (Eccles, 1999)
3.
: (Eccles, 1999)
pH
(mg
L-1)
<10
>10
<100
>10
:
-
>10
>10
,
.
(bioleaching),
11 14
50/_4/.
/
.
.
(, 2003).
5.
.
/ ,
(, )
.
, ,
,
(, et al., 2004).
.
(, 2007).
.
.
.
, ,
.
12 14
50/_4/.
6.
Abd El Wahab, M., Melegy, A. & Helal, S., 2011. Distribution and Enrichment of Heavy Metals
in Recent Sediments of Safaga Bay, Egypt. Marine Georesources & Geotechnology, 29(4), pp.
364-375.
Anon., n.d. - . []
Available at: http://el.wikipedia.org/wiki/%CE%8A%CE%B6%CE%B7%CE%BC%CE%B1
[ 25 3 2014].
Ansari, T., Marr, I. & Tariq, N., 2004. Heavy Metals in Marine Pollution Perspective. Journal of
Applied Sciences, 4(1), pp. 1-20.
Birth, G., 2003. A scheme for assessing human impacts on coastal aquatic environments
using sediments. In: Woodcoffe CD,. Papers in Center for Maritime Policy, p. 14.
Butter, T., 1988. : The use of biosorption, elution and electrolysis for
the removal and recovery of heavy metals from aqueous solutions, Newcastle: Civil
Engineering Dept., Univ. Newcastle.
Cesar, A. ., 2009. Integrative ecotoxicological assessment of sediment in Portmn Bay
(southeast Spain). Ecotoxicology and Environmental Safety, Issue 72, pp. 1832-1841.
Dar, M. A., 2014. Distribution patterns of some heavy metals in the surface sediment
fractions at northern Safaga Bay, Red Sea, Egypt. Arabian Journal of Geosciences, 7(1), pp.
55-67.
Dean, W., Leinen, . M. & Stow, . D., 1985. Classification of deep sea, fine-grained sediments.
Journal of Sedimentary Petrology, Issue 55, pp. 250-256.
Eccles, H., 1999. Treatment of metal-contaminated wastes: why select a biological process..
Trends in Biotechnology, 17, pp. 462-465.
Edwing, M., Carpenter, G. & Windish, C., 1973. Sediment distribution in the oceans: The
Antlantic. Geological Society of America Bulletin, Issue 84, pp. 71-88.
Mueller, P. J. & Suess, E., 1979. Productivity, sedimentation rate, and sedimentary organic
matter in the oceansI. Organic carbon preservation. Deep Sea Research Part A.
Oceanographic Research Papers, 26(12), p. 13471362.
Ohman, L. & Sjoberg, S., 1988. Metal Speciation: Theory and Analysis and Applications. p. 1.
Patterson, J. W., 1985. Industrial wastewater treatment technology. 2nd ed. Stoneham, USA:
Butterworth Publishers.
13 14
50/_4/.
Sinex, . S. A. & Helz, G. R., 1981. Regional geochemistry of trace elements in Chesapeake Bay
sediments. Environmental Geology, 3(6), pp. 315-323.
Soares, H., Boaventura, R., Machado, A. & Esteves da Silva, J., 1999. Sediments as monitors
of heavy metal contamination in the Ave river basin (Portugal): multivariate analysis of data.
Environmental Pollution, 105(3), p. 311323.
Sutherland, R., 2000. Bed sediment-associated heavy metals in an urban stream.
Environmental Geology, 39(6), pp. 611-627.
, . ., 2004. .
50/4 . : .
, ., 2000. , . ' . :
Gutenberg.
, ., , . & , ., 2002.
. s.l.: .
, ., , ., , . & , ., 2004.
. 50/2 . : .
, ., 2003. :
. : ,
.
, ., 2007. :
. (): & ,
.
, ., 1988. - ,
, . : & .
, ., 2007. :
. (): & ,
.
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