Datos Y Resultados Experimentales: E Log Pka+Ph

DATOS Y RESULTADOS EXPERIMENTALES
V (mL)
V total NaOH
(mL)
pH
dV
dE
d2E
Vp
dVp
dE/dV
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
0.00
1.00
1.20
0.80
1.00
1.00
1.00
1.00
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.20
1.80
2.00
0.00
1.00
2.20
3.00
4.00
5.00
6.00
7.00
7.50
8.00
8.50
9.00
9.50
10.00
10.50
11.00
12.00
13.00
14.00
15.00
16.00
17.00
18.00
19.00
20.00
21.00
22.00
23.00
25.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
40.00
42.00
44.00
46.20
48.00
50.00
11.69
11.28
10.99
10.84
10.66
10.47
10.29
10.09
10.02
9.90
9.77
9.60
9.40
9.10
8.53
7.88
7.33
7.04
6.83
6.74
6.56
6.48
6.25
5.97
5.43
2.94
2.42
2.18
1.95
1.88
1.74
1.67
1.59
1.54
1.50
1.47
1.42
1.40
1.37
1.34
1.34
1.33
16.43
16.02
15.73
15.58
15.40
15.21
15.03
14.83
14.76
14.64
14.51
14.34
14.14
13.84
13.27
12.62
12.07
11.78
11.57
11.48
11.30
11.22
10.99
10.71
10.17
7.68
7.16
6.92
6.69
6.62
6.48
6.41
6.33
6.28
6.24
6.21
6.16
6.14
6.11
6.08
6.08
6.07
1.00
1.20
0.80
1.00
1.00
1.00
1.00
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.20
1.80
-0.41
-0.29
-0.15
-0.18
-0.19
-0.18
-0.20
-0.07
-0.12
-0.13
-0.17
-0.20
-0.30
-0.57
-0.65
-0.55
-0.29
-0.21
-0.09
-0.18
-0.08
-0.23
-0.28
-0.54
-2.49
-0.52
-0.24
-0.23
-0.07
-0.14
-0.07
-0.08
-0.05
-0.04
-0.03
-0.05
-0.02
-0.03
-0.03
0.00
-0.01
0.12
0.14
-0.03
-0.01
0.01
-0.02
0.13
-0.05
-0.01
-0.04
-0.03
-0.10
-0.27
-0.08
0.10
0.26
0.08
0.12
-0.09
0.10
-0.15
-0.05
-0.26
-1.95
1.97
0.28
0.01
0.16
-0.07
0.07
-0.01
0.03
0.01
0.01
-0.02
0.03
-0.01
0.00
0.03
-0.01
0.50
1.60
2.60
3.50
4.50
5.50
6.50
7.25
7.75
8.25
8.75
9.25
9.75
10.25
10.75
11.50
12.50
13.50
14.50
15.50
16.50
17.50
18.50
19.50
20.50
21.50
22.50
24.00
25.50
27.00
29.00
29.00
31.00
33.00
35.00
37.00
39.00
41.00
43.00
45.10
47.10
1.10
1.00
0.90
1.00
1.00
1.00
0.75
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.75
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.50
1.50
1.50
2.00
0.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.10
2.00
-0.24
-0.19
-0.18
-0.19
-0.18
-0.20
-0.14
-0.24
-0.26
-0.34
-0.40
-0.60
-1.14
-1.30
-0.55
-0.29
-0.21
-0.09
-0.18
-0.08
-0.23
-0.28
-0.54
-2.49
-0.52
-0.24
-0.12
-0.07
-0.14
-0.04
-0.04
-0.02
-0.02
-0.02
-0.02
-0.01
-0.02
-0.02
0.00
-0.01
Ka
1.8 x 10^(-5) =
0.000018
E = log
pKa
=pKa+pH
4.74473
E = log
=pKa+pH
18.00
16.00
14.00
12.00
10.00
E
8.00
6.00
4.00
2.00
0.00
0.00
10.00
20.00
30.00
40.00
50.00
40.00
50.00
Volumen de la base total (mL)
14.00
12.00
10.00
8.00
pH
6.00
4.00
2.00
0.00
0.00
10.00
20.00
30.00
d2E/dVp2
Grfica de log [A-]/[HA] en funcin del pH

18.00
16.00
14.00
log [A-]/[HA]
0.11
0.14
-0.03
-0.01
0.01
-0.02
0.17
-0.10
-0.02
-0.08
-0.06
-0.20
-0.54
-0.16
0.13
0.26
0.08
0.12
-0.09
0.10
-0.15
-0.05
-0.26
-1.95
1.97
0.28
0.01
0.11
-0.05
0.03
#DIV/0!
0.02
0.00
0.00
-0.01
0.02
-0.01
0.00
0.01
0.00
12.00
10.00
8.00
6.00
4.00
y = x + 4.7447
R = 1
2.00
0.00
0.00
2.00
4.00
6.00
8.00
pH
10.00
12.00
0.00
0.00
5.00
10.00
15.00
20.00
25.00
30.00
35.00
40.00
35.00
40.00
-0.50
dE/dV
-1.00
-1.50
-2.00
-2.50
60.00
-3.00
Volumen promedio de la base
2.50
2.00
1.50
d2E/dVp2
1.00
0.50
0.00
0.00
5.00
10.00
15.00
20.00
25.00
30.00
-0.50
-1.00
-1.50
-2.00
60.00
-2.50
12.00
14.00
40.00
45.00
50.00
40.00
45.00
50.00
Hallando la constante de ionizacin
V total
NaOH (mL)
pH
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
0.00
0.50
1.00
1.50
2.00
2.50
3.00
3.50
4.00
4.50
5.00
5.50
6.00
6.50
7.00
7.50
8.00
8.50
9.00
3.22
3.57
3.76
3.91
4.08
4.18
4.32
4.46
4.53
4.64
4.75
4.89
4.96
5.08
5.20
5.38
5.59
5.93
6.69
V eq.
0.054348
0.108696
0.163043
0.217391
0.271739
0.326087
0.380435
0.434783
0.489130
0.543478
0.597826
0.652174
0.706522
0.760870
0.815217
0.869565
0.923913
0.978261
-1.240549
-0.913814
-0.710399
-0.556303
-0.428135
-0.315270
-0.211807
-0.113943
-0.018885
0.075721
0.172161
0.273001
0.381550
0.502675
0.644612
0.823909
1.084321
1.653213
9.2 mL
2.000000
1.500000
= 4.35
log (x/(1-x))
1.000000
0.500000
0.000000
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
-0.500000
-1.000000
-1.500000
pH
Determinar la constante de ionizacin y la concentracin del acido actico en mg/100mL de la solucin original
De la grfica se obtiene:
= 4.35 = 4.35 = 4.46684105
8.00
Valoracin normal
V total
NaOH (mL)
pH
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
0.00
1.00
2.20
3.00
4.00
5.00
6.00
7.00
7.50
8.00
8.50
9.00
9.50
10.00
10.50
11.00
12.00
13.00
14.00
15.00
16.00
17.00
18.00
19.00
20.00
21.00
22.00
23.00
25.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
40.00
42.00
44.00
46.20
48.00
50.00
11.69
11.28
10.99
10.84
10.66
10.47
10.29
10.09
10.02
9.90
9.77
9.60
9.40
9.10
8.53
7.88
7.33
7.04
6.83
6.74
6.56
6.48
6.25
5.97
5.43
2.94
2.42
2.18
1.95
1.88
1.74
1.67
1.59
1.54
1.50
1.47
1.42
1.40
1.37
1.34
1.34
1.33
Primera Derivada
Segunda Derivada
Vol. Prom.
(mL)
Volumen
(mL)
2
2
0.5
1.6
2.6
3.5
4.5
5.5
6.5
7.25
7.75
8.25
8.75
9.25
9.75
10.25
10.75
11.5
12.5
13.5
14.5
15.5
16.5
17.5
18.5
19.5
20.5
21.5
22.5
24
25.5
27
29
31
33
35
37
39
41
43
45.1
47.1
49
-0.41
-0.24166667
-0.1875
-0.18
-0.19
-0.18
-0.2
-0.14
-0.24
-0.26
-0.34
-0.4
-0.6
-1.14
-1.3
-0.55
-0.29
-0.21
-0.09
-0.18
-0.08
-0.23
-0.28
-0.54
-2.49
-0.52
-0.24
-0.115
-0.07
-0.07
-0.035
-0.04
-0.025
-0.02
-0.015
-0.025
-0.01
-0.015
-0.01363636
0
-0.005
1.05
2.1
3.05
4
5
6
6.875
7.5
8
8.5
9
9.5
10
10.5
11.125
12
13
14
15
16
17
18
19
20
21
22
23.25
24.75
26.25
28
30
32
34
36
38
40
42
44.05
46.1
48.05
0.1530303
0.05416667
0.00833333
-0.01
0.01
-0.02
0.08
-0.2
-0.04
-0.16
-0.12
-0.4
-1.08
-0.32
1
0.26
0.08
0.12
-0.09
0.1
-0.15
-0.05
-0.26
-1.95
1.97
0.28
0.08333333
0.03
7.4015E-17
0.0175
-0.0025
0.0075
0.0025
0.0025
-0.005
0.0075
-0.0025
0.00064935
0.00681818
-0.00263158
Curva de valoracin normal

14.00
12.00
10.00
8.00
pH
6.00
4.00
2.00
0.00
0.00
10.00
20.00
30.00
40.00
Volumen de agente valorante (mL)
Curva de valoracin de primera derivada

0
0
10
20
30
-0.5
-1
-1.5
-2
-2.5
-3
V (mL)
40
50.00
Curva de valoracin de segunda derivada

2.5
2
1.5
(^2 )/(^2 )
0.5
0
-0.5
10
20
30
-1
-1.5
-2
50.00
60.00
-2.5
50
60
V (mL)
in de segunda derivada
40
50
60

Datos Y Resultados Experimentales: E Log Pka+Ph

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Datos Y Resultados Experimentales: E Log Pka+Ph

Uploaded by

Copyright:

Available Formats

DATOS Y RESULTADOS EXPERIMENTALES

Volumen de la base total (mL)

Volumen de la base total (mL)

Volumen de la base total (mL)

Grfica de log [A-]/[HA] en funcin del pH

Volumen promedio de la base

Volumen promedio de la base

Volumen promedio de la base

Hallando la constante de ionizacin

= 4.35 = 4.35 = 4.46684105

Curva de valoracin normal

Volumen de agente valorante (mL)

Curva de valoracin de primera derivada

Curva de valoracin de segunda derivada

You might also like