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Week 2 Lecture 1

OPV working principles


Mikkel Jrgensen
Active material
Donor material (polymer)
Acceptor (fullerene)
Working principles
Absorption of photon
Creation of exciton
Exiton diffusion
Charge separation
Charge transport
Active material
Donor material (polymer)
Acceptor (fullerene)
Indirect band gap material
Silicon
Direct bandgap material
Thin film inorganic
Thin film organic
Low band gap material
Limits voltage
Efficiency limit
ShockleyQueisser limit
Silicon 33%

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Infinite junctions: 86%


Exciton
Electron-hole pair
Limited lifetime
10-20 nm
Bulk hetero junction
Microphase separated material
Bulk hetero junction
Microphase separated material
Bi-layer geometry
Less effective
Internal electrical field
Two different materials
Organic Solar Cells
- Theory and Practice
Producers:
Instructors:
Eva Bundgaard
Morten V. Madsen
Eva Bundgaard
Mikkel Jrgensen
Frederik C. Krebs

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