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JEE(Advanced)-2014

ANSWERS, HINTS & SOLUTIONS


FULL TEST I
(Paper-2)

ALL INDIA TEST SERIES

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FIITJEE

Q.
No.

PHYSICS

CHEMISTRY

MATHEMATICS

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

1.

(A) (s), (B) (q),


(C) (p), (D) (r)

(A p, q, r), (B q),
(C p, r, S), (D p)

(A) (q), (B) (r),


(C) (s), (D) (p)

2.

(A) (q); (B) (r);


(C) (s); (D) (p)

(A p, q, s), (B r, s),
(C q), (D r, s)

(A) (s), (B) (p),


(C) (q), (D) (r)

3.

(A) (p), (B) (r),


(C) (s), (D) (q)

(A p, r), (B q, p),
(C q), (D q, s)

(A) (s), (B) (r),


(C) (p), (D) (q)

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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

Physics
2.

3.

PART I

T sin = mg/2
T = T cos
mg
mg
=
cot
2
2 tan

T sin

T cos

1
mv 2 pt (P = const)
2
2Pt

v=
m

a=

dv

dt

2P 1
m 2 t

F = ma =

5.

mP
1

2t
v


F F1 F2 F3 F4 F5

F2 F5 and F2 F4

F1 F3 2F2 cos 30 2F1 cos 60

F3

F2

F4

F1

Gm2
Gm2
Gm2
F3 =
;
F
=
;
F
=
2
1
4a2
3a2
a2
Gm2 5
1
2
F=

= m a
2
a 4
3

F5

Gm 5
1

a3 4
3

T = 2

4 3a3

Gm 5 3 4

6.

S
R

Q
V

7.

a=
t=

10.

v g a m g a
m

= 20 m/s2

2h
= 1 sec
a

Time period becomes 2

R
. We cant neglect the roundness of earth for the pendulum of
g

infinite length.

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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

d
signifies the direction of induced emf.
dt

12.

The ve sign is

14.

process AB U = constant
P RT

and U t
M

P = const
Process BC isochoric
Process CA isothermal

15.

16.

Q = QAB + QBC + QCA


10U0
Q = 5U0 + 3U0 +
ln2.5
3
W AB = QAB UAB = 5U0 (3U0) = 2U0

17.

For lens L1, ray must move parallel to the axis after refraction

18.

For lens L2, image must form at centre of curvature of the curved surface after refraction through
plane part.
2

0
R2 x

1 w 1

x = 10 cm

x
R1

x = 8 cm

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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

Chemistry

PART II

1.

CH2MgBr
Br

OH
H

H
Mg

Ether

O
H3C

Re arrangment

H3C

2.

H3CO

CH O

H3CO

O
O

OH

COOCH3
H3COOC
3.

PAo X A

PAo

PBo

PAo

PAo

PBo

1 XB

O
COOCH3

PBo XB

Thus PAo 120 Torr

4.

PAo PBo 75 PBo 45 Torr


Hence C is correct answer.
1000
o
BaSO

4
Conc normality
Normality

1000
o
BaSO
4

1000 8 10 5
= 2 10-4.
400

Normality
10 4 M Solubility
2
Ksp = S2 = 108 M2.
1
Tav
K
10 0.693 6.93
T99.9 10 ty 2

K
K
6.693 1
Number of natural life times =
/
K K
= 6.93
Molarity

5.

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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

OH

6.
O
HO

B
O

B
B

OH

OH

7.

Ca OCl Cl.H2 O Cl2


145

71

71
100 49
145
Hence D is correct answer.
d c 0.0033
1.32 104 m min1


dt
25

Percentage

17.

d c
4
1
dt 2.6 10 m min

II

18.
19.

dc
3
1

1.02 10 m min
dt III
On comparing rates order w.r.t A = 2, and w.r.t. B = 1. Thus rate law = K[A]2[B]
dx
2
K A B
dt
dx / dt
K
0.26
A 2 B

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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

Mathematics

PART III

1.

Total number of lines made = 9C2 = 36


Now, these 36 lines are 9 sets each with 4 parallel members. With 5 vertices number of lines
made
5
= C2 = 10
Clearly, atleast 2 members belong to the same set
So, atleast one pair is parallel

2.

cos

OA 2 OB 2 AB2
2OA OB
2

OA OB
OA 2 OB2

2
2

2
3 OA OB 1
=
2OA OB
8 OA OB
4
For maximum cos ,
1
3 OA 2 OB 2 1 3 2 OA OB 1
=


8 OA OB 2 8
OA OB
4
2

3.

S1 = a1
S2 = a1 + a2
S3 = a1 + a2 + a3

Sn = a1 + a2 + .. + an
If we divide all S1, S2, .. Sn by 23 we get remainders 1, 2, 3, 4, .., 22
So, two of these give same remainders Sp, Sq
Sp Sq will be divisible by 23
Sp Sq = ap + 1 + ap + 2 + .. + aq

4.

Using Cauchy we get,

5.

Point of intersection is

z1 z2

12
12
22
42
2
z3 z 4

1 1 2 4 64
z
z
z
z
2
3
4
1

1 b
ln
2 a

For C1,
dr
d
ae , now tan 1 r
= ae a 1e 1
d
dr

1
4
For C2,
dr
1
be tan 2 be e 1
d
b
3
2
4
3
Angle of intersection is 2 1

4 4 2

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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

6.

Let c, d, e be the three points where y = f(x) crosses xaxis. Then, f(c) = f(d) = f(e) = 0
Assuming a < c < d < e < b. The function f satisfies Rolles theorem in two intervals (c, d) and
(d, e). Since f and f are continuous and f(c) = f(d) = 0
So, there exists, at least one point in the interval (c, d) and (d, e) such that derivative is zero
Let, C1 (c, d) such that f(C1) = 0 and C2 (d, e) such that f(C2) = 0. Now the function f
satisfies Rolles theorem since f, f are continuous and f(C1) = f(C2) = 0
So, by Rolles theorem, there exists a number C3 in between C1 and C2 such that f(C3) = 0
Minimum one root C3 of the equation f(x) = 0 lies in the interval (a, b)

7.

Dividing the given differential equation by 3xy(y2 x2)


y y2 2x2
3xy y 2 x2

dx

x 2y 2 x2
3xy y 2 x 2

dy 0

dx
xdx
ydy
dy

0
x y2 x 2 y2 x 2
y

d ln xy

2
2
1 d y x
0
2 y2 x2

d ln x 2 y 2 y 2 x 2 0
ln x 2 y 2 y 2 x2 c
x2y2(y2 x2) = c
8.

Let the circle be x 2 y a2 . Let the point of intersection of tangents at P and Q be (h, k).
Then equation of PQ, is hx k y a2 0 . As it passes through a,0 , so,
ha k a2 0 .
2 k a h a 0. D 0 k 2 4a h a 0

i.e. y 2 4a x a .
1

9.

Consider

x 2 f x dx

f x 2xf x x f x dx =
2

22 + 2 = 0

However f(x) assumes only positive values i.e. in (0, 1)


2
( x) (f(x)) > 0 integral cant be zero
10.

Differential equation can be written as, (p x)(p 2 sin x)(2p + cos x) = 0 which has solution as
2
(2y x c)(y + 2 cos x c)(2y + sin x c) = 0

11.

Put x = 1 we get (1 + 1) p(1) + 1 = (1)


1n1

n 1 !

n+1

(n + 1)!

1n1 x x 1 ..... x n
x

n 1 ! n 1
x 1
where 'n' is odd
1,

Clearly, p n 1 n
n 2 , where 'n' is even
So, p x

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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

13.

If e is the eccentricity then, e2


1

Now, we know,
2 2
2

ab

1
2

ab

, 2 2

2
1
2 2

ab h2

1
ab h2

a b 2 4 ab h2
ab h 2

2
a b 4 ab h2

For an ellipse
So, e2

ab h2

2 2

2
a b a b 4 ab h2

a b 2 4h2
2
2
a b a b 4h
2

2 ab h

14.

Put y = z = t = 0
f(0)[f(x) + f(0)] = f(0)
Put x = 0
2f 2(0) = f(0)
1
f(0) = 0,
2
1
1
If f(0) =
f(x) +
=1
2
2
1
f(x) =
2
If f(0) = 0, z = t = 0
f(x) f(y) = f(xy)
Let, x = y = 1 f 2(1) = f(1)
f(1) = 0 or f(1) = 1
We have f(0) = 0, f(1) = 0, y = 1
f(x) = 0
Also, f(0) = 0, f(1) = 1, x = 0, y = t = 1
(f(0) + f(z)) (f(1) + f(1)) = f(z) + f(z)
2f(z) = f(z) + f(z)
f(z) = f(z)

15.

If y = x in f(x) f(y) = f(xy)


2
2
f(x ) = f (x) 0
Put x = t, y = z
[f(x) + f(y)]2 = f(x2 + y2)
f(x2 + y2) = f2(x) + f 2(y) + 2f(x)f(y) f2(x)
f(x2 + y2) f(x2)
f is non decreasing for positive x

16.

Put y = z = t = 1
2(f(x) + 1) = f(x 1) + f(x + 1)
f(2) = 4, f(z) = 9, f(1) = 1, f(0) = 0
f(n) = n2 (Possible function), if f(n 1) = (n 1)2
2[f(n 1) + 1] = f(n 2) + f(n)

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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

f(n) = n2

p
(rational number)
q
p
p
f f q2 f pq f q2 p2 q2
q

q

Now, for x

p p
f (True for rational number)
q q
Now, if x R, lets prove for positive x since if it is proved the function is even and will follow for
negative x
Assume for x > 0, f(x) < x2
So, now a rational number r between f x and x f x < r < x
2
2
f(x) < r < x
2
[f(r) = r , f is non decreasing]
f(r) = r2 f(x) [contradiction]
2
f(x) < x (impossible)
Similarly we can prove contradiction f(x) > x2
So, only possibility f(x) = x2 substituting f(x) = x2 we get
(f(x) + f(z)) (f(y) + f(t)) = f(xy zt) + f(xt + yz)
(x2 + z2)(y2 + t2) = (xy zt)2 + (xt + yz)2 [Lagrange identity]
1
So, f(x) = , f(x) = 0, f(x) = x2 are the required solutions
2

17.

am3 + m(2a h) + k = 0
am3 + m(2a x1) = 0
am2 = x1 2a {m = 0 (one possible value)}
x 2a
m2 1
, if x (0, 2a)
a
m2 = () number, so non real roots

18.

Let P(h, k) be the point am 3 + m(2a h) + k = 0


Since, m1, m1, m1 are the possible roots
3m1 = 0 m1 = 0
If m1 = 0 is the root then k = 0
am3 + m(2a h) = 0
h 2a
m2
0 h = 2a
a
(2a, 0) is the only point

19.

A1

8a

2a

2
2
4
5 / 2 8a
3/2
x 2a dx =
x 2a 2a
27a
3 3a 5

2 5 / 2
2
2
48 2a2
6a

36a2 6a =
5
3 3a 5
3 3a 5
2

8a

A1

4axdx 2 a

4
64
2 3 / 2 8a
a 8a 8a
2a2
x
0 =
3
3
3

11 352 2a2
4 3
Area = 2(A2 A1) = 2 16 2a2 = 32 2a2

15
15
3 5

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10

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

SECTION B
1.

(A) |A xI| = 0
There exists a non zero matrix X such that AX = xX
[(Adj A)A]X = x(adj A)X
|A|IX = x(adj A)X
|A|X = x(adj A)X
AX

adj A X
x
AX
adj A X
2
(B) A ' I A I ' A I
A ' I 0 if and only if A I = 0
A ' I 0 if and only if A I = 0
or is the root of A ' xI 0 if and only if is the root of |A yI| = 0
ei is the required solution
A11 A12 .......... A1n

A 22 ..... A 2n
0

|
|
(C) B I
=0
|
|
|

|
|

|
A nn
|
(|A11| )(|A22| ) .. (|Ann| ) 0
Clearly the elements of principal diagonal become the roots
(D) Let, AX = X [X is a non zero matrix]
X' AX = X' X = X' AX'IX

X' AX and X'IX are both real


Also, X' X 0 , X 0
X' AX / XIX is real so can have real values
2.

(A) z = cos + i sin , z

1
2cos
z

1
2isin
z
1
zp p 2cosp
z
z

1
1
1
1

4
2

Now, 2isin 2cos z z = z 6 6 2 z 4 4

z
z

z
then, 2 cos 6 2.2. cos 4 2 cos 2 + 4
4 4
4
2
2
2 i sin 2 cos = 2(cos 6 2 cos 4 cos 2 + 2)
=2

2 1
z 2 4

z

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11

(B) Volume of tetrahedron =

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

1
ArABD CQ
3

1 AB

DP CQ
3 2
Let, CD be the largest side and AB = x 1
Let, T be closer to A than B
x
BT
2
x2
CT 2 BC2 BT 2 1
4

CT 1

Q
T

P
A

x2
(same for DP, CQ)
4

1 x
x2
1
1
1
x 4 x 2 Vmax

3 2
4 24
8
(C) By AM GM
cos x
cos3 x
cos2 x (x is an acute angle)
4
Now, setting x = A, B, C we get
x1 + x3 cos2 A + cos2 B + cos2 C + 2 cos A cos B cos C = 2x2
3
x1 + x2 + x3 3x 2
2
A
B
C
Sa
Sb
Sc
(D) Let, u cot , v cot , w cot u
, v
, w
2
2
2
r
r
r
S S a S b S c

uvw
r
r
2
Now we can rewrite as 49[u + 4v2 + 9w2] = 36(u + v + w)2
(3u 12v)2 + (4v 9w)2 + (18w 2u)2 = 0
1 1
u:v:w=1: :
4 9
S a S b S c 2S b c
Multiplying by r we get

36
9
4
94
2S c a 2S a b
a
b
c
=

4 36
36 9
13 40 45

So, V

3.

1
3
4
2
and substitute, 8y + 4y + a
=0
2
2
3
2
Again, z = y we get, 8z2 4z a 0
2
3
3
When a there are 2 non real roots and two real and a we have 4 non real roots
2
2
3

1, a 2
Sum =
2, a 3

(A) Put x y

xy
(B) xy
1 0 < xy 1
2
3 3 3
3
x y (x + y ) = 2(xy)3((x + y)2 3xy) = 2(xy)3 (4 3xy)

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12

Put z = xy
4

4 3z 3z
z3 4 3z
1

3 3 3
3
x y (x + y ) 2
(C) There are 9 possible numbers of the type 7775775, 7757575, 7575575 etc.
(D) We have f(9) = f(4 + 5) = f(4 . 5) = f(20) = f(16 + 4) = f(16 . 4) = f(64)
f(64) = f(8 . 8) = f(8 + 8) = f(16) = f(4 . 4) = f(4 + 4) = f(8) = 9

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