12/8/2014

Chapter14ExtraCredit

Chapter14ExtraCredit
Due:11:59pmonMonday,December8,2014
Youwillreceivenocreditforitemsyoucompleteaftertheassignmentisdue.GradingPolicy

SelfAssessment14.12
ThereactionX2 (g) 2X(g) occursinaclosedreactionvesselatconstantvolumeandtemperature.Initially,the
vesselcontainsonlyX2 atapressureof1.70atm.Afterthereactionreachesequilibrium,thetotalpressureis2.65
atm.

PartA
Whatisthevalueoftheequilibriumconstant,Kp ,forthereaction?
Expressyouranswerusingtwosignificantfigures.
ANSWER:
Kp

= 4.8

Correct

SelfAssessment14.11

PartA
Whatistheeffectofaddingheliumgas(atconstantvolume)toanequilibriummixtureofthereaction:
CO(g) + Cl 2 (g) COCl2 (g)

ANSWER:
Thereactiondoesnotshiftineitherdirection.
Thereactionshiftstowardtheproducts.
Thereactionslowsdown.
Thereactionshiftstowardthereactants.

Correct

SelfAssessment14.10
ThesolidXY decomposesintogaseousXandY:

XY(s) X(g) + Y(g)

Kp =4.1(at0 C ).

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Chapter14ExtraCredit

PartA
Ifthereactioniscarriedoutina22.4Lcontainer,whichinitialamountsofXandYwillresultintheformationof
solidXY ?
ANSWER:
1mol X1mol

5mol X0.5mol
2.0mol

2.0mol

noneoftheabove

Correct

SelfAssessment14.9
ThedecompositionofNH 4 HS isendothermic:
NH 4 HS(s) NH 3 (g) + H 2 S(g)

PartA
WhichchangetoanequilibriummixtureofthisreactionresultsintheformationofmoreH2 S?
ANSWER:
anincreaseintheamountofNH 4 HS inthereactionvessel
adecreaseinthevolumeofthereactionvessel(atconstanttemperature)
anincreaseintemperature
alloftheabove

Correct

SelfAssessment14.8
ConsiderthereactionofAtoformB :
5(at298 K )
2A(g) B(g)
Kc =1.710
Areactionmixtureat298K initiallycontains[A] =0.60M .

PartA
WhatistheconcentrationofB whenthereactionreachesequilibrium?
Expressyouranswertotwosignificantfiguresandincludetheappropriateunits.
ANSWER:
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Chapter14ExtraCredit
[B]

= 6.1106M

Correct

SelfAssessment14.7
Considerthereactionbetweeniodinegasandchlorinegastoformiodinemonochloride:
I 2 (g) + Cl 2 (g) 2ICl(g)
Kp =81.9(at298 K )
Areactionmixtureat298K initiallycontainsPI =0.30atmandPCl =0.30atm.
2

PartA
Whatisthepartialpressureofiodinemonochloridewhenthereactionreachesequilibrium?
Expressyouranswertotwosignificantfiguresandincludetheappropriateunits.
ANSWER:
P ICl

= 0.49atm

Correct

SelfAssessment14.6
Forthereaction2A(g) B(g) ,theequilibriumconstantisKp =0.76.Areactionmixtureinitiallycontains2.0atmof
eachgas(PA =2.0atmandPB =2.0atm).

PartA
Whichstatementistrueofthereactionmixture?
ANSWER:
Thereactionmixturewillproceedtowardproducts.
Thereactionmixturewillproceedtowardreactants.
Thereactionmixtureisatequilibrium.
Itisnotpossibletodeterminefromtheinformationgiventhefuturedirectionofthereactionmixture.

Correct

SelfAssessment14.5
NO
Cl 2
NOCl
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Chapter14ExtraCredit

ConsiderthereactionbetweenNOandCl 2 toformNOCl :
2NO(g) + Cl 2 (g) 2NOCl(g)
Areactionmixtureatacertaintemperatureinitiallycontainsonly[NO]
comestoequilibrium,theconcentrationofNOCl is0.22M .

0.50M and[Cl 2 ]

0.67.Afterthereaction

PartA
Findthevalueoftheequilibriumconstant(Kc )atthistemperature.
Expressyouranswerusingtwosignificantfigures.
ANSWER:
Kc

= 1.1

Correct

SelfAssessment14.1

PartA
Whatisthecorrectexpressionfortheequilibriumconstant(Kc )forthereactionbetweencarbonandhydrogengas
toformmethaneshownhere?
C(s) + 2H 2 (g) CH4 (g)

ANSWER:

Kc =

[CH 4 ]
[C][H2 ]

Kc =

[CH 4 ]
[H2 ]

Kc =

Kc =

[CH 4 ]
[H ]
2
[CH 4 ]
[C][H ]
2

Correct

SelfAssessment14.2
TheequilibriumconstantforthereactionshownhereisKc =7.0102.Areactionmixtureatequilibriumcontains
3M .
[A] =2.310
A(g) B(g)

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PartA
WhatistheconcentrationofB inthemixture?
Expressyouranswerusingtwosignificantfigures.
ANSWER:
[B]

= 1.6 M

Correct

SelfAssessment14.3

PartA
Usethedatabelowtofindtheequilibriumconstant(Kc )forthereactionA(g)
A(g) 2X(g) + C(g)
B(g) X(g)

Kc =

Kc =

2B(g) + C(g)

2.14

21.1

Expressyouranswerusingthreesignificantfigures.
ANSWER:
(Kc )

= 4.81103

Correct

SelfAssessment14.4
ThereactionshownherehasaKp

4.1102at900K .

CH4 (g) + CO 2 (g) 2CO(g) + 2H 2 (g)

PartA
FindKc forthereactionatthistemperature.
Expressyouranswerusingtwosignificantfigures.
ANSWER:
Kc

= 7.5102

Correct
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Chapter14ExtraCredit

ScoreSummary:
Yourscoreonthisassignmentis100%.
Youreceived12outofapossibletotalof12points.

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