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GENERAL PRINCIPLE
S
PRINCIPLES
AND PR
OCE
SSE
S OF
OCESSE
SSES
PROCE
ISOL
ATION OF
ISOLA
ELEMENTS
(i)
(ii)
(iii)
(iv)
When copper ore is mixed with silica, in a reverberatory furnace copper matte
is produced. The copper matte contains ____________.
(i)
(ii)
(iii)
(iv)
no
2.
3.
(ii)
Cu2O + C 2Cu + CO
(iii)
(iv)
Cu2O +
1
1
Cu2S 3Cu + SO2
2
2
4.
(i)
Al and Fe
(ii)
Al and Cu
(iii)
Fe and Cu
(iv)
Cu and Ag
(ii)
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5.
6.
7.
(iii)
(iv)
In the extraction of copper from its sulphide ore, the metal is formed by the
reduction of Cu2O with
(i)
FeS
(ii)
CO
(iii)
Cu2S
(iv)
SO2
(ii)
1
Cl (g) + e ;
2 2
9.
E Cell = 1.36V
V
+
2H2O (l ) O2 (g) + 4H + 4e ; E Cell = 1.23V
(iii)
(iv)
H (aq.) + e
+
1
H (g) ;
2 2
E Cell = 2.71V
V
E Cell = 0.00V
(i)
Al is oxidised to Al (s).
(ii)
(iii)
(iv)
no
8.
Cl (aq.)
Cu and Zn
(ii)
Ge and Si
(iii)
Zr and Ti
(iv)
Zn and Hg
78
10. Extraction of gold and silver involves leaching the metal with CN ion. The
metal is recovered by ________________.
(i)
(ii)
(iii)
(iv)
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Fig. 6.1
no
11. Choose the correct option of temperature at which carbon reduces FeO to iron
and produces CO.
(i)
(ii)
(iii)
(iv)
(ii)
(iii)
(iv)
13. For the reduction of FeO at the temperature corresponding to point D, which
of the following statements is correct?
G value for the overall reduction reaction with carbon monoxide is
zero.
(ii)
G value for the overall reduction reaction with a mixture of 1 mol carbon
and 1 mol oxygen is positive.
(iii)
G value for the overall reduction reaction with a mixture of 2 mol carbon
and 1 mol oxygen will be positive.
(iv)
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(i)
14. At the temperature corresponding to which of the points in Fig.6.1, FeO will
be reduced to Fe by coupling the reaction 2FeO 2Fe + O2 with all of the
following reactions?
(a) C + O2 CO2
(i)
Point A
(ii)
Point B
(iii)
Point D
(iv)
Point E
Cast iron is obtained by remelting pig iron with scrap iron and coke
using hot air blast.
(ii)
(iii)
(iv)
no
(i)
(ii)
(iii)
(iv)
acts as catalyst.
80
17. Which of the following statements is correct about the role of substances added
in the froth floation process?
(i)
(ii)
(iii)
(iv)
18. In the Froth Floatation process, zinc sulphide and lead sulphide can be
separated by ______________.
using collectors.
(ii)
(iii)
using depressant.
(iv)
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(i)
CuO
(ii)
ZnO
(iii)
Fe2O3
(iv)
SiO2
Haematite
(ii)
Galena
(iii)
Copper pyrites
(iv)
Magnetite
(ii)
2FeS2 +
(iii)
(iv)
ZnS +
11
O Fe2O3 + 4SO2
2 2
3
O ZnO + SO2
2 2
no
22. For the metallurgical process of which of the ores calcined ore can be reduced
by carbon?
(i)
haematite
(ii)
calamine
(iii)
iron pyrites
(iv)
sphalerite
81
23. The main reactions occurring in blast furnace during extraction of iron from
haematite are ________.
(i)
(ii)
(iii)
(iv)
24. In which of the following method of purification, metal is converted to its volatile
compound which is decomposed to give pure metal?
heating with stream of carbon monoxide.
(ii)
(iii)
liquation.
(iv)
distillation.
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(i)
(ii)
(iii)
(iv)
(i)
(ii)
(iii)
(iv)
V
V
27. Why is an external emf of more than 2.2V required for the extraction of Cl2 from
brine?
28. At temperatures above 1073K coke can be used to reduce FeO to Fe. How can
you justify this reduction with Ellingham diagram?
no
29. Wrought iron is the purest form of iron. Write a reaction used for the
preparation of wrought iron from cast iron. How can the impurities of sulphur,
silicon and phosphorus be removed from cast iron?
30. How is copper extracted from low grade copper ores?
31. Write two basic requirements for refining of a metal by Mond process and by
Van Arkel Method.
32. Although carbon and hydrogen are better reducing agents but they are not
used to reduce metallic oxides at high temperatures. Why?
Exemplar Problems, Chemistry
82
33. How do we separate two sulphide ores by Froth Floatation Method? Explain
with an example.
34. The purest form of iron is prepared by oxidising impurities from cast iron in
a reverberatory furnace. Which iron ore is used to line the furnace? Explain
by giving reaction.
35. The mixture of compounds A and B is passed through a column of Al2O3 by
using alcohol as eluant. Compound A is eluted in preference to compound B.
Which of the compounds A or B, is more readily adsorbed on the column?
36. Why is sulphide ore of copper heated in a furnace after mixing with silica?
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38. Which method is used for refining Zr and Ti? Explain with equation.
41. How are metals used as semiconductors refined? What is the principle of the
method used?
42. Write down the reactions taking place in Blast furnace related to the metallurgy
of iron in the temperature range 500-800 K.
43. Give two requirements for vapour phase refining.
44. Write the chemical reactions involved in the extraction of gold by cyanide
process. Also give the role of zinc in the extraction.
Note : Match the items given in Column I and Column II in the following
questions.
45. Match the items of Column I with items of Column II and assign the correct code:
Column I
Column II
(B) Malachite
(C) Calamine
(3) Na3AlF6
no
(A) Pendulum
(D) Cryolite
Code :
(i)
A (1)
B (2)
C (3)
D (4)
(ii)
A (2)
B (4)
C (5)
D (3)
(iii)
A (2)
B (3)
C (4)
D (5)
(iv)
A (4)
B (5)
C (3)
83
D (2)
General Principles and Processes of Isolation of Elements
46. Match the items of Column I with the items of Column II and assign the correct
code :
Column I
Column II
(4) Chromatography
(5) Liquation
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Code :
(i)
A (1)
B (2)
C (4)
D (5)
(ii)
A (4)
B (3)
C (1)
D (2)
(iii)
A (3)
B (4)
C (2)
D (1)
(iv)
A (5)
B (4)
C (3)
D (2)
47. Match items of Column I with the items of Column II and assign the correct
code :
Column I
Column II
(1) Ultrapure Ge
(3) Extraction of Al
(4) Extraction of Au
(5) Purification of Ni
Code :
(i)
A (4)
B (2)
C (3)
D (1)
(ii)
A (2)
B (3)
C (1)
D (5)
(iii)
A (1)
B (2)
C (3)
D (4)
(iv)
A (3)
B (4)
C (5)
D (1)
48. Match the items of Column I with the items of Column II and assign the correct
code :
Column II
(A) Sapphire
(1) Al2O3
(B) Sphalerite
(2) NaCN
(C) Depressant
(3) Co
(D) Corundum
(4) ZnS
no
Column I
(5) Fe2O3
84
Code :
(i)
A (3)
B (4)
C (2)
D (1)
(ii)
A (5)
B (4)
C (3)
D (2)
(iii)
A (2)
B (3)
C (4)
D (5)
(iv)
A (1)
B (2)
C (3)
D (4)
49. Match the items of Column I with items of Column II and assign the correct
code :
Column I
Column II
(1) Aluminium
(3) Iron
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(A) Blisterred Cu
Code :
(i)
(ii)
(iii)
(iv)
A (2)
B (3)
C (4)
D (1)
A (1)
B (2)
C (3)
D (5)
A (5)
B (4)
C (3)
D (2)
A (4)
B (5)
C (3)
D (2)
(i) Both assertion and reason are true and reason is the correct explanation
of assertion.
(ii) Both assertion and reason are true but reason is not the correct explanation
of assertion.
(iii) Assertion is true but reason is false.
(iv) Assertion is false but reason is true.
no
Assertion
Reason
51. Assertion
Reason
85
52. Assertion
Reason
53. Assertion
Reason
54. Assertion
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Reason
(a) CO2 is a better reducing agent below 710K whereas CO is a better reducing
agent above 710K.
(b) Generally sulphide ores are converted into oxides before reduction.
(c) Silica is added to the sulphide ore of copper in the reverberatory furnace.
(d) Carbon and hydrogen are not used as reducing agents at high
temperatures.
no
(e) Vapour phase refining method is used for the purification of Ti.
86
ANSWERS
I. Multiple Choice Questions (Type-I)
1. (iii)
2. (iii)
3. (iv)
4. (i)
5. (ii)
6. (iii)
7. (i)
8. (ii)
9. (i)
10. (i)
11. (iv)
12. (i)
13. (i)
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28.
29.
30.
no
2+
31.
(i) The metal should form a volatile compound with an available reagent.
32.
33.
34.
Haematite
Fe2O3 + 3C 2Fe + 3CO
Since compound A comes out before compound B, the compound B is
more readily adsorbed on column.
36.
Iron oxide present as impurity in sulphide ore of copper forms slag which
is iron silicate and copper is produced in the form of copper matte.
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35.
37.
Sulphides are not reduced easily but oxides are easily reduced.
38.
van Arkel method is used for refining Zr and Ti. In this method crude
metal is heated with iodine.
Zr + 2I2 ZrI4
1800K
ZrI4
Zr + 2I2
39.
40.
41.
42.
43.
(i) The metal should form a volatile compound with available reagent.
no
44.
4Au (s) + 8CN (aq) + 2H2O (aq) + O2 (g) 4 [Au (CN)2] (aq) + 4OH (aq)
88
46. (ii)
47. (i)
48. (i)
49. (i)
53. (ii)
54. (ii)
51. (i)
52. (ii)
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55.
(d) Hint : Carbon and hydrogen react with metals at high temperature
to form carbides and hydrides respectively.
no
(e) Hint : Ti reacts with iodine to form volatile TiI4 which decomposes at
high temperature to give extra pure titanium.
89