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  • Set of Standard Solutions For Calibration Curve

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    The document contains data from standard solutions used to generate a calibration curve for determining the equilibrium constant (Kc) for the reaction of iron(III) and thiocyanate. Test solutions were prepared with varying concentrations of iron(III) and thiocyanate and their absorbances measured. The calibration curve was used to determine the equilibrium concentrations of the complex ion (FeNCS2+), which were then used to calculate Kc values for each test solution. The average Kc, standard deviation, and percent relative standard deviation were reported.

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    The document contains data from standard solutions used to generate a calibration curve for determining the equilibrium constant (Kc) for the reaction of iron(III) and thiocyanate. Test solutions were prepared with varying concentrations of iron(III) and thiocyanate and their absorbances measured. The calibration curve was used to determine the equilibrium concentrations of the complex ion (FeNCS2+), which were then used to calculate Kc values for each test solution. The average Kc, standard deviation, and percent relative standard deviation were reported.

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    6 views3 pages

    Set of Standard Solutions For Calibration Curve

    Uploaded by

    gatedsprint
    The document contains data from standard solutions used to generate a calibration curve for determining the equilibrium constant (Kc) for the reaction of iron(III) and thiocyanate. Test solutions were prepared with varying concentrations of iron(III) and thiocyanate and their absorbances measured. The calibration curve was used to determine the equilibrium concentrations of the complex ion (FeNCS2+), which were then used to calculate Kc values for each test solution. The average Kc, standard deviation, and percent relative standard deviation were reported.

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    of 3

    SET OF STANDARD SOLUTIONS FOR CALIBRATION CURVE

    Molar concentration of Fe(NO3)3


    STANDARD SOULTIONS

    Molar concentration of NaSCN

    0.2

    0.001

    BLANK

    1*

    A.1

    Volume of NaSCN (mL)

    A.2

    Moles of SCN-

    1.00E-06

    2.00E-06

    3.00E-06

    4.00E-06

    5.00E-06

    A.3

    [SCN-] (25.0 mL)

    4.00E-05

    8.00E-05

    1.20E-04

    1.60E-04

    2.00E-04

    A.4

    [FeNCS2+] (mol/L)

    4.00E-05

    8.00E-05

    1.20E-04

    1.60E-04

    2.00E-04

    A.5

    ABSORBANCE

    0.285

    0.472

    0.706

    1.09

    1.14

    * Show all calculations for standard #1 in space below

    0.9

    CALIBRATION CURVE
    f(x) = 0.2385428571x - 0.2194

    0.8

    0.7

    0.6

    0.5
    ABSORBANCE
    0.4

    0.3

    0.2

    0.1

    0
    0

    0.00004

    0.00008

    0.00012

    0.00016

    Concentration of FeNCS2+ (mol/L)

    0.0002

    PART B - ABSORBANCE FOR TEST SOLUTIONS


    Molar concentration of Fe(NO3)3 (read bottle)

    0.002

    TEST SOULTIONS

    10

    5.00

    5.00

    5.00

    5.00

    5.00

    1.00E-05

    1.00E-05

    1.00E-05

    1.00E-05

    1.00E-05

    1.00

    2.00

    3.00

    4.00

    5.00

    2.00E-06

    4.00E-06

    6.00E-06

    8.00E-06

    1.00E-05

    3.16E-01

    3.22E-01

    4.80E-01

    7.08E-01

    8.35E-01

    B.1 Volume of Fe(NO3)3 (mL)


    B.2 Moles of Fe+3 Initial (mol)
    B.3

    Volume of NaSCN (mL)

    B.4

    Moles of SCN- ( Initial) (mol)

    B.5 Absorbance(A)

    Molar concentration of NaSCN (read bottle)

    0.002

    * Show all calculations for Test Solution #6 in space below

    PART C - CALCULATION OF KC
    TEST SOULTIONS
    C.1
    C.2

    10

    [FeNCS+2], Equilibrium, from Calibration Curve

    2.224

    2.27

    2.93

    3.89

    4.42

    Moles of [FeNCS2+] at Equilibrium (10mL) (mol)

    2.22E-02

    2.27E-02

    2.93E-02

    3.89E-02

    4.42E-02

    [Fe ] at equilibrium
    3+

    3+
    C.3 Moles of Fe reacted (mol)

    2.22E-02

    2.27E-02

    2.93E-02

    3.89E-02

    4.42E-02

    3+
    C.4 Moles of Fe , equilibrium (mol)

    -2.22E-02

    -2.27E-02

    -2.93E-02

    -3.89E-02

    -4.42E-02

    -2.22E+00

    -2.27E+00

    -2.93E+00

    -3.89E+00

    -4.42E+00

    10

    C.5

    [Fe3+ ], equilibrium unreacted (10 mL) (mol/L)

    * Show all calculations for Test Solution #6 in space below

    [SCN-], EQUILIBRIUM
    TEST SOULTIONS
    C.6 Moles of SCN- reacted (mol)
    C.7 Moles of SCN-, equilibrium (mol)
    C.8 [SCN- ], equilibrium unreacted (10 mL) (mol/L)

    6*

    2.22E-02

    7
    2.27E-02

    2.93E-02

    3.89E-02

    4.42E-02

    -2.22E-02

    -2.27E-02

    -2.93E-02

    -3.89E-02

    -4.42E-02

    -2.22E+00

    -2.27E+00

    -2.93E+00

    -3.89E+00

    -4.42E+00

    4.41E-01

    3.41E-01

    2.57E-01

    2.26E-01

    * Show all calculations for Test Solution #6 in space below

    C.9 Kc =[C.1]/[C.5][C.8]

    4.50E-01

    * Show all calculations for Test Solution #6 in space below

    C.11

    AVERAGE Kc
    Standard Deviation of Kc

    C.12

    %RSD

    C.10

    0.3431404012
    0.0916108294
    26.6977683487

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