Professional Documents
Culture Documents
Introduction, Rank Grade, Type of Coal
Introduction, Rank Grade, Type of Coal
Introduction
Coal's Past,
Although coal has always been an important and
plentiful fuel source, many people may not realize
just
how long it has been used? or
how much it is used today?.
A look at past and present uses of coal can tell,
what the future of coal might be.
The Past
Coal has been used for nearly as long as mankind
has thrived. In fact, coal was used to provide heat
in caveman times!
Coal's Past,
In the 1300s in what is now the United States,
Native Americans used coal for cooking, making
clay pots, and heating. By the mid-1700s, the first
U.S. coal mining operations opened in Virginia.
Wood charcoal had long been used to provide fuel
in England, but in the 18th century it was
discovered that coal burned cleaner and hotter.
Soon after, coal use skyrocketed during the
Industrial Revolution, when demands for energy
sources increased.
Coal's Past,
In 19th-century, America, Coal was used to fuel
the boilers on steam-powered trains, which
became a popular mode of transportation. At the
same time, coal was being used in the production
of weapons during the American Civil War, and
coke (a coal residue) took charcoal's place as the
primary fuel for making steel.
About one hundred years ago in the United States,
coal's abundance led to its widespread use for
heating homes, generating electricity, providing
cooking heat, powering railroads and boats, and
fueling factories.
Coal's Present,
Coal's Present,
Coal's Present,
Coal's Future
Coal's Future
Coal will likely continue to be an important source
of electricity generation because it is more
abundant and cost-effective than oil and natural
gas. Compare these energy costs per million
British thermal units (Btus):
Coal$1.20
Oil$4.45
Natural gas$4.30
Although coal is widely used for electricity
generation in the United States and in countries
throughout Europe, there will likely be a significant
increase in the use of coal for electricity generation
in countries such as China and India.
Coal's Future
In addition to these new and increased uses of
coal, new technologies will continue to enhance
our ability to identify the shape and composition of
untapped coal reserves. Core samples and
information about the layers of overburden (the
topsoil, subsoil, and other layers of earth and rock
covering the coal bed) can be analyzed before the
expensive process of coal removal begins. New
technologies will also continue to improve the
effects of the production and use of coal on the
environment.
Origin of Coal
Hydrogen
%
Oxygen
%
Nitrogen
%
Calorific value
(Kilo Joule/kg)
Range between
Wood
50.0
6.0
43.0
1.0
14,400
17,400
Peat
57.0
6.0
35.5
1.7
13,800
20,000
Lignite
65.0
5.2
28.3
1.5
23,000
29,000
Bituminous
coal
84.0
5.2
9.3
1.5
29,000
35,000
Anthrocite
93.5
2.8
2.8
0.9
35,000
35,400
in situ theory
Considered that old forests or marshes due
to disturbances on the surface of the earth
were buried at the place of their growth
under a cover of sediments.
In course of time due to overburden
pressure and temperature it was
transformed into coal.
Upright fossil tree trunks or fossil roots
found in coal seams suggest growth in the
original position of the forest and support
this theory.
drift theory
Vegetable matters are shifted from the
place of their origin by running water or
glacier and accumulate in deep lake,
estuary, river valleys and afterwards are
covered with sediments like sands or
clays.
Seat earths are often absent in the coal
seams produced by drifting of plant
material and seams lie directly on
sandstone, conglomerate or shale; upright
tree trunks are absent.
Biochemical stage:
During the initial stage of biochemical phase the
decomposition and degradation of plant material
take place due to atmospheric oxidation by fungi
and also by aerobic bacteria.
In nature, the accumulated plant material
subsides under its own weight. At this stage
anaerobic conditions prevail and anaerobic
bacteria take part in decomposing and
degrading the plant material at a slower rate.
The accumulated vegetable matters are covered
by clay or sands brought mainly by the running
water.
peat
lignite
bituminous coal
anthracite
Coalification
Mechanistic theories
Workers have contributed to explain the chemical change during
coalification.
Regnault (1905) based on analysis of mine gases postulated the
following mechanism:
(C6H10O5)4 C9H6O + 7 CH4 + 8 CO2 + 3 H2O
Cellulose
Bituminous coal
Parr (1906), explained the mechanism of conversion to lignite and
bituminous coal by the following equation
(C6H10O5)5 C20H22O4 + 3 CH4 + 6 CO2 + CO + 8 H2O
Cellulose
(C6H10O5)5 C22H20O4 + 5 CH4 + 8 CO2 + CO + 10 H2O
Cellulose
Since bituminous coal is a further stage of the metamorphosis of lignocellulose, Parr (1909) proposed further the mechanism of formation
of bituminous coal from ligno-cellulose as follow:
3 C12H18O9 C22H20O3 + 5 CH4 + 8 CO2 + CO + 7 H2O
Bituminous coal
Cellulose
Lignin
1 Effect of Heating
2 Solubility in
Insoluble
Soluble
3 Texture
Fibrous
4 Chemical
(C6H10O5)n
Six Carbon atom straight
chain structure with four
OH groups
(C6H10O5)n
Six Carbon atom phenolic
ring structure with methoxy
group and glycerol side
chain.
alkalies
structure
Classification of Coal
a) Rank
The classification system used in North America
and that is fairly universal is maintained by the
American Society for Testing and Materials
(ASTM) and designated D388.
This approach uses standard methods of
measuring and reporting the calorific value on a
moist, mineral-matter-free basis and volatile
matter and fixed carbon on a dry, mineralmatter-free basis to classify coal rank.
Implicit in this characterization is the fact that the
amount of moisture, yield of ash and total sulfur
must be measured to obtain the correct basis of
comparison.
Table 3 - Some of the Parameters Used by ASTM for the Classification of Coals by Rank
b) Type
As discussed previously, coal is composed
of the sum of all the organic vegetable
matter preserved and buried as peat.
Changes in the chemical and physical
properties of whole coal are the
summation of changes to the coal
constituents.
There are three main groups of materials
that constitute coals and that are used to
define coal type.
c) Grade
Coal grade is a term used to indicate the
value of coal material as determined by
the amount and nature of ash yield and
the sulfur content following the complete
oxidation of the organic fraction.
Calorific value is one of the principal
measures of a coal's value as a fuel and is
directly influenced by mineral impurities.
d) Industrial Properties
Most of the ancillary mechanical and
physical tests used to characterize coals
and often included in classification
schemes, were developed in support of
efforts to identify coals for coke making.
As stated earlier, the unique property that
sets coking coals apart from other coals, is
caking ability.
Ash Ranges
Steel Grade I
Steel Grade II
Washery Grade I
Washery Grade II
Washery Grade IV
Grade
Exceeding 6200.
Exceeding 6200.
TYPES OF COAL