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Topic 8 Natural Materials and Manufactured or Man Made Materials PDF
Topic 8 Natural Materials and Manufactured or Man Made Materials PDF
Natural
Materials and
Manufactured
or Man-made
Materials
LEARNING OUTCOMES
Bytheendofthistopic,youshouldbeableto:
1. Definematerial;
2. Describeeachtypeofmaterials;
3. Explainthepropertiesofmaterials;
4. Statetheimportanceofmaterials;
5. Comparenaturalmaterialsandmanufacturedmaterials;
6. Describehowtopreserveournaturalmaterials;
7. Describecompositematerials;and
8. Discuss the materials in industry in the context of soap, natural and
syntheticrubber,naturalandsyntheticfibreandplastics.
275
X INTRODUCTION
Materialsarethethingsthatyoucanobserveallaroundyou.Fromfallingrain
to plants and human beings, from window curtains to floor mats and from
computers to printing materials, these are all materials. The air that you
breatheinandoutisalsoamaterial.
Materialsareveryusefultohumanbeingsfortheirsurvival.Theynotonlyuse
naturalmaterialsbutalsocreatenewmaterialsinordertofulfiltheirneeds.
8.1
Acloudisseenasabulkofmovingobjectintheair.Whenitisveryheavy,it
starts to drop tiny droplets of water. When the sun shines on the water
droplets,itturnstovapour.Haveyoueverthoughtoftheprocessesthatoccur
inthisevent?
Thiseventisjustoneinathousandofeventsthatinvolvematerials.Materials
arethethingsallaroundyou.Materialshavemassandoccupyspace.Gases,
woods,plastics,foods,animalsandwaterareallexamplesofmaterials.
276
Element
An element is the simplest substance of a material. It cannot be broken
down or separated by chemical or physical methods into any simpler
components. An element is made up of only one type of atom. Some
elements have atoms of the same types, which are combined to form
molecules.Thereare112typesofelements,inwhich92oftheseelements
occurnaturallyintheearthand20arecreatedbyscientists.
Elements can be grouped into metals and nonmetals. Gold, zinc, iron,
aluminium, oxygen, carbon, hydrogen and nitrogen are examples of
elements.
Figure 8.1 shows the atom of an element with its nucleus at the centre
andelectronsmovingaroundthenucleus.
Figure8.1:Theatomofanelement
277
(b) CombinedElements
Therearetwotypesofcombinedelementscompoundsandmixtures.
(i) Compound
Twoormoreelementscanbecombinedtogetherchemicallytoform
a new material called a compound. A molecule is the smallest
particle in a compound. Water is an example of a compound. A
water molecule is made up of one oxygen atom and two hydrogen
atoms,whicharecombinedchemically(seeFigure8.2).
Oxygen atom
Hydrogen
atoms
Figure8.2:Watermolecule
ACTIVITY 8.1
Lookoutsideyourlaboratory.Identifytheobjectsandlistdownthe
objects. They are made of different types of materials. Most of the
materialsaremadefromacombinationofelements.Somearemade
ofonlyonetypeofelement.Canyouguesswhichobjectsaremade
ofonlyoneelement?Canyounametheelementineachcase?Write
downyourfindings.
Table8.1showsseveraltypesofcompoundsanditselements.
278
Table8.1:SeveralTypesofCompounds
Compound
Elements
Carbon dioxide
Sodium chloride
Benzene
Ammonia
Water
ACTIVITY 8.2
ACTIVITY 8.2
Have you ever burnt a magnesium ribbon? Magnesium and
oxygencanbecombinedtomakeacompound.Holdasmallpiece
of magnesium ribbon by using a tong and move it slowly into a
flame.Observe theappearanceofmagnesium and oxygenbefore
andafteritwasburnt.Identifytheendproductoftheexperiment.
(ii) Mixtures
Materialthatismadeupofacombinationoftwoormoresubstances
thatarecombinedphysicallyiscalledamixture.Thismeansthatthe
mixture can be separated by physical methods such as filtration,
evaporation, distillation, chromatography, extraction, precipitation,
magnetic forces, sieving and heating or evaporation processes. By
theseseparationmethods,thechemicalstructureofthecomponentis
notchangedbecausethesubstanceinamixturedoesnotunite.
279
Therearetwotypesofmixturehomogenousandheterogeneous.A
homogenous mixture is formed when its substances are mixed
evenlyandtheidentityofeachsubstancecannotbeidentifiedeasily.
A heterogeneous mixture is formed when its substance can be
identified easily. When sugar is put in a glass of hot drink, it
becomes a homogenous mixture. A mixture of sulphur with iron
fillings and air are examples of a heterogeneous mixture (see Table
8.2).
Table8.2:SeveralTypesofMixtures
Mixture
Components
Air
Soil
Water,clay,loam,sand,humus,gravel
Seawater
Chocolate
cake
Flour,water,oil,egg,chocolatepowder
Blood
SELF-CHECK 8.1
1. Whatisamaterial?
2. Nameafewexamplesofmaterials.
280
ACTIVITY 8.3
Do you know how to separate gases in the air? What are the
proceduresthatshouldbetakentoturnitintoliquid?Discusswith
yourcoursemates.
Each material has its unique physical properties, which means different
materialshavedifferentproperties.Someoftheimportantphysicalproperties
of materials are elasticity, shine, buoyancy, water absorbency, electrical
conductivity, heat conductivity and magnetism. Other physical properties of
materials are hardness, toughness and brittleness, strength, flexibility,
solubilityandwaterproof.
281
Mechanicalpropertieslikeelasticity;
(b) Thermodynamicpropertieslikespecificheatcapacityandmeltingpoint;
(c)
(d) Chemicalpropertieslikethecapacityforoxidationorthesolubilityina
certainliquid;
(e) Biological or biochemical properties like LD50, antibiotic or anaesthetic
effect;
(f)
Letusnowtakealookatthetypesofmaterialproperties.
(a)
Elasticity
Whatiselasticity?
Elasticityistheabilityofamaterialtoreturntoitsoriginalshapeand
sizeafterbeingbent,twisted,stretchedandsqueezed.
Materials that are able to return to their old shape when force is no
longer applied are called elastic materials. However, materials which
retaintheirnewshapeswhenforceisnolongerappliedarecalledplastic
materialsornonelasticmaterials.Somematerialssuchasrubberbands,
balloons and gloves are elastic materials but some materials such as
plastic, wood and belt are nonelastic materials. To determine whether
materials are elastic or nonelastic, you may need to carry out some
activity.
282
Figure8.3:Effectofforceonmaterials
(i)
ElasticChange
When enough force is applied to an object, it deforms. However,
when the force is removed, the material will often return to its
originalshape.
(ii)
PlasticChange
Whenalargerforceisapplied,amaterialmaycontinuetodeform.
However,whentheforceisremoved,itwillstayinthisnewshape.
283
(iii) Break
If enough force is applied to a material, it will become brittle and
eventuallybreakorfracture.
Somematerialsthatexhibitelasticbehaviourare:
(i)
(ii)
Metals:Smalldeformation,thenpermanentlydeform;
(iii)
Ceramics:Smalldeformation,thenfracture;
(iv)
Electronicmaterials:Smalldeformation,thenfractureordeform;
(v)
Glass:Smalldeformation,thenfracture.
(vi)
Humanskin:Largedeformations.
(vii)
Polymers:Temperaturedependent.
(viii)
Liquidsunderuniformhydrostaticpressure.
SELF-CHECK 8.3
1. Statetheimportanceofphysicalpropertiesofmaterials.
2. Giveanexampleofamaterialforeachphysicalproperty.
(b) Shiny
Whenitcomestomaterialproperties,whatdoesshinymean?
Some materials are shiny and some are not. Shiny materials can
reflectthelightsuchassometypesofmetalsandglasses.
Shineisimportantinmakingjewelleryandaccessories.Inrelationtothis
shinypropertyofmaterials,somematerialsallowlighttopassthrough
thembutsomedonot.Materialssuchasglassandplasticallowlightto
pass through them. On the other hand, materials such as wood and
metaldonotallowlighttopassthroughthem.Accordingtotheability
of materials to allow light to pass through them, materials can also be
284
Figure8.4:Objectsmadeoftransparent,translucentandopaque
materials
Transparentmaterials
If the materials allow most of the light to pass through them, it is
known as transparent materials. Examples of this type are glass,
plain plastic, air, water, aquariums, some doors and walls of
buildings made from clear glass. We can clearly see objects behind
thesematerials.
Translucentmaterials
If the materials allow some of the light to pass through them, it is
known as translucent materials. Objects behind a translucent
material cannot be seen clearly. It will appear blurred. Examples of
these materials are tissue paper, wrapping plastic, some window
panes,bulbs,foodcontainersandsunglasses.
Opaquematerials
Opaquematerialsarematerialswhichcannotallowanylighttopass
through them. We cannot see anything behind opaque materials.
Metals, woods, rubber, bricks, roofs, walls, bags, hats and paper
boxesareexamplesofthesematerials.
285
(c)
Buoyancy
Buoyancyistheabilityofmaterialstofloatinliquid.
Why do some things float? Dense objects sink and light objects float.
Therefore, buoyancy is also related to density. Density is mass per unit of
volume.
Floatingisrelatedtothevolumeofliquiddisplacedbyanobject.Theliquidis
pushedasidewhenanobjectisplacedinit.Therefore,ourbodydisplacesthe
water.When an object floats in water, onlyapartofitdisplacesthewater.
Theotherpartoftheobjectremainsabovethewater.Theobjectsfloataftera
definiteamountofwaterisdisplaced.AccordingtoArchimedes,theancient
Greekphysicist,whenthemassofthedisplacedliquidisequaltothemassof
the objects, the objects will float. Plastic, wood and rubber are examples of
floatingmaterials.Figure8.5showsfloatingmaterialsandliquidsofdifferent
densities.
Figure8.5:Floatingmaterialsandliquidsofdifferentdensities
286
(d) WaterAbsorbency
Materialswhichcanabsorbwaterareknownasabsorbentmaterialsand
materials which cannot absorb water are known as nonabsorbent
materials.Thematerialsthatareabletoabsorbwaterbecomecompletely
wet.Examplesofabsorbentmaterialsarewood,paperandcottoncloth.
Raincoats, umbrellas, plastic and hats are examples of nonabsorbent
materials.
ACTIVITY 8.4
(e) ElectricalConductivity
ACTIVITY 8.4
287
Figure8.6:Testofelectricalconduction
ACTIVITY 8.5
How do you test for electrical conduction? Arrange equipment to find
out which materials are electrical conductors and which are electrical
insulators. Figure 8.6 will help you do the test. Place the material
betweenthebatteryandthebulbtobetested.Seewhathappenstothe
lightbulb. Test several types of samples such as pencil, flower, soil,
waterandspoon.
Table8.3summarisestheelectricalresistivityofsomecommonmaterials.
Table8.3:ElectricalResistivityofSomeCommonMaterials
Materials
ElectricalResistivity(108ohms/m)
Copper
1.67
Aluminium
2.65
Iron
9.71
Steel
12.0
Pyrexglass
105
Concrete
0.1
Nylon
1016
Rubber
Softwood
288
(f)
HeatConductivity
Whatisheatconductivity?
Amaterialthatallowsheattopassthroughiteasilyisamaterialthat
conductsheat.
Metals can conduct heat while nonmetals cannot conduct heat. Each
materialconductsheatinitsownspecialway.Agoodconductorwould
beusedinradiatorswhereasapoorconductorwouldbeusedtoinsulate
extremeheat.
Table8.4:ValuesofHeatConductionofSomeMaterials
Materials
ValuesofHeatConduction(Relative)
Copper
8000
Aluminium
4000
Brass
2500
Steel
1100
Pyrexglass
24
Concrete
Solidplastic
Rubber
FoamedPlastic
289
(g) Magnetism
Magnetismisthepropertyofmaterialstoattractiron,forexample,iron
oxide, cobalt, nickel and certain types of alloy. Actually, it is quite
difficult to explain the definition of magnetism; however, it is much
easier to explain what magnets do. Some of the characteristics of
magnetismareasfollows.
(i)
Magneticmaterialscanbeattractedbymagnets;
(ii)
Attractionmayhappenfromadistance;
(iii) Everymagnethastwopoles:northandsouthpoles;
(iv) Differentpoleswillbeattractedbutsimilarpoleswillberepelled;
(v)
Theregionaroundamagnetisknownasamagneticfield;
(vi) Bringing iron into close contact with a magnet will produce a
temporarymagnet;
(vii) Bringing steel into close contact with a magnet will produce a
permanentmagnet;and
(viii) Magnetismisreducedbyheatingorhammeringamagnet.
(h) OtherPropertiesofMaterials
Table8.5:OtherPropertiesofMaterials
Properties
Explanation
Hardness
290
Solubility
Waterproof Resistancetoliquids.Repelswater.
ACTIVITY 8.6
Go on the Internet and find out more on materials and their uses
based on their properties. Discuss your findings with you
coursemates.
Materials play a pivotal role in our life, particularly in the areas of living
environment,health,communication,consumergoodsandtransport.Pressing
environmentalconcernsforceustousematerialsmoreefficiently.Itwillhelp
in the long run if we develop new energy generation technologies, more
energy efficient devices, and easily recyclable, less toxic materials. As far as
consumer goods are concerned, we need to emphasise not only on the
material products but also on the way they are handled such as packaging,
fasterproductionandhigherqualitygoods.
291
292
Table8.6:OtherUsesofPropertiesofMaterialsinProducingSomeEveryday
Objects
Property
Materials
Strength
Uses
Structuralcomponents
E.g.,rolledsteeljoints
Malleability
Waterpipes
Metals
Thermal
conductivity
Radiators,saucepans,ovens
Electrical
conductivity
Electricalcables
Hardness
Drillbits,hammerheads
Strength
Brick,concrete
Heatresistance
Ceramics
Abrasion
resistance
Ovenware
Crockery
Glass
Thermal
insulation
Loft,cavitywallinsulation
Transparency
Windows
Flexibility
Mouldeditems
Electrical
insulation
Sheathingofelectricalcables
Plastics
Thermal
insulation
Saucepanhandles
Lightness
strength
and
Construction,windowframes
Lightness
strength
and
Construction,
frames,
Wood
furniture
Flexibility,
insulation
Fabrics
doors,
window
Curtains,clothing,furnishing
293
8.2
NATURAL MATERIALS
Alllivingthingsandnonlivingthingsaresourcesofmaterials.Materialsthat
are originated from nature such as living organisms, plants and animals are
classifiedasbioticorbiologicalderivednaturalmaterial.Materialsoriginated
from soil, petroleum or metals are classified as abiotic or nonbiological
naturalmaterials.Weneedthesematerialstosupportourdailyneeds.
Naturalmaterialsaremadenaturallyafteralongperiodoftime.Forexample,
a rubber tree may take many years to become mature and ready for cutting
downtomake furniture,papersand insulators. Chemistry hasenabled us to
synthesise new materials, which have desired properties, thus making them
evenbetterthannaturalmaterialsinashorterperiodoftime.
(a) IdentifyingNaturalMaterials
Table8.7:GasesandTheirUses
Gas
%Present
inAir
Uses
Nitrogen
78.0
Nitratesinsoil,useinammoniaproduction.
Oxygen
21.0
Respiration,oxidation,medicalapplication
Carbondioxide
0.04
Photosynthesis,dryice
Neon
Trace
Lighting
Argon
Trace
Domesticlightbulb
Helium
Trace
Airships
Krypton
Trace
Hightemperaturelightbulb
Xenon
Trace
Hightemperaturelightbulb
294
Waterisacolourless,odourlessliquid,whichisoriginallyderivedfrom
theearthsatmosphere.Itisrecycledfromtheatmospheretothecrustof
theearth.Itisimportantbecauseitsupportslifeontheplanet,asalmost
all the significant reactions at cellular level depend on the aqueous
solutions.
Wood,metal,leather,cotton,rubberandsilkarematerialsthataremade
of natural materials. These materials are considered valuable in their
relativelyunmodified(natural)form.
(b) ObjectsfromNaturalMaterials
Materials from natural materials vary in their use. Table 8.8 shows
naturalmaterialsandtheiruses.
Table8.8:NaturalMaterialsandTheirUses
(c)
NaturalMaterial
Uses
Rubber
Latex
Wood
Timber
Paraffinwaxandstearicacid
Candles
Carbonblackandwateroroil
Ink
Vegetablefibre
Woodpulp
Vegetablewaxes,oilandsap
Carnaubawax,linseedoil
Animalfibre
Wool,alpaca
Animalproduct
Leather,tallow,lard
SourceofRawMaterials
Rawmaterialsarematerialsthatareextractedfromtheearth.Processed
rawmaterialsarecalledsemifinishedmaterials.Whenitistransferred
intoanewcycleofproduction,theendproductisreadyforuse.
Theearthisthemainsourceofrawmaterials.Bioticmaterialsandnon
bioticmaterialsare thetypesofsources ofrawmaterials.Wood,straw,
humus, spider silk, and bone are examples of biotic materials. Biotic
materials are usually biodegradable, renewable and processing has
minimal impact on the environment. Somehow, in certain cases,
295
Anotherexampleiscotton.Cottonisproducedfromamaturedflowerof
a cotton tree. It is harvested by plucking from a matured cotton tree
flower. The fluffy white material is then brought to the factory and
processedtoproducecottonthread.
SELF-CHECK 8.3
1. Whatisanaturalmaterial?
2. Statesomeobjectsthataremadefromnaturalmaterials.
3. Giveasmanyexamplesasyoucanofrawmaterialsthatcanbefound
inyoursurroundings.
8.3
MANUFACTURED MATERIALS
(a) IdentifyingManufacturedMaterials
296
Thesawingoftimber,theproductionofpaperfromwoodpulpandthe
production of latex from rubber are examples of basic manufacturing
processes that involve biological raw materials. Secondary industries
involve the production of plastics (including synthetic fibres such as
nylon and terylene) from crude oil derivatives, detergents, paint and
perfumefromcoal,andothers.
Manufacturedmaterialsusuallyhavebetterpropertiescomparedtothe
naturalmaterialsfromwhichtheycomefrom.Theyareusuallydesigned
forspecificneeds,liketyresaremadeoflatexandsulphur.Metals,glass,
ceramics,plastics(includingrubber),paperand fabricsare examplesof
manufacturedmaterials.
ACTIVITY 8.7
(b) ObjectsfromManufacturedMaterials
Table8.9:ObjectsfromManufacturedMaterials
Manufactured
Material
Synthetic
rubber
Metals
Synthetic
Polymer
Uses
Styrenebutadiene
Tyres,shoesoles
rubber(SBR)
Neoprenerubber
Waterpipes,handgloves
Butylrubber
Tyres,shoesoles,hoses
Stainlesssteel
Cookingutensil,
Bronze
Medals,
Duralumin
Cookingutensil
297
Glass
Ceramic
Fabric
Plastic
Pyrex
Laboratory
utensil
apparatus,
cooking
Crystal
Cookingutensil
Brick
Building
Tiles
Building
Pottery
Decoration
Nylon
Cloth
Polyvinylchloride
Nylon
Synthetictextile,string,parachutes
Polythene
Plasticbags,foodcontainers,pails
Polystyrene
Packagingmaterials,heatinsulators,
toys
Melamine
Plates,cups
Epoxyglue
Glue,electricalinsulators
SELF-CHECK 8.4
1. Explainwhatmanufacturedmaterialsare.
ACTIVITY
8.8
fairtest.
298
8.4
PRESERVATION OF NATURAL
MATERIALS
Aboutacenturyago,almosttheentirecountrywascoveredwithforests.Wild
cuttingofforestsduringtheearlysettlementcausedvastareasofbaredland.
This phenomenon of cutting down plants for timber and development
continuestoday.
Preservationreferstotheefforttomaintainnaturalresourcesintheiroriginal
stateoringoodcondition.Generally,preservationisrelatedtoconservation.
Conservation refers to the sustainable use and management of natural
materialstopreventloss,wastageordamage.
Preservationshouldbepractised.Someoftheactionsthatshouldbetakento
preservenaturalmaterialsare:
(a) PreventingForestFires
Forest fires are wildly destructive. Plants and wildlife are killed. Forest
fires are caused by lightning (natural cause) and peoples carelessness
(accidentalcause).
(b) ImprovementCutting
Unwanted trees in a forest are removed from the stand. Crooked, aged
anddiseasedtreesaswellastreesoflessdesirablespeciesarecut.Inthis
way, space is provided for the growth of healthy, more valuable trees.
Thispracticeincreaseslumberyieldandimprovesitsquality.
(c) EnforcementofLawsandRegulation
299
Figure8.7:Thegovernmenttodayhasenforcedlawsandregulationtoprotect
theorangutanandtheirhabitat
SELF-CHECK 8.5
Whatactionsshouldwetaketopreserveournaturalmaterials?
ACTIVITY 8.9
1. Whatnaturalresourcesaredestroyedbyforestfire?
2. In a group, discuss what action should be taken to prevent forest
fire.
8.5
COMPOSITE MATERIALS
Composite materials are those that combine the properties of two or more
constituents in order to get the exact properties needed for a particular job.
The examples of material usually used are metals, alloys, glass, ceramics,
plasticsandpolymers.Acompositematerialhaspropertiesthataresuperior
tothoseoftheoriginalcomponents.
300
cellulosefibresinaligninmatrix(seeFigure8.8).Seashellsandlimestoneare
bothmadeofcalciumcarbonate,butseashellsaremuchharderbecausethey
are composites of crystalline calcium carbonate with embedded polypeptide
fibres.
Figure8.8:Thecombinationofcellulosefibresandligninmakethecellwall
strong
Thecompositeindustrywaslaunchedintheearly1960swiththedevelopment
offibreglassorglassreinforcedplastic.Itismadebyembeddingshortfibres
ofglassinamatrixofplastic.Theglassfibresgivetheplasticextrastrengthso
that it does not break when it is bent or moulded into shape. The finished
producthasthelightnessofplasticaswellasthestrengthandflexibilityofthe
glass fibres. They have found in many marine, housing, construction, sports
and industrial applications. Figure 8.9 shows the use of glassreinforced
plasticinmakingthebodyoftheboat.
Figure8.9:Theglassreinforcedplasticusedtomakeboats
301
Anothercompositematerialwhichisusuallyusedfortheconstructionoflarge
structures like highrise buildings, bridges and oil platforms are reinforced
concrete (see Figure 8.10). Concrete is a composite material that consists of a
mixtureofstones,chipsandsandboundtogetherbycement.Itisstrongbut
brittleandweakintensilestrength.Toovercomethisweakness,theconcrete
canbereinforcedwithsteelwirenettingorsteelrod,whichresultstoavery
tough material with high tensile strength. Reinforced concrete is relatively
cheapandcanbemouldedintoanyshape.
Figure8.10:Thereinforcedconcretewithsteelwirenettingandsteelrods
Thestrongestnewcompositearetheadvancedcomposites,inwhichfibresare
alignedorinterwovenbeforebeingsetwithintheresin.Advancedcomposites
have extraordinary strength in the direction of the aligned fibres and are
relativelyweakintheperpendiculardirection.Weaknessinonedirectioncan
beovercomebylaminatinglayerstogetheratdifferentangles,asinplywood,
afamiliarcomposite.Strengthinalldirectionscanbeachievedbyweavingthe
fibres into a threedimensional network. Besides strength, advanced
compositesarealsoknownfortheirlightness,whichmakethemidealforcar
parts, sporting goods and artificial limbs. Advanced composites tend to be
expensive, however because much of their production is still done by hand.
Aeroplane parts, and even whole aeroplane, are now being fabricated out of
lightweightadvancedcompositesinordertosavefuel.In1986,thefirstplane
302
built with all advanced composites material is Voyager, which can fly
aroundtheworldwithoutrefuelling(seeFigure8.11).
Figure8.11:ThealladvancedcompositeVoyageraeroplane
ACTIVITY 8.10
1.
2.
3.
8.6
What is a composite and what are some examples found in nature other
MATERIALS IN INDUSTRY
Letusnowlearnonthematerialsinindustry.
8.6.1 Soap
303
Figure8.12:Soapismanufacturedbyheatingnaturalfatsandoilwithastrong
alkali
Nowadays, fat is boiled with aqueous sodium hydroxide to form soap. The
esters are broken down in the presence of waterhydrolysed. This type of
reaction is called saponification. The equation given below is that for the
saponificationofglycerylstearate(afat)(seeFigure8.13).
(soap)
Figure8.13:Saponificationreaction
304
The cleaning properties of the soap depend on its structure and bonding.
Sodium stearate consists of a long hydrocarbon chain which is hydrophobic
(waterhating)attachedtoanionicheadwhichishydrophilic(waterloving)
(seeFigure8.14).
Figure8.14:Simplifieddiagramofasoapmolecule
Covalent compounds are generally insoluble in water but they are more
solubleinorganicsolvents.Ioniccompoundsaregenerallywatersolublebut
tendtobeinsolubleinorganicsolvents.Whensoapisputintowaterwhich
hasagreasydish(oragreasycloth)init,thehydrophobichydrocarbonchain
oneachsoapmoleculebecomeattractedtothegreaseandbecomeembedded
init(Figure8.15).
with
agitation
Figure8.15:Howsoapswork
305
On the other hand, the hydrophilic ionic head group is not attracted to the
grease/dirt/oilbutisstronglyattractedtothewatermolecules.Whenthewater
isstirred,thegrease/dirt/oilisslowlyreleasedandiscompletelysurrounded
bythesoapmolecules.Thesoapisabletoremovethegrease/dirt/oilbecause
ofthecombinationofthecovalentandionicbondspresent.
Naturalrubberisapolymerwithitsmonomerunit,isoprene(seeFigure8.16).
Duringpolymerisation,thousandsofisopreneunitswilljointogethertoform
poly(isoprene)ornaturalrubber(seeFigure8.17).
Figure8.16:Isopreneunit
306
Figure8.17:Polyisoprene(naturalrubber)
Naturalrubbercommonlyhashighlyelasticitybutisunstabletoheatandoxidation.
Whenitiswarmedabove50C,itsoftensandbecomesstickyandwilldecomposeif
weheatittoatemperatureabove200C.Thepresenceofdoublebondsinthepolymer
chainmakesitsusceptibletooxidationandbreaksupthepolymerchains.
VulcanisationisamanufacturingprocessdiscoveredbyCharlesGoodyearin1939to
convertnaturalrubberintoatoughusefulproduct.Inthisprocess,about1%to3%by
weightofsulphurisaddedtorawrubberandthemixtureiscarefullyheated.Sulphur
atoms form crosslinks between adjacent chains of rubber polymer at the carbon
carbondoublebonds(seeFigure8.18).
Figure8.18:Vulcanisedrubbershowingdisulfidecrosslinks
Synthetic rubber is any type of artificial elastomer mainly synthesised from
petroleum by products. An elastomer is a material with the mechanical (or
material) property that it can undergo much more elastic deformation under
stress than most materials and still return to its previous size without
permanentdeformation.Syntheticrubber,likenaturalrubber,hasusesinthe
automotive industry for door and window profiles, hoses (see Figure 8.19),
307
Table8.10:ComparisonofPropertiesbetweenManufacturedMaterials
(SyntheticRubber)andNaturalMaterials(NaturalRubber)
SyntheticRubber
Properties
NaturalRubber
Synthetic
Typeofpolymer
Natural
Abletowithstand
hightemperature
Hightemperatureeffect
Decomposesand
becomeliquid
Verypermeableto
gasandwater
Permeabilitytogasand Notpermeabletogas
water
andwater
Doesnotreactto
acidandalkali
Abilitytowithstand
actionsofacidand
alkali
Reacttoacidand
alkali
Lowability
Abilitytoabsorb
pressure,vibrationand
sound
Highability
Canbevulcanised
Vulcanisation
Easilyvulcanised
Figure8.19:Productfromsyntheticrubber
308
Additional key advantages of natural fibres are their high strength and
stiffness per weight along with benefits such as acoustic isolation, safety
management, rapid production and potentially low cost. The most viable
structural fibres typically derive from specifically grown textile plants and
fruit trees. There are two categories of natural fibres, vegetable fibres and
animalfibres.Vegetablefibresaresubdividedintobastfibres(flax,hemp,jute
and kenaf) leaf fibres (sisal, pineapples and henequen), grass fibres (bamboo
and miscanthus), straw fibres (corn and wheat), seed fibres (cotton and
capok), wood fibres (pinewood) and fruit fibres (coconut), whereas animal
fibresaresilk,avian,hairandwool(seeFigure8.20).Figure8.21showskenaf
plantswhichisfromthebastfibrescategory.
Figure8.20:Twocategoriesofnaturalfibres
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Figure8.21:Kenafplantsisasourceofnaturalfibre
Syntheticfibresaremadefromsynthesisedpolymersorsmallmolecules.The
compoundsthatareusedtomakethesefibrescomefromrawmaterialssuch
as petroleum based chemicals or petrochemicals. These materials are
polymeriseintoalong,linearchemicalthatbondtwoadjacentcarbonatoms.
Different chemical compounds will be used to produce different types of
fibres. Although there are several different synthetic fibres, they generally
havethesamecommonproperties.Syntheticfibresarecommonlyveryheat
sensitive,resistanttomostchemicals,insect,fungiandrot.Ithaslowmoisture
absorbency,flameresistant,lowmeltingtemperature.Syntheticfibresarealso
very easy to wash and maintain and the main thing is that it is often less
expensivethannaturalfibres.
Thefirstsyntheticfibreknownasnylonwasdiscoveredin1931.Itsnoveluse
asamaterialforwomensstockingovershadowedmorepracticaluses,suchas
a replacement for the silk in parachutes and other military uses. Other
commonsyntheticfibresaremodacrylic,olefin,acrylic,polyesterandcarbon
fibre. Specialty synthetic fibres include vinyon, saran, spandex, vinolon,
aramids, modal, sulfar, orlon, zylon, vecran, derclon and rayon. Figure 8.22
showstwoexamplesofsyntheticfibres.
310
Figure8.22:Nylonandpolyester
ACTIVITY 8.11
1. Compareandcontrastnaturalfibresandsyntheticfibres.
2. Find out the uses of all common natural and synthetic fibre
giveninthetext
8.6.4 Plastics
311
Figure8.23:Tupperware,polyethylenefoodcontainer
312
x
x
x
313
x
x
x
x
x
x
x
x
x
x
x
x
Materials which can absorb water are known as absorbent materials and
materials which cannot absorb water are known as nonabsorbent
materials.
A material that allows electricity to pass through it is a material that
conductselectricity.
A material that allows heat to pass through it easily is a material that
conductsheat.
Magnetism is the property of materials to attract iron, for example, iron
oxide,cobalt,nickelandcertaintypesofalloy.
Knowledgeaboutthepropertiesofmaterialsisveryimportant,especially
inchoosingsuitablematerialstomakevariousobjects.
Thepropertiesofmaterialshavemanyusefulapplicationsinourdailylife.
Materialsaremadeofthousandsofsmallparticlescalledatoms.
Materials can be divided into three categories according to their
componentsofatom:element,compoundandmixture.
Materials can be classified into two types according to their use: natural
materialsandmanmadematerialsormanufacturedmaterials.
Natural materials originate from soil, rocks, water, plant, animal or
minerals.
Manufactured materials are made from a mixture of natural materials
throughchemicalprocesses.
Manufacturedmaterialsaredesignedaccordingtotheneedsofthemarket.
Preservation refers to the effort to maintain natural resources in their
originalstateoringoodcondition.
Conservation refers to the sustainable use and management of natural
materialstopreventloss,wastageordamage.
Composite materials are the materials which combine the properties of
twosubstancesinordertogettheexactpropertiesrequiredforaparticular
job.
314
Saponificationistheprocessofmakingsoapbyheatingnaturalfatsandoil
withastrongalkali.
x
x
x
Abiotic
Mixture
Biotic
Naturalmaterial
Component
Plastics
Compositematerials
Preservation
Conservation
Rawmaterial
Element
Rubber
Fibre
Soap
Manufacturedmaterial
Synthetic
Material
315
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