Jika pada kasus terdapat suatu kondisi dimana molekul N2 pada tekanan 7,514 x 10-9 Pa

dan temperatur 1000 K dan jumlah molekul per m2 adalah 5,44 x 1011 dan pada
ketinggian 106 m dengan diameter tumbukan molekul N2 adalah 5 x 10-10 m maka N2
akan memiliki kecepatan rata-rata sebesar:

8 ( 8,314 J K 1 mol1) (1000 K )

(3.14)(28 x 103 kg mol1)

= 0,869 x 103 m.s-1

Sehingga N2 mempunyai frekuensi tumbukan sebesar

2 d 2 c Na p

RT

2 ( 5 x 1010 m ) (0,869 x 103 m . s1 )(6,023 x 1023 mol1)(7,514 x 1 09 Pa)

(8,314 J K1 mol1)(1000 K )
= 5,25x 106 s-1
Jadi N2 akan mempunyai jarak bebas rata-rata sebesar
=

0,869 x 10 3 m . s1
5,25 x 1 06 s1

30% N2
50% CO
15% H2
5% O2
STP: 1 Atm, 0C
Fraksi mol=fraksi gas
Asumsi 100L
Fraksi Berat: fraksi mol x Mr
Mr rata2: fraksi mol dikali Mr

= 0,165 x 10-3 m

Tekanan parsial
Fraksi mol x tekanan total
Densitas
Mr/22,4

V
N

80
40
3200

Ave
Sum

84,793
39
280

85
62
52
70

90
5
45
0

95
12
1140
85,494
18

z
km
=280 2 2 85.5
3.14 s 2 k m2
V
jam

10
0
2
20
0

v
n

80
38
3040

av
e

86,194
97

85
59
50
15

90
50
450
0

95
10
95
0

10
0
2
20
0

3) pada tekanan 1 atm, tentukan mr dari vapor

mass of vessel filled with dry air at 25C = 97.432 g
mass of vessel filled with vapor at 175C = 99.420 g
mass filled water at 23C = 550 g
1. Hitung volume tabung (m/rho)
2. Hitung berat tabung (berat tabung isi udara-berat udara) berat
udara=volume x rho udara (1.2gr/cm3)

3. Hitung berat vapor (berat penuh-berat tabung). PVMr=mRT->Mr=mRT/PV

A mixture of O2 and nitrous oxide, N2O, is sometimes used as a mild anesthetic in dental surgery. A certain mixture
of these gases has a density of 1.482 g L1 at 25 and 0.980 atm. What was the mole-percent of N2O in this mixture?

SOLUTION
First, find the density the gas would have at STP:

The molar mass of the mixture is (1.65 g L 1)(22.4 L mol1) = 37.0 g mol1. The molecular weights of

O2 and N2 are 32

and 44, respectively. 37.0 is 5/12 of the difference between the molar masses of the two pure gases. Since the
density of a gas mixture is directly proportional to its average molar mass, the mole fraction of the heavier gas in the
mixture is also 5/12:

37324432=512=0.42

Find the composition of a mixture of CO2 (44 g/mol) and methane CH4 (16 g/mol) that has a STP density of 1.214 g/L.

SOLUTION
The density of a mixture of these two gases will be directly proportional to its composition, varying between that of
pure methane and pure CO2. We begin by finding these two densities:
For CO2:
(44 g/mol) (22.4 L/mol) = 1.964 g/L
For CH4:
(16 g/mol) (22.4 L/mol) = 0.714 g/L
If x is the mole fraction of CO2 and (1x) is the mole fraction of CH4, we can write
1.964 x + 0.714 (1x) = 1.214
(Does this make sense? Notice that if x = 0, the density would be that of pure CH4, while if it were 1, it would be that
of pure CO2.)
Expanding the above equation and solving for x yields the mole fractions of 0.40 for CO2 and 0.60 for CH4.