Hall-Yarborough (1973) z-factor calculation

Hall, K.R. & Yarborough, L. (1973): A New Euation of State for Z-factor Calculations,
The Oil and Gas Journal, June 18, 82-92
Molecular weight oxygen, MO
Molecular weight sulfur, MS
Molecular weight, carbon, MC
Molecular weight, hydrogen, MH
Molecular weight air, MA
Components
Methan, CH4
Ethan, C2H6
Propan, C3H8
i-Butane, C4H10
n-Butane, C4H10
i-Pentane C5H12
n-Pentane C5H12
Hexane C6H14
Heptane C7H16
Hydogen, H2
Nitrogen, N2
Oxygen, O2
Carbon dioxid, CO2
Hydrogensulfid, H2S
Dihydrogenoksid, H2O
Total molecular weight gas

15.9994
32.07
12.01
1.01
28.97
Molecular weight
g/mole
16.042
30.07
44.10
58.12
58.12
72.15
72.15
86.18
100.21
2.02
28.01
32.00
44.01
34.08
18.02
Mole fraction

g/mole
g/mole
g/mole
g/mole
g/mole
Mole fraction
yi

0.00 g/mole

Spesific gravity
Temperature
Pressure
Method used (1, 2 or 3)

0.00
0.00 oC
0.000E+00 Pa

Compressebility factor, z

#DIV/0!

Method 1 (Properties from composition, Key's rule)

Pseudo critical temperature
TPc (oil field units)
TPc (SI units)
Pseudo critical pressure

0.00 oR
0.00 K

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0000

PPc (oil field units)

PPc (SI units)

0.00 psia
000.0E-2 Pa

Method 2 (Sutton's correlations)

Pseudo critical temperature
TPc (oil field units)
TPc (SI units)

169.20 oR
93.67 K

Pseudo critical pressure

PPc (oil field units)

756.80 psia

PPc (SI units)

521.9E+4 Pa

Method 3 (Standing's correlation)

Pseudo critical temperature
TPc (oil field units)
TPc (SI units)

168.00 oR
93.00 K

Pseudo critical pressure

PPc (oil field units)

667.00 psia

PPc (SI units)

Pseudo reduced properties

TPR
PPR

460.0E+4 Pa

#DIV/0!
#DIV/0!

Hall-Yarborough
t
a
Reduced-density parameter, y0

#DIV/0!
#DIV/0!
0.01

T pr =

T
T pc

P pr=

p
p pc

t=

1
T pr

Continue until f(y) < 1x10^(-5)

Iteration 1
f(y)
Derivated of f(y), df(y)
Newton Rapson: Reduced- density parameter, y1

#DIV/0!
#DIV/0!

Compressebility factor, z

#DIV/0!

#DIV/0!

Z=

p pr
y

Iteration 2
f(y)
Derivated of f(y), df(y)
Newton Rapson: Reduced-density parameter y2

#DIV/0!
#DIV/0!

Compressebility factor, z

#DIV/0!

Iteration 3
fy
Derivated of f(y), df(y)
Newton Rapson: Reduced-desity parameter y3

#DIV/0!
#DIV/0!

Compressebility factor, z

#DIV/0!

Iteration 4
f(y)
Derivated of f(y), df(y)
Newton Rapson: Reduced-density parameter y4

#DIV/0!
#DIV/0!

Compressebility factor, z

#DIV/0!

#DIV/0!

#DIV/0!

#DIV/0!

Iteration 5
f(y)
Derivated of f(y), df(y)
Newton Rapson: Reduced-density parameter y4

#DIV/0!
#DIV/0!

Compressebility factor, z

#DIV/0!

#DIV/0!

f
y i+1 = y i
f'

Instructions
1.
2.
3.
4.
Tci
Tci
oR
K
343 190
549.8 305
665.7 370
734.7 408
765 425
829 460
845 469
913 507
972 540
60
33
227.4 126
277.8 154
547.6 304
672.4 373
1165 647

Pci
psia
667.8
708
616
529
551
491
489
437
397
187
492
731
1071
1306
3199

Pci
Mpa
4.61
4.88
4.25
3.65
3.80
3.39
3.37
3.01
2.74
1.29
3.39
5.04
7.38
9.01
22.06

273.15 K

Insert mole fractions.

Insert temperature [C] and pressure [Pa].
Choose which pseudo method you will use.
Read your z-factor beneath.

(Insert values in cells where the font color is red)

Convertion
oC -> K
atm -> bar
cp -> Pas
bar -> Pa
m m -> m
oR -> K
psig -> bar
oF -> oR

273.15
1.01325
1.00E-03
1.00E+05
1.00E-03
0.56
0.07
460

Methods for finding pseudo critical pressure

and pseudo critical temperature
1. Properties from composition, Key's rule (Preferred choice).
Newton-Rapson iteration.
2. Sutton's correlations
3. Standing's correlations

TPc= T i y i
PPc= Pi y i

TPc 169.2 + 349.5 g - 74,0 g

PPc = 756 . 8 - 131,0 g - 3 . 6

If we have a "dry" gas, SG < 0,75

T pr =

T
T pc

P pr =

p
p pc

t=

If we have a "wet" gas, SG

T pcHC =168+325 gHC 12, 5

gHC 2

p pcHC =667+15 ,0 gHC 37 , 5

gHC2

pr

T pcHC =187+330 gHC 71

p pcHC =706+51 , 7 gHC 11 ,

a=0, 06125 te
2

f ( y )=0=ap pr +

Z=

g2

( 1,2(1t )2)

1
T

p pr
y

y+ y + y y
( 14 ,76 t 9, 76 t 2 +4, 58 t 3 ) y 2 + ( 90
3
( 1 y )

df ( y ) 1+ 4 y + 4 y 2 4 y3 + y 4
=
( 29 , 52 t 19 , 52t 2 + 9, 16 t 3 ) y+ ( 2, 18+
4
dy
( 1 y )

f ( y)
y i+1 = y i
f ' ( y)

[Pa].
l use.

r is red)

al pressure

erred choice).

wet" gas, SG 0,75

87+330 gHC 71 ,5

6+51 , 7 gHC 11 , 1

gHC 2

gHC 2

76 t 2 +4, 58 t 3 ) y 2 + ( 90 , 7 t 242 , 2t 2 + 42 , 4 t 3 ) y2, 18+2, 82 t

t 2 + 9, 16 t 3 ) y+ ( 2, 18+ 2, 82t ) ( 90 , 7 t 242 , 2 t 2 +42 , 4 t 3 ) y 1, 18+2, 82 t