28 Ans

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ALL INDIA INTEGRATED TEST SERIES
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AIITS-PT-III-(Paper-1)-PCM(S)-JEE(Advanced)/15
JEE(Advanced)-2015
ANSWERS, HINTS & SOLUTIONS
PART TEST III
(Paper-1)
Q. No.
PHYSICS
B
CHEMISTRY
C
MATHEMATICS
A
A, B
C, D
A, B, C, D
A, D
B, C
A, B, C
A, C, D
A, D
A, C, D
B, D
A, B, D
B, C, D
A, D
A, C
A, D
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
1.
2.
3.
4.
5.
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AIITS-PT-III-(Ppaer-1)-PCM(S)-IITJEE(Advance)/15
Physics
PART I
2.
Potential energy will be finite and maximum at x = 0.
5.
B1 B2 = 20 T, B1 + B2 = 50 T and B i
6.

Use M B
7.
Use symmetry arguments. Net B will be perpendicular to the plane of the loop
9.
Use P = qi ri
Chemistry
PART II
SECTION A
1.
In alkaline medium, alanine exists as anion:

OH
H3C CH NH2
H3C CH NH2
COOH
COO
CH3 O
2.
H3C
CH3
O
C
H(not appropriate for Cannizzaro reaciton)
O
H3C
C
O
3.
NH2
NCl
NaNO2 HCl
05 C
4.
NH2
COOH
CuCN
H2 O/H
Hoffmann bronamide degradation.
5.
CN
Cl
NaCN
DMF
SN 2 reaction
polar approtic solvent
6.
CN
NaBH4 selectively reduceds

O
C
7.
Gattermann Koch reaction.
8.
MnO2 oxidized allylic alcohol.
9.
OCH 3
OCH 3
COOCH 3
H O
CH OH
3
OH
O
H O
OH
COOCH 3
COOH
O
10.
COOH
OH
BrO
NH
CONH 2
NH 2
11.
H3C
CH
CHO
H3C
(A)
H /H2 O
H3C
CH
CH
H2 O
H3C
CH COOH
CH
CH3
CH3 CN
CH3
12.
OH
OH
HCN
CH COOH
CH3
CH3
H3C
CH
E2
CH3
9 H
(B)
CH3
H3C
CH
CH2 CH3 E2
8 H
(C)
CH
3 H
C
(D)
C
E2
CH CH3
OH
C
C
CH3 shift
H3C
OH
C
C
C
CH3
ether and NOT an alkalene

13.
O
H3C
sp2
hybridised
planar
H
CH2 CH3 C
CN
above & below
the plane
OH
C
OH
C
LiAH4
C
C
CN
CH2 NH2
A
B
R as well as S racemic mixture racemic mixture
LiAH4
14.
Organic compound is
O
H3C
NH
o and p directing
meta directing
SECTION C
1.
NH2 si basic.
COO is (conjugate) base.
+
NH3 is acidic.
2.
OH
H
O
2
aldol
3'
1'
4
O
4'
5'
4'
3.
3'
O 2'
2'
1'
5'
OH
The compound A is represented by the 3 structures as follows:

OH
H3C
CH2 CH
CH3
dehydration
CH3
C
H3C
CH3
C
H3C
H3C
CH2 CH
CH2
trans
cis
Br2 / CCl4
Br2 / CCl4
Br2 / CCl4
meso
d and forms
d and forms
racemic
racemic
5 products
4.
O
H3C
O
H3C
CH2
NaOH/I2
O
H3C
CH2
O
H3C
CH2
2 more times
CI3
OH
I
I
O
CH3 COO CHI3 CI3
H3C
OH
1 molecules of H3C
5.
CH3 requires 3 molecules of I .

2
O
CH2CH2 CH2Cl
CH3 MgI
OH
Mathematics
PART III
SECTION A
1.
(a, 0) lies on the given curve

o sin 2a 3 sina
sin a = 0 or cosa
a
(as a > 0 and 1st point of intersection with positive x-axis) and
6
/6
3
2
sin 2x
3 sin x dx =
7
7
3 2cosa 4A + 8 cos a = 7
4
4
2.
Let g(x) = (sin x)ln x = e ln x ln(sin x)

ln sin x
ln x
f x g' x sin x cot x ln x
Hence, f g' 0
2

2
3.
Put 2x7m + 7x2m + 14xm = tm

14 m(x7m 1 + x2m 1 + xm 1) dx = mtm 1 dt
4.
u(x) = 7v(x) p = 7
'
u x

0 q=0
v x
pq
1
pq
5.
6.
7.
dx
3 2t
4
dt
t
dy
3 2t
3
dt
t
f[g(x)] = x f[g(2)] g(2) = 12 f(a) g(2) [putting x = 2]
a10
1 a2
Given f ' a
g' 2 10
2
1 a
a
1
integrating
1 cos x
x
f x tan c
2
f(0) = 3 c = 3
x
f x tan 3
2
f 4
2
f 'x
8.
2y = 3x 1 y ln 2 = ln (3x 1)
dy 3x ln3
ln3
ln2
dx 3x 1 1 3 x
dy ln3
1
lim
lim
log2 3
x dx
ln2 x 1 3 x
9.
I sin100x x sin x dx =
99
dx
II
100
99
sin 100x cos x cos100x sin x sin x

99
100
100x cos x sin x dx cos 100x sin x dx
sin

sin 100x sin x
100
100
100
100
cos 100x sin x dx cos 100x sin x dx
100
100
=
10.
sin 100x sin x
Using Lopital Rule

a tan1 x / a b tan1 x / b
lim
x 0
x x
a
1 1
b
1 1

2
2
a 2 x
b 2 x
1 x / a
1 x / b
= lim
x 0
3
x
2
2
2
a2
b2
1 = a b
= lim 2
2
x 0 a x x
3a2b2
b x x 3
13.
14.
100
1
3
if x 0
x sin
f x
x
0
if x 0
2x x2 = xn
x = 0 and 1
1
A
0
x 3 x n 1
2
1
2x x x dx x
=
3 n 1
3 n1
2
2
1
1
Hence,
3 n 1 2
n=5
Hence, n is devisor of (20, 15, 30)
15.
0x
cos x
2
Given f x
and f is periodic with period
2
x
x
2
2
We draw the graph of y = f(x)
3
2
5
2
2
From the graph the range of the function is 0,
4
n
It is discontinuous at x = n, n I at x
,nI
2
Area bounded by y = f(x) and the x-axis from n to n for n N
2
/2
= 2n f x dx 2n cos x dx x dx = 2n 1
24
2
0
/2
SECTION C
/4
1.
We have In In 2
/4
tann xdx
/4
n 2
tan
tann x 1 tan2 x dx un du
So, In In 2
xdx
1
(where u = tan x)
n1
1
1
which implies that In1 In3

1 n
n2
Hence,
In In 1 In In 3 In1 In 2 In 2 In 3
n0
In In 2 In1 In 3
n0
1 1
n 1 n 2 n 1 n 2
n0
n0
1
1
Sn 1
lim 1
1
x
n2
n 2
2.
x 2 sin2 x
sin x
sin1
cos1
x2
x
L : lim
= lim
x 0
x
0
x
x
sin1 M
M
= lim
lim
(Using cos1 t sin1 1 t 2 )
x 0
x 0 x
M
x 2 sin2 x
= 1 lim
x x
x0
= lim
x 0
1 lim
x sin x x sin x
x3
x0
1
1
1
2
L
6
3
3
x
U : f x
sin t
t cos x cos t 2 t sin x dt
or f x cos x sin t 2 t dt sin x cos t 2 t dt

0
f ' x cos x sin x 2 x sin t 2 t dt sin x cos t 2 t dt cos x cos x 2 x sin x
f " x sin x 2 x sin x cos x cos x 2 x 2x 1
sin t 2 t dt cos x sin x sin x x 2 x
cos x 2 x cos x sin x sin x2 x 2x 1
cos x cos x 2 x cos t 2 t dt sin x
f(0) = 1 U = 1
3.
1
2
/2
x 2 sin2 x 1dx =
Put 2x = t, dx
4.
1
2
/2
x cos2x dx
dt
2
Consider the numerator cos 4x cos 4

= (2 cos2 2x 1) (2 cos2 2 1)
= 2(cos2 2x cos2 2)
= 2(cos 2x + cos 2)(cos 2x cos 2)
= 4(cos 2x + cos 2)(cos x cos )(cos x + cos )
I 4 cos2x cos 2 cos x cos dx = 4 cos 2 cos dx (all other integral vanish)
0
4 cos cos 2

28 Ans

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FIITJEE

ALL INDIA INTEGRATED TEST SERIES

Potential energy will be finite and maximum at x = 0.

In alkaline medium, alanine exists as anion:

H(not appropriate for Cannizzaro reaciton)

Hoffmann bronamide degradation.

polar approtic solvent

NaBH4 selectively reduceds

Gattermann Koch reaction.

MnO2 oxidized allylic alcohol.

ether and NOT an alkalene

The compound A is represented by the 3 structures as follows:

CH3 requires 3 molecules of I .

(a, 0) lies on the given curve

Let g(x) = (sin x)ln x = e ln x ln(sin x)

Put 2x7m + 7x2m + 14xm = tm

sin 100x cos x cos100x sin x sin x

sin 100x sin x

Using Lopital Rule

which implies that In1 In3

t cos x cos t 2 t sin x dt

or f x cos x sin t 2 t dt sin x cos t 2 t dt

f ' x cos x sin x 2 x sin t 2 t dt sin x cos t 2 t dt cos x cos x 2 x sin x

f " x sin x 2 x sin x cos x cos x 2 x 2x 1

sin t 2 t dt cos x sin x sin x x 2 x

cos x 2 x cos x sin x sin x2 x 2x 1

cos x cos x 2 x cos t 2 t dt sin x

Consider the numerator cos 4x cos 4

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