Treat 500 SCFM of air containing 14%mol acetone to remove 95% of the acetone by absorption

in liquid water in a packed bed operating at 80F and 1 atm, with 1 in rasching rings.
The feed water contains 0.02% acetone and the flowrate is 1.1 times the minimum.
The partial pressure of acetone over an aqueous solution at 80F can be calculated from
pA = PAAxA where ln A = 1.95(1-x)^2
where PA = 0.33 atm at 80F.
V2
L2
As designer, you must select the following:
Y2
0.0081
X2

2.67
0.0002

flowrate of water
diameter of tower
height of packing
Jawab
500 SCFM
G
0.14
y1
Recover
0.95
0.0002
x2
L2
1.1 Lmin
pA = PAAxA where ln A = 1.95(1-x)^2
PA
0.33 atm
P
1 atm

V1
Y1

1.39
0.1628

L1
X1

0.0810

1. Merubah SCFM menjadi lbmol/min

V (STP)
22.4 ltr/gmol
359 ft3/lbmol
1.39 lbmol/min
V1
2. Menentukan Laju alir minimum
2.1 Menggambar kurva kesetimbangan
Dalam bentuk rasio mol
x
0
0.01
0.02
0.03
0.04
0.05
0.06

A
7.0287
6.7612
6.5064
6.2636
6.0322
5.8117
5.6014

pA
0.0000
0.0223
0.0429
0.0620
0.0796
0.0959
0.1109

y* = pA/P
0.0000
0.0223
0.0429
0.0620
0.0796
0.0959
0.1109

0.07
0.08
0.09
0.1

5.4008
5.2095
5.0269
4.8525

0.1248
0.1375
0.1493
0.1601

0.1248
0.1375
0.1493
0.1601

2.2 Membuat garis operasi

Merubah dalam bentuk rasio mol
X = x / (1-x)
Y = (L/V) X + Y2 = 1.91 X + 0.00814
0.0002 V1 y1 + L x = V y + L1 x1
0.1628 V' (y1/(1-y1)) + L' (x/(1-x)) = V'(y/(1-y)) + L'(x1/(1-x1))

x2
0.0002 -->
X2
y1
0.1400 -->
Y1
Y2
0.00814
Kurva kesetimbangan (EC) berada di bawah garis operasi (OL).
Selanjutnya, minimum slope tercapai ketika OL menyinggung EC.
Akhirnya, X1 bisa dibaca pada OL.
X1 =
0.081
1
(L'/V')min =(Y1-Y2)/(X1-X2)
1.914
maka Lmin
2.666 lbmol/min
Atau
X
0.0000
0.0101
0.0204
0.0309
0.0417
0.0526
0.0638
0.0753
0.0870
0.0989
0.1111

18 lbmol/min
Y*
0.0000
0.0228
0.0449
0.0661
0.0865
0.1061
0.1247
0.1425
0.1595
0.1755
0.1907

8.330 lb/gal

5.76 gal/min

Pembuktian rumus
V' = V(1-y2)
L' = L(1-x2)
y2
0.008074
1-y2
0.991926
1-x2
0.9998
jadi V' hampir sama V
jadi L' hampir sama
L

Y
0.0081
0.0274
0.0471
0.0672
0.0877
0.1087
0.1301
0.1519
0.1742
0.1970
0.2204

Jika diinginkan x1 = 0.07

Hitung berapa nilai NOG ?

V2
y2

0.00807

L2
x2

0.00
0.0002

V1
y1

1.39
0.1400

L1
x1

0.0700

Jawab
1. Menghitung slope OL
L [x1/(1-x1) - x2/(1-x2)] = V [y1/(1-y1) - y2/(1-y2)]
L [X1 - X2] = V [Y1 - Y2]
y1
y2
x1
x2

0.14
0.00807
0.07
0.0002
Y1-Y2
X1-X2
L/V

Y1 0.1628
Y2 0.0081
X1 0.0753
X2 0.0002
-0.1547
-0.0751
2.060178 slope

y* = 0.33 * exp (1.95*(1-x2)^2) * x

2. Menghitung
NOG
Menggunakan metoda Wiegand
NOG = INTEGRAL y1-y2 [dy/(y*-y)]
atau dibalik
NOG = INTEGRAL y2-y1 [dy/(y-y*)]
y
0.00807
0.022
0.036
0.05
0.063
0.076
0.089
0.102
0.115
0.128
0.14

X
0.0002
0.0072
0.0144
0.0218
0.0289
0.0362
0.0437
0.0514
0.0593
0.0675
0.0753

x
0.0002
0.0071
0.0142
0.0213
0.0281
0.0349
0.0418
0.0489
0.0560
0.0632
0.0700

y*
0.0005
0.0161
0.0311
0.0456
0.0585
0.0708
0.0827
0.0941
0.1051
0.1155
0.1248

1/(y-y*) Integrasi
131.467
2.0885
168.393
2.6133
204.932
3.0153
225.819
2.8986
220.119
2.6900
193.725
2.2949
159.343
1.8611
126.987
1.4787
100.508
1.1737
80.063
0.8741
65.615
20.988

3. Menghitung ketinggian tower, jika

Kga
0.04 lbmol/s m3
DT
1 m
Jawab
R
0.5
S
0.7854
dari soal diatas V=
G
0.0295
HOG
0.7374
Z
15.48

m
m2
1.39 lbmol/min 0.023167 lbmol/s
lbmol/s m2
m
HOG = V/S/Kga
m
Z=HOG x NOG

A gas stream containing a valuable hydrocarbon (MW = 44) is to be scrubed with na nonvolatile oil (MW=300) in a tower packed with 1-in Raschig rings.
The entering gas analyzes 20 mole percent hydrocarbon and 95% percent of this hydrocarbon is to be recovered.
The inert gas molecular weight is 29.
The gas stream enters the column at 5000 lb/hr ft2 and hydrocarbon-free oil enters the top of the column at 10000 lb/hr/ft2.
Determine the NOG for this operation.
Jawab
Dari soal
MW HC
MW Gas Inert
MW Oil
GV
GL
y1
Recover
L2
x2

44
29
300
5000
10000
0.2
0.95
33.3
0

V2
y2

126.6
0.0123

L2
x2

33.3
0

V1
y1

156.25
0.20

L1
x1

63.0
0.471

lb/lbmol
lb/lbmol
lb/lbmol
lb/hr/ft2
lb/hr/ft2
fraksi mol
lbmol/hr ft2
fraksi mol

1. Menghitung V1
Basis 1 lbmol gas masuk
Menghitung MW gas
% in V
MW
0.2
8.8
0.8
23.2
32
Maka
156.25 lbmol/hr ft2
V1

cara cepat menghitung y2

Y1
0.25
Y2
0.0125
y2
0.0123457

2. Menghitung V2
Menghitung y2
Gas bebas solute masuk = Gas bebas solute keluar
=
0.8 lbmol/mol gas masuk
HC keluar
0.01 lbmol
0.01235
y2
126.6 lbmol/hr ft2 = 0.8*V1/(1-Y2)
V2

3. Menghitung x1
Lb mol HC di L1
HC di L1
Oil bebas solute
Total mole
x1

0.19
29.7
33.3
63.0
0.47

lbmol/mol V1
lbmol
lbmol
lbmol
fraksi mol

4. Membuat operating line

V1 y1 + L x = V y + L1 x1
V' = V(1-y)
non difusing component
L' = L(1-x)
V' (y1/(1-y1)) + L' (x/(1-x)) = V'(y/(1-y)) + L'(x1/(1-x1))
V' =
125
L' =
33.33
31.25
33.33 *(x/(1-x)) =
125 *(y/(1-y))+
(x/(1-x)) =
3.75 *(y/(1-y))+
-0.04687
x
0
0.0307
0.1325
0.271
0.383
0.472

(x/(1-x))
0.0000
0.0317
0.1527
0.3717
0.6207
0.8939

(y/(1-y))
y
0.0125
0.0209
0.0532
0.1116
0.1780
0.2509

0.0123
0.0205
0.0505
0.1004
0.1511
0.2006

5. Membuat equilibrium line

Membuat pers EC (karena di soal dalam bentuk grafik)
y
y*
(y/(1-y))
(x/(1-x)) x
0.0124
0
0.0126
0.0002
0.03
0.003
0.0309
0.0691
0.05
0.0117
0.0526
0.1505
0.08
0.03
0.0870
0.2792
0.1
0.0475
0.1111
0.3698
0.14
0.0945
0.1628
0.5636
0.15
0.106
0.1765
0.6149
0.18
0.1445
0.2195
0.7763
0.2
0.173
0.2500
0.8906
6. Menghitung NOG

29.6875

0.0002
0.0646
0.1308
0.2183
0.2700
0.3604
0.3808
0.4370
0.4711

(menggunakan metoda penurunan)

y* dibaca dari kurva

y interval dari y2 ke y1
y
(y/(1-y))
0.0124
0.0126
0.03
0.0309
0.05
0.0526
0.08
0.0870
0.1
0.1111
0.14
0.1628
0.15
0.1765
0.18
0.2195
0.2
0.2500
Jadi NOG =

(1-y)lm =
(x/(1-x))
0.0002
0.0691
0.1505
0.2792
0.3698
0.5636
0.6149
0.7763
0.8906

x
0.0002
0.0646
0.1308
0.2183
0.2700
0.3604
0.3808
0.4370
0.4711

(1-y)-(1-y*)/ln((1-y)/(1-y*))
A
y*
1-y
0.0003
0.9876
0.0029
0.9700
0.0107
0.9500
0.0308
0.9200
0.0488
0.9000
0.0931
0.8600
0.1056
0.8500
0.1452
0.8200
0.1731
0.8000

5.3279 menggunakan trapeziodal rule

1-y*
0.9997
0.9971
0.9893
0.9692
0.9512
0.9069
0.8944
0.8548
0.8269

B
(1-y)lm
0.9936
0.9835
0.9695
0.9444
0.9254
0.8832
0.8720
0.8373
0.8134

C
y*-y
-0.0121
-0.0271
-0.0393
-0.0492
-0.0512
-0.0469
-0.0444
-0.0348
-0.0269

D
B/(A*C)
-83.2
-37.4
-26.0
-20.8
-20.1
-21.9
-23.1
-29.3
-37.7

Integrasi
1.0610
0.6336
0.7021
0.4092
0.8399
0.2251
0.7864
0.6706
5.3279

-D
83.2
37.4
26.0
20.8
20.1
21.9
23.1
29.3
37.7

Metoda Wiegand
1/(y-y*) Integrasi
82.65
1.0520
36.89
0.6232
25.43
0.6862
20.31
0.3983
19.52
0.8174
21.34
0.2193
22.51
0.7686
28.73
0.6583
37.11
5.2233

Bisa menggunakan metoda W