The document discusses the working principles of organic photovoltaic cells, including how they absorb photons to create excitons, use charge separation at the donor-acceptor interface, and transport charges through active materials like polymers and fullerenes. It also covers concepts like indirect and direct bandgaps, the Shockley-Queisser limit on efficiency, using a bulk hetero-junction design to separate charges, and how an internal electrical field is generated at the donor-acceptor interface.
The document discusses the working principles of organic photovoltaic cells, including how they absorb photons to create excitons, use charge separation at the donor-acceptor interface, and transport charges through active materials like polymers and fullerenes. It also covers concepts like indirect and direct bandgaps, the Shockley-Queisser limit on efficiency, using a bulk hetero-junction design to separate charges, and how an internal electrical field is generated at the donor-acceptor interface.
The document discusses the working principles of organic photovoltaic cells, including how they absorb photons to create excitons, use charge separation at the donor-acceptor interface, and transport charges through active materials like polymers and fullerenes. It also covers concepts like indirect and direct bandgaps, the Shockley-Queisser limit on efficiency, using a bulk hetero-junction design to separate charges, and how an internal electrical field is generated at the donor-acceptor interface.
Mikkel Jrgensen Active material Donor material (polymer) Acceptor (fullerene) Working principles Absorption of photon Creation of exciton Exiton diffusion Charge separation Charge transport Active material Donor material (polymer) Acceptor (fullerene) Indirect band gap material Silicon Direct bandgap material Thin film inorganic Thin film organic Low band gap material Limits voltage Efficiency limit ShockleyQueisser limit Silicon 33%
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Infinite junctions: 86%
Exciton Electron-hole pair Limited lifetime 10-20 nm Bulk hetero junction Microphase separated material Bulk hetero junction Microphase separated material Bi-layer geometry Less effective Internal electrical field Two different materials Organic Solar Cells - Theory and Practice Producers: Instructors: Eva Bundgaard Morten V. Madsen Eva Bundgaard Mikkel Jrgensen Frederik C. Krebs