University of Jordan

Faculty of Engineering and Technology

Chemical Engineering Department
Chemical Engineering Thermodynamics II
Exam II (Make-up)
Type: Openbook Exam
Given on: Tuesday 27/5/2003
Duration: 50 minutes
Weight: 100 points
1. (20 points) Calculate the fugacity of liquid isobutane at 190

F and
150 psia if vapor pressure of isobutane at 190

F is 229.3 psia. The
following P-V data is available.
P(psia) V (ft
3
/lb)
10 11.854
14.7 8.023
20 5.860
40 2.861
60 1.860
80 1.360
100 1.060
150 0.6557
200 0.4504
250 0.03499
2. (20 points) establish by direct calculation that for steam mixture at 2.5
MPa and 224

C.
G
L
= G
V
(1)
3. (20 points) The following expression for the heat of mixing has been
suggested
H
mix
= A + Bx
1
x
2
(2)
1
(a) What is the value of A?
(b) Find an expression for the partial molar enthalpy of component 1.
(c) Find an expression for the innite dilution partial molar enthalpy
of component 1.
4. (20 points) The following set of reactions has been proposed for the
reactions of steam with coal
C + 2H
2
O CO
2
+ 2H
2
C + H
2
O CO + H
2
C + CO
2
2CO
C + 2H
2
CH
4
CO + H
2
O CO
2
+ H
2
How many independent reactions are there?
5. (20 points) Compute the adiabatic mixing temperature when equal
weights of aqueous solutions containing 10 (wt)% sulfuric acid at 20

C
and, 90 (wt)% sulfuric acid at 70

C are mixed.
2