Chemistry CH# 6

Total marks=40

Attempt any 10 questions.

2*10=20

a) Sigma bond is stronger than pi bond explain.

b) Why MOT theory is superior than VBT.
c) CO2 has linear structure but H2O has angular justify it.
d) Define bond order.
e) Lone pair of electrons of an atom occupy more space explain.
f) Discuss variation of electronegativity in a group and period.
g) 2nd ionization energy is always greater than 1 st one explain.
h) How molecular orbit theory explains that He is mono atomic.
i) Define electron affinity and give its trend in periodic table.
j) Define polar and non polar covalent bond.
k) No bond in chemistry is 100 % ionic justify it.
l) The abnormality of bond length and bond strength in HI is less prominent than that of HCl.
m) Bond distance is compromise distance between two atoms.

Attempt four questions.

5*4=20
Define ionization energy and write a note in it.
Define dipole moment give its S.I unit and write a note on that.
Define hybridization and explain the structure of H2O and CH4 with help of that.
How will you describe paramagnetic character of O2 molecule on the basis of MOT.
Define VESEPER write postulates of VESEPER theory.

Chemistry CH# 7

Total

marks=30

NoteAttempt all questions.

8*2=16

a) Differentiate between reversible and irreversible reactions.

b) Define 1st law of thermodynamics and its mathematical form.
c) Define state function.
d) Define system and surroundings.
e) Differentiate between enthalpy and internal energy.
f) Differentiate between endothermic and exothermic reactions. Give ex.
g) Define Enthalpy of solution and Enthalpy of atomization give ex.
2) Write bomb calorimeter method for the determination of enthalpy of combustion. 05
3)State and explain Hess,s law for constant heat summation with one example.
05
4) Define born Haber cycle give ex.
04